Functionality of graphene as a result of its heterogenic growth on SiC nanoparticles on the basis of reversible hydrogen storage

This article presents the results from research related to graphene functionality based on the production of spatial structures provided for the reversible storage of hydrogen. The functionality process was conducted during graphene synthesis onto a liquid metallic support, on a single level, using SiC nanoparticles. Within the scope of research it was proved that heterogenic growth of the domains of polycrystalline graphene onto the SiC nanoparticles is possible. These nanoparticles are in-built into the graphene structure constituting the pillars of the spatial structure. Material produced in such a way constitutes the foundation for creating a spatial 3D structure (through the rolling operation), called GraphRoll, for the reversible storage of hydrogen in order to conduct its sorption and de-sorption. So, independently of the theoretical configuration, deviations or a possible exception from the 2D configuration on the silicon carbide/graphene were discussed. These differences resulted from the difference between the crystallographic structures of the analyzed forms as well as the structure determined to decrease tensions within the structure.     

Synthesis and properties of porous ion-exchange membranes,I. Polymer-polymer-filler system

A method of preparation of porous ion-exchange membranes (PIEM's) with sulfonic groups is presented. One of the four studied polymer blends is recommended for PIEM's preparation. It is the ternary blend of polyethylene with poly(styrene-co-divinylbenzene), isotactic polypropylene, and calcium carbonate. The effect of blend composition on membrane properties is also discussed. Both blend components, PP and CaCO₃, affected the membrane porosity while only PP governed the pore diameter. A model of PIEM's creation is suggested. The antifouling behaviour of PIEM's was evaluated by means of ultrafiltration of bovine serum albumine or poly(ethylene glycol) solutions as well as skimmed-milk and an active sludge designated for bioconversion of aldehydes. It was found that membranes with ion-exchange capacity higher than 1 mmol/g offer antifouling effect. PIEM's have also higher solute rejection parameter and are easier to regenerate than membranes without sulfonic groups.     

Thermal and flow effects during adsorption in conventional,diluted and annular packed beds

Previous investigations have shown a complex combination of thermal and flow effects during adsorption in highly loaded, narrow packed beds. Respective conditions were realized by packing relatively large zeolite particles in a narrow tube (which causes wall channelling) and adsorbing water vapour from air on the particles (which is highly exothermic). The present work extends the investigation to novel column configurations with purposely altered conditions of heat generation and flow—namely to diluted beds, annular beds and beds consisting of coated particles. Experimental results obtained by near infrared tomography are compared with the results of breakthrough experiments in conventional columns and with numerical calculations. The latter are conducted with a non-isothermal, two-dimensional model that not only considers the increase of porosity and flow velocity near the tube wall, but also expresses the effective transport coefficients as functions of the radial coordinate. The model provides reasonable accuracy under conditions for which the usual plug-flow assumption is questionable.     

Oligomer and Polymer Formation in Hexamethylcyclotrisiloxane (D<Subscript>3</Subscript>) – Hydrosilane Systems Under Catalysis by tris(pentafluorophenyl)borane

Summary Reactions of hexamethylcyclotrisiloxane, D₃, with 1,1,3,3-tetramethyldisiloxane, ^HMM^H, 1,1,1,3,3-pentamethyldisiloxane, ^HMM, phenyldimethylsilane and phenylmethylsilane catalyzed by tris(pentafluorophenyl)borane were studied. These reactions lead to ring opening of D₃ by the SiH reactant producing open chain oligomers with hydrosilane functionality at one or both chain ends. The reactivity of the hydrosilanes toward D₃ decreases in the series: PhMeSiH₂ > ^HMM^H > PhMe₂SiH > ^HMM. Competitive self-oligomerization of ^HMM^H and ^HMM also occurs. Primary products of these processes are able to enter into reactions with the SiH and D₃ reactants; some also undergo cyclization. Thus, consecutive and competitive processes lead to a series of various oligohomologues. Gas chromatography in conjunction with chemical ionization mass spectroscopy permitted identification of structure and determination of the basic directions of these oligomerization processes. Polysiloxanes of higher molecular weight may be also formed in some of these systems. The reactions, which occur in the systems studied, are rationalized on the basis of the mechanism involving the hydride transfer from silicon to trivalent boron. This includes the transient formation of tertiary trisilyloxonium borate which decomposes by the hydride transfer to one of the silicon atoms of the trisilyloxonium center. Footnote: This paper is dedicated to Professor Ian Manners in recognition of his significant contributions to the field of organometallic polymers.     

Mechanics of Oil Sands Slurry Flow in a Flexible Pipeline System

Slurry transportation is an economic haulage system in oil sands and coal-mining operations characterized by long haulage distances and rugged terrain. In such conditions, the ton-km-hr limits are exceeded creating extreme tire wear and high maintenance costs. Steep haul grades and rugged terrain also cause mechanical wear and tear, which decrease haulage equipment economic life. Hydraulic transportation is a proven and viable technology for slurry transportation in such conditions. Currently, stationary pipeline transportation is being used in transporting minerals in many mines. There is an increasing demand to create slurrified minerals at the mining faces to be transported to the processing plant. However, stationary pipelines are not capable for dealing with the rapidly changing configuration of the mining faces. In this paper, the authors develop the ground articulating pipeline (GAP) technology to address this problem. The GAP system consists of pipelines connected together with flexible joints in each pipe section, which allows deflection to avoid torsional stresses from the adjoining frames. This flexible arrangement accommodates the horizontal and vertical displacements of the mobile system as it follows the hydraulic shovels in the excavation process. The mechanics of the GAP system, as well as the production–economic function, are formulated and simulated over an extended period using data and information from Syncrude’s North Mine. The results show that the GAP system is technically and economically viable for productivity between 6,300 and 6,500 tons per hour. The simulated head loss for the GAP system is 15.66 m per 400 m, which compares with 20 m per 400 m for the existing stationary system at Syncrude. The pressure gradient-radius curves are asymptotic to the pipe boundaries, which indicates steep axial pressure gradient in these areas.     

MULSOPS: Multivariate Optimized Pit Shells Simulator for tactical mine planning

Abstract

Production planning, scheduling and allocation of resources in large-scale surface mining operations present a great challenge to mine planning engineers. Ore and waste extraction plans must be executed to achieve tactical objectives using appropriate tools. Many production planning and scheduling and resource allocation methods are based on trial and error, crisis management or subjective judgements with no detailed economic basis or mathematical rigour. In addition, these methods do not consider the random processes governing critical development and production variables. In this study, the authors develop a multivariate pit shell simulator, MULSOPS, which addresses these problems. Rigorous geometric formulations of the ellipsoidal approximations of the pit shells geometry, their expansions and sequential interactions are modeled to mimic material displacement dynamics in an open pit operation. Stochastic and numerical modeling techniques are used to provide solutions to the time-dependent geometric models in random multivariate states Under different production and economic paradigms, the geometric models are simulated to yield the source and characteristics of appropriate cuts. Combined production from successive exposed cuts provides periodic targets for tactical planning. Variance simulation is also used to provide analysts with sensitive stochastic variables for input data definition and tight production target tolerance. A numerical example is used to illustrate the use of MULSOPS for tactical planning in a typical open pit operation.     

Free volume in condensed phases: Separation of contributions

Free volume present in condensed phases is either divided among the atoms present, or treated as independent holes. If a distribution of hole sizes is assumed, both approaches can be reconciled: smaller holes (interstitials) can be considered as being attached to atoms, while holes larger than a critical size (e.g. atomic) can be treated as independent. The distribution obtained depends on the choice of a free volume model. The model of Landau and Lifshits is studied in detail as an example. Numerical calculations are reported for liquid toluene in the 220–370K range. Temperature increase produces an increase in the number of independant holes which continually coalesce. Initially, interstitial holes grow slightly with a temperature increase, but then their size tends asymptotically to a limit.