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排序方式: 共有998条查询结果,搜索用时 250 毫秒
71.
N‐Oligo(3‐hydroxybutyrate)‐functionalized polypyrroles: towards bio‐erodible conducting copolymers 下载免费PDF全文
Anna Domagala Wojciech Domagala Przemyslaw Ledwon Marta Musiol Henryk Janeczek Agnieszka Stolarczyk Piotr Kurcok Grazyna Adamus Mieczyslaw Lapkowski 《Polymer International》2016,65(12):1395-1404
New copolymer materials have been prepared by chemical grafting of oligomeric 3‐hydroxybutyric acid (OHB) onto polypyrrole (PPy) derivatives. The influence of grafting density and molecular weight of OHB brushes on the physicochemical properties of prepared copolymers was investigated. PPy substrates were prepared by FeCl3‐driven oxidative homopolymerization of N‐(2‐carboxyethyl)pyrrole or its copolymerization with pyrrole. The grafting method employed involved controlled anionic polymerization of β‐butyrolactone on pyrrole‐tethered potassium carboxylate active sites. Obtained PPy‐g‐OHB copolymers of varying grafting density and pendant polyester chain length were characterized and the observed structure–property relationships discussed. The impact of real time exposure to phosphate‐buffered saline environment was investigated and the residue products were characterized. Cross‐correlation of spectroscopic, thermal, electrical and elemental analysis data afforded comprehensive evaluation of the structure of prepared materials and their behaviour in hydrolytic medium. Erosion and degradation pathways have been identified, indicating ways to consciously tailor the physicochemical properties of these new biomimetic materials. © 2016 Society of Chemical Industry 相似文献
72.
In this work the electrochemical characteristics of copper and steel in chromate, cyanide, and phosphate baths as well as in a commercial bath (ENSTRIP S-180), in the absence of chromium and cyanides were determined. Average rates of copper coatings stripping from steel in the above mentioned baths and the baths influence on the morphology of steel surfaces were described. It was found that the commercial bath ENSTRIP S-180 could be successfully used for stripping of copper coatings from steel elements. 相似文献
73.
Ewaryst Rafajłowicz Wojciech Rafajłowicz 《Multidimensional Systems and Signal Processing》2013,24(4):637-656
A new view on uncertain system parameters is presented considering them in the same way as other independent variables, e.g., time or space variables. After re-interpreting the well known equations for the sensitivities of a system to parameter changes, we consider the problem of optimal control that takes into account not only the quality of control itself, but also a reduction in the influence of parameter changes. Firstly, we re-derive and elucidate known results for systems described by linear ordinary differential equations in the state-space form. Then, it is shown how to extend the well known theory of designing optimal controllers with quadratic criterion so as to cover the reduction of uncertainties in systems described by a class of linear partial differential equations. As a result, we obtain a controller that has a new modal structure in space. Furthermore, the controller incorporates additional sensitivity signals for each mode. 相似文献
74.
A Lamarckian Hybrid of Differential Evolution and Conjugate Gradients for Neural Network Training 总被引:1,自引:1,他引:0
The paper describes two schemes that follow the model of Lamarckian evolution and combine differential evolution (DE), which
is a population-based stochastic global search method, with the local optimization algorithm of conjugate gradients (CG).
In the first, each offspring is fine-tuned by CG before competing with their parents. In the other CG is used to improve both
parents and offspring in a manner that is completely seamless for individuals that survive more than one generation. Experiments
involved training weights of feed-forward neural networks to solve three synthetic and four real-life problems. In six out
of seven cases the DE–CG hybrid, which preserves and uses information on each solution’s local optimization process, outperformed
two recent variants of DE. 相似文献
75.
In this work we present studies on applicability of transition metal additives as sintering and electrical conductivity aids for cerium gadolinium oxide electrolyte. The nanosized Ce0.85Gd0.15O1.925 powder obtained by coprecipitation method was modified with Cr3+, Fe3+, Ni2+ or Cu2+ ions. Using high-intensity high-resolution X-ray powder diffraction data we have determined that Cr, Fe and Ni ions do not incorporate into the cerium gadolinium oxide surface or bulk when sintered at 1300 °C, but react with Gd ions to form Cr0.9Gd0.1O, GdFeO3 and GdNiO3 phases, while Cu incorporates in the material up to 0.7 mol% with a significant fraction of remaining material showing poorly crystalline CuO phase. The nanosized Ce0.85Gd0.15O1.925 material shows already improved sintering properties than previous reports but full sintering is not achieved below 1300 °C, however Cr, Fe and mainly Cu impregnation allows full sintering at 1300 °C. 0.5 mol% Ni impregnated material sintered at 1500 °C shows enhanced grain boundary conductivity that probably indicates that Ni incorporates into Ce0.84Gd0.15O1.925 above 1300 °C. The global results indicate, however, that optimization of ceria microstructure is at least of equal importance for sinterability and grain boundary conductivity than impregnation of the material with transition metal ions. 相似文献
76.
Frydrychowski AF Gumiński W Rojewski M Kaczmarek J Juzwa W 《IEEE transactions on bio-medical engineering》2002,49(8):887-904
This paper presents technical foundations for a new technique of near-infrared transillumination-backscattering sounding, which is designed to enable noninvasive detection and monitoring of changes in the width of the subarachnoid space (SAS) and magnitude of cerebrovascular pulsation in humans. The key novelty of the technique is elimination of influence of blood flow in the scalp on the signals received from two infrared sensors-proximal and distal. A dedicated digital algorithm is used to estimate on line the ratio of the powers of received signals, referred to as two-sensor distal-to-proximal received power quotient, TQ (t). The propagation duct for NIR radiation reaching the distal sensor is the SAS filled with translucent cerebrospinal fluid. Information on slow fluctuations of the average width of the SAS is contained in the slow-variable part of the TQ (t), called the subcardiac component, and in TQ itself. Variations in frequency and magnitude of faster oscillations of the width of that space around the baseline value, dependent on cerebrovascular pulsation, are reflected in instantaneous frequency and envelope of the fast-variable component. Frequency and magnitude of the cerebrovascular pulsation depend on the action of the heart, so this fast-variable component is referred to as the cardiac component. 相似文献
77.
Wojciech Zielonka 《Journal of Logic, Language and Information》2000,9(3):339-352
An axiomatics of the product-free syntactic calculus L ofLambek has been presented whose only rule is the cut rule. It was alsoproved that there is no finite axiomatics of that kind. The proofs weresubsequently simplified. Analogous results for the nonassociativevariant NL of L were obtained by Kandulski. InLambek's original version of the calculus, sequent antecedents arerequired to be nonempty. By removing this restriction, we obtain theextensions L
0 and NL
0 ofL and NL, respectively. Later, the finiteaxiomatization problem for L
0 andNL
0 was partially solved, viz., for formulas withoutleft (or, equivalently, right) division and an (infinite) cut-ruleaxiomatics for the whole of L
0 has been given. Thepresent paper yields an analogous axiomatics forNL
0. Like in the author's previous work, the notionof rank of an axiom is introduced which, although inessentialfor the results given below, may be useful for the expectednonfinite-axiomatizability proof. 相似文献
78.
A new method of the electrode modification and DNA immobilization for a biosensor is reported. Outer layer of a conventional carbon paste electrode (CPE) was modified with carboxyl groups by mixing stearic acid with the paste. Single-stranded deoxyribonucleic acid was attached to the modified electrode through a linker - ethylenediamine. Immobilization process was performed in the presence of activators - water soluble 1-ethyl-3(3′-dimethylaminopropyl)-carbodiimide (EDC) and N-hydroxysulfosuccinimide (NHS). Stearic acid concentration and other experimental parameters of the procedure were optimized. Covalent immobilization of DNA on the electrode surface exhibits some advantages as compared to simple adsorption mainly due to the fact that nucleic acid chains are bound to an electrode surface by one end only and it ensures structural flexibility and increases hybridization without DNA leakage. Modified electrode with immobilized (21-mer) oligonucleotide as a specific probe was successfully applied in preliminary investigations for the detection of bar gene commonly used in genetically modified food. 相似文献
79.
G Jacek C Kazimierz R Wojciech H Jolanta K Czes?aw 《Canadian Metallurgical Quarterly》1998,66(5-6):304-311
A group of 37 patients--20 (54%) men and 17 (46%) women--aged 2-65, mean 31.6 years, was treated between 1978 and 1995 for different kinds of primary mediastinal germ cell tumours. In 14 (37.8%) of them a mature solid teratoma was diagnosed, in 13 (35.1%)--dermoid cyst, in 5 (13.5%)--malignant teratoma, in 1 (2.7%)--immature teratoma, in 4 (10.8%)--seminoma. Mediastinal tumour was removed completely in 30 (81.1%) patients, partially in 7 (18.9%). Out of 37 patients, 3 (8.1%) died during postoperative time. Out of 26 patients discharged after surgical removal of mature teratomas, all are alive and have been followed-up for 10 years (17 patients) or 5 years (6 patients). Out of 8 discharged after surgical removal of malignant neoplasm, 3 are alive and all of them had primary mediastinal seminoma. One of them has survived 17 years after complete resection, and two patients--7.5 years and 2 years after partial resection and radiotherapy. Mean survival time is 4 years and 2 months for all patients with malignant neoplasm. 相似文献
80.
Poly(phenylene sulphide) was synthesized by a direct method. Benzene and elemental sulphur were used as substrates, and aluminium chloride as a catalyst. The obtained final product was characterized by IR, VIS-UV, wide angle X-ray and mass spectroscopy, thermal, and elemental analyses. On the base of the analytical methods the molecular structure of the obtained polymer was discussed. 相似文献