Single-layer Rh nanosheets with ultrahigh peroxidase-like activity for colorimetric biosensing

When the dimensionality of layered compounds decreases to the physical limit, ultimate two-dimensional (2D) anisotropy and/or quantum confinement effects may lead to extraordinary physicochemical attributes. Here, we report single-layer Rh nanosheets (NSs) exhibiting ultrahigh peroxidase-like activity, far exceeding that of horseradish peroxidase (HRP) and of most known layered nanomaterial-based peroxidase mimics. Considering per NS as an active subunit, the Rh NSs displayed a catalytic rate constant (K_cat) as high as 4.45 × 10⁵ s^–1 to H₂O₂, two orders of magnitude higher than those of HRP and Rh nanoparticles. The high atom efficiency of the Rh NSs can be attributed to the full exposure of surface-active Rh atoms, which greatly facilitates electron transfer and formation of superoxide anions, representing reactive oxygen species in the catalytic process. As a proof-of-concept application, the Rh NSs were successfully used as peroxidase mimics for the colorimetric detection of H₂O₂ and xanthine, with high sensitivity and selectivity. Moreover, a simple, rapid, and sensitive Rh-based paper sensor for ascorbic acid was also developed. In summary, this work provides a novel example of single-layer metallic NSs for biosensing.

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基于节点状态输出的动力学网络的自适应同步

基于微分方程不变原理,针对带有一般耦合函数的动力学网络,设计了实现网络同步的自适应同步方法.与其它的自适应同步方法相比较,该方法的优点是利用网络的一个节点的状态作为控制目标轨道来设计控制器.这一改进可以降低控制系统的维数,并且减少控制过程中各节点间的信息传递量.最后,通过一些数值算例验证所设计控制方法的有效性.     

一种适用锥头体的嵌入式大气数据传感系统改进校准算法

嵌入式大气数据传感系统的空气动力学模型基于钝头体推导,该模型是否适用于锥头体尚未得到证实;对一典型锥头体进行了空气动力学模型适用性验证,验证结果表明该空气动力学模型用于锥头体时动静压相对误差超过了2.5%;对此,提出了一种适用于锥头体的改进校准算法,并且进行了仿真验证;仿真结果表明动静压相对误差小于0.5%,改进的校准算法有效消除了模型误差。     

基于粗糙集的一体化保障技术属性约简问题研究

一体化保障技术是目前提高复杂武器系统测试和保障能力的研究重点,为解决一体化保障技术中存在的指标冗余问题,结合粗糙集相关理论,提出了基于属性重要性和属性间影响度的约简算法;通过在某型一体化保障设备的柴油发电机子模块中应用该算法,在精简测试指标的同时,保证了较高的测试准确性,缩短了测试时间,验证并说明该理论可以有效地解决一体化保障技术中的指标冗余问题。     

企业兼并的意义 现状 问题及对策

以企业兼并为主要方式的企业资产重组是当前我团经济体制改革的热点之一。本文从实际出发,阐明企业兼并对我国经济建设的意义,分析近十多年来我国企业兼并的基本特征及存在的问题,并提出相关的解决问题的对策建议。     

一次风反切系统的数值模拟和多相流动特性分析

四角切圆燃烧锅炉,存在着稳燃和结渣的矛盾,一次风微反切技术已在多台锅炉上得到应用,较好地解决了这对矛盾并能在一定程度上降低ＮＯｘ的排放量。本文把湍流理论和多相流动理论应用于炉内空气动力场的计算机数值模拟,用投影法编制的计算软件对６００ＭＷ锅炉炉内流动进行了计算,得出了一次风反切系统中炉内速度场、实际切圆、颗粒运动轨迹等结果,与冷炉和冷模试验基本吻合,对一次风反切系统的设计和调试具有参考价值。     

Ensemble of surrogates with recursive arithmetic average

Surrogate models are often used to replace expensive simulations of engineering problems. The common approach is to construct a series of metamodels based on a training set, and then, from these surrogates, pick out the best one with the highest accuracy as an approximation of the computationally intensive simulation. However, because the choice of approximate model depends on design of experiments (DOEs), the traditional strategy thus increases the risk of adopting an inappropriate model. Furthermore, in the design of complex product system, because of its feature of one-of-a-kind production, acquiring more samples is very expensive and intensively time-consuming, and sometimes even impossible. Therefore, in order to save sampling cost, it is a reasonable strategy to take full advantage of all the stand-alone surrogates and then combine them into an ensemble model. Ensemble technique is an effective way to make up for the shortfalls of traditional strategy. Motivated by the previous research on ensemble of surrogates, a new technique for constructing of a more accurate ensemble of surrogates is proposed in this paper. The weights are obtained using a recursive process, in which the values of these weights are updated in each iteration until the last ensemble achieves a desirable prediction accuracy. This technique has been evaluated using five benchmark problems and one reality problem. The results show that the proposed ensemble of surrogates with recursive arithmetic average provides more ideal prediction accuracy than the stand-alone surrogates and for most problems even exceeds the previously presented ensemble techniques. Finally, we should point out that the advantages of combination over selection are still difficult to illuminate. We are still using an “insurance policy” mode rather than offering significant improvements.     

移动云计算数据保护性能分析

文章基于移动云计算平台,采取通过Socket数据传输的方法,针对两种数据加密算法DES和RSA,测试定量数据传输过程中的时延和终端能耗,结果表明数据保护对移动云计算中事务处理性能有着显著的影响。最后,文章指出高效数据保护算法的研究是未来移动云计算安全方面的研究重点。     

基于MAXQ3108+DS8102的三相智能电能表设计

针对目前市场上采用电磁式电流互感器作为电流传感器的三相智能电能表计量精度普遍易受外部强磁场干扰的不足,采用美信半导体公司提出的MAXQ3108+DS8102芯片组,解决方案设计了一款采用锰铜分流器作为电流传感器的三相智能电能表,解决了锰铜分流器采样电流方式下各相电压、电流信号与数据采集MCU电气隔离的技术瓶颈,并详细阐述了信号采集与测量的过程;样机测试结果表明:文中设计的三相智能电表能够有效抑制外部强磁场干扰,有功电能计量精度满足IEC62053标准中有功0.5S级相关技术指标要求。