4-(2-噻唑偶氮)-5-二甲氨基苯胺与铑(Ⅲ)显色反应研究及其应用

研究了显色剂 4 ( 2 噻唑偶氮 ) 5 二甲氨基苯胺 (简称TADMA)与铑 的显色反应。结果表明 ,在 pH3 2～ 4 8范围内 ,铑 与TADMA反应形成 1∶2红色络合物 ,加入无机酸后色泽加深 ,络合物的表观摩尔吸光系数为 1 2 1× 10 5,铑质量浓度在 0～ 0 92 μg/mL范围内服从比尔定律。本方法操作简便 ,灵敏度高 ,选择性好 ,常见金属离子在一定范围内无干扰 ,用于催化剂中微量铑的测定 ,结果满意     

改进异步电机直接转矩控制系统的仿真研究

本文介绍了直接转矩控制系统的控制原理,并针对基于直接转矩控制的异步电动机运行时存在较大的电流及转矩脉动问题,提出一种新的控制方案,并基于Matlab 6.5对这种新方法进行仿真,仿真结果表明该方案能有效的解决电流及转矩脉动的问题.     

小型中间下料预焙电解槽技术条件摆布的思考

对小型中间下料预焙电解槽技术条件摆布的原则和具体数据进行了探讨，提出了尽可能利用从大型预焙槽上得出的先进经验，并消化吸收，掌握好各种条件的平衡，以取得好经济技术指标的观点。     

SDS/正戊醇/水体系的液晶研究

在 2 5℃测定了十二烷基硫酸钠 (SDS) /正戊醇 /水三元体系的相平衡 ,确定了液晶区域的边界范围。在液晶区域内选取一系列样品点 ,用差示扫描量热法 (DSC)和2 HNMR与液晶照片对照 ,研究了该体系的液晶结构特点。结果表明 :在恒定温度下 ,该体系存在着两个液晶区域 ,并且随含水量的增加 ,液晶结构发生变化。当组成固定时 ,体系的液晶相结构随温度升高也发生变化     

各向异性损伤理论与复合材料层板损伤的实验研究(一)-各向异性损伤理论

本文讨论了各向异性损伤力学的基本概念并介绍了以应变等效性假设为基础的Lemaitre模型和以能量等效性假设为基础的Cordebois模型.在此基础上作者导出了两种损伤模型的损伤能释放率的表达式.文中作者定义了一维损伤时弹性材料板单元的一些损伤定义,并导出了两种模型在一维损伤时损伤能释放率Y₂的简单表达式,从而为复合材料层板损伤测量的实验研究提供了理论基础,     

溶胶-凝胶法制备Li（MoO4）2：Eu及表征

用溶胶-凝胶法制备了平均粒径为2～3μm的小颗粒、高亮度的Li（2-x）（MoO4）2：Eu系列钼酸盐红色荧光体。用XRD、SEM、粒度分析和分子荧光光度计对荧光体进行了表征和研究。常规的固相反应合成Li（2-x）（MoO4）2：Eux系列红色荧光粉需要在900℃以上的高温才能够形成均一的固溶体，而采用溶胶-凝胶法制取，在700℃就可以形成均一的单相Li（2-x）（MoO4）2：Eux，在750℃就可得到发光亮度最高的荧光体。其亮度是常规固相反应于900℃制得的荧光体的124％。采用溶胶-凝胶法制取Li（2-x）（MoO4）2：Eux系列，可以在相当宽的实验条件范围内得到小粒径、窄分布和高亮度的荧光体，具有良好的颗粒形貌。     

Itemset trees for targeted association querying

Association mining techniques search for groups of frequently co-occurring items in a market-basket type of data and turn these groups into business-oriented rules. Previous research has focused predominantly on how to obtain exhaustive lists of such associations. However, users often prefer a quick response to targeted queries. For instance, they may want to learn about the buying habits of customers that frequently purchase cereals and fruits. To expedite the processing of such queries, we propose an approach that converts the market-basket database into an itemset tree. Experiments indicate that the targeted queries are answered in a time that is roughly linear in the number of market baskets, N. Also, the construction of the itemset tree has O(N) space and time requirements. Some useful theoretical properties are proven.     

国外尾矿坝安全与环境研究综述

安全与环境一直是国外尾矿坝研究的重点。笔者综述了自1990年以来国外涉及尾矿坝安全与环境方面有代表性的文献 ,内容包括尾矿坝溃坝、溃坝理论研究、安全管理、环境污染、污染监测、污染治理、污染理论研究及生态复垦 ,这些对提高我国尾矿坝管理、工程技术水平都有较好的参考价值     

垂直管吸收器内泡式吸收过程的数值研究

建立垂直管吸收器管内泡式吸收过程中传热传质的数学物理模型，对其泡式吸收过程进行数值研究，获得泡式吸收方式的一些传热传质特性，为吸收器的优化设计提供一定理论指导。     

Extracting Modes of Constrained Structure with Elastic Supports from Free Test Data

The dynamic flexibility (DF) and improved dynamic flexibility (IDF) methods can be applied to extract constrained structural modes from free-free modal test data. The residual flexibility method is also good for boundaries of constrained structure with rigid supports. Under elastic support boundary conditions both the DF and residual flexibility methods cannot produce accurate results. This paper expands the previously published IDF method to become a more general approach for structural design engineers. A new method called the general dynamic flexibility (GDF) method has been developed in this paper to extract constrained structural modes from free test data. The GDF method can always be applied as follows: (1) when the boundary support stiffness is very stiff, the GDF method can accurately obtain results from rigid support as by Liu et al. in 2001 and Zhang and Wei in 2003; (2) when the support stiffness is soft, the present method can produce results similar to those free-free modal parameters measured by hanging structures using rubber band; (3) when the support stiffness is zero, the method can reproduce true free-free modal parameters; and (4) when the support stiffness has any finite values, the GDF method can also achieve satisfactory results for engineering use. The algorithm included in the GDF method converges rapidly and is numerically stable in the analysis. This feature is very practical for many engineering applications for using the GDF method.