Synthesis of Titanium Oxycarbide from Titanium Slag by Methane-Containing Gas

In this study, reaction steps of a process for synthesis of titanium oxycarbide from titanium slag were demonstrated. This process involves the reduction of titanium slag by a methane-hydrogen-argon mixture at 1473 K (1200 °C) and the leaching of the reduced products by hydrofluoric acid near room temperature to remove the main impurity (Fe₃Si). Some iron was formed by disproportionation of the main M₃O₅ phase before gaseous reduction started. Upon reduction, more iron formed first, followed by reduction of titanium dioxide to suboxides and eventually oxycarbide.     

Impact of Aging Temperature on the Performance of a Nickel-Iron-Based Superalloy

In this study, the effects of aging temperature on the microstructure and properties of a nickel-iron (Ni-Fe)-based superalloy were investigated. On the one hand, owing to the increase in the size and particle spacing of Ni3Al (γ′) precipitate, long-term aging induced a significant drop in the alloy strength. Moreover, the increasing aging temperature from 700 °C to 750 °C further induced more than 75 MPa decline in the alloy yield strength. Furthermore, it led to a decrease in the critical stress because of dynamic recrystallization. On the other hand, the long-term aging increased the alloy’s ductility. The crack propagation along the grain boundary was inhibited, because of the decreasing grain boundary brittleness. Although the grain boundary precipitates changed from carbide to γ′ when the aging temperature increased, a distinct change in the alloy’s ductility was not observed. The transmission electron microscopy results showed that both precipitates were sheared by the grain boundary during the alloy deformation. These results confirm that aging temperature has less effect on alloy’s ductility.     

层层组装晶种法制备Mg-MOF-74膜及其分离性能

以2,5-二羟基对苯二甲酸和乙酸镁溶液为原料通过交替浸渍层层组装法在a-Al₂O₃载体表面预置晶种层, 再利用二次生长法制备出连续而致密的Mg-MOF-74晶体膜。采用X射线衍射(XRD)和扫描电镜(SEM)对膜进行了表征。实验结果表明:相比于原位溶剂热合成法, 通过2, 5-二羟基对苯二甲酸和乙酸镁交替浸渍层层组装法可以增强Mg-MOF-74与氧化铝基体之间的附着效果, 提高晶体薄膜的致密性与连续性, 实验发现4次交替浸渍层层组装预置晶种可以制备出具有分子筛分性能的Mg-MOF-74晶体膜, 单组分气体渗透测试表明其H₂/CO₂的理想选择性可以达到8.96, 高于其努森扩散选择性。XRD测试表明该晶体膜的特征衍射峰与文献报告的粉末MOF-74完全一致, 表明Mg-MOF-74晶粒以无取向形式生长于氧化铝载体表面。SEM表征表明Mg-MOF-74晶粒呈麦粒状微观外形, 其BET比表面积可以达到1182 m²·g^-1。     

光学遥感图像多目标检测及识别算法设计与实现

针对目前光学遥感图像处理与分析多集中在单目标检测及识别领域的局限性,多目标检测及识别成为了一个非常值得关注的研究课题,提出了一种光学遥感图像多目标检测及识别算法.首先,采用自适应阈值算法对目标快速检测分割;然后,结合图像金字塔思想和基于尺度不变特征变换的特征包(BoF-SIFT)特征提出了一种分层的BoF-SIFT特征表示目标的全局特征和局部特征,详细地描述了目标的分布特性;最后,采用基于径向基核函数的支持向量机为弱分类器的AdaBoost算法,经过不断更新权重之后得到一个强分类器对待测试目标图像完成分类识别,识别率达到了93.52%.实验结果表明,所提算法对多类遥感图像目标的分割效果显著,特征选取恰当,识别方法快速有效.     

下盘铁矿矿柱爆破回采对上盘矾矿稳定性影响分析

根据七角井铁矿下盘铁矿体和上盘矾矿体的空间赋存关系,如果对铁矿体预留的矿柱进行回采,很有可能对矾矿体的稳定性造成重大影响。为了保障矾矿体的安全高效开采,在回收下盘铁矿体预留矿柱的同时,尽可能减小对矾矿体稳定性造成影响,提出了2种矿柱回收方案和空区处理方案,矿柱回采方案为间隔间柱抽采法和间隔间柱控制爆破堆坝法,并对2个方案进行了数值仿真模拟,模拟结果显示：采用方案一可有效控制上盘围岩的垂直位移量,最终位移量仅为10.83 mm,而采用方案二开挖上盘围岩的垂直位移量较大,达到17.45 mm,可能会造成上盘围岩的坍塌,最终确定方案一为矿柱回收和空区处理方案。     

Some Refined Eigenvalue Perturbation Bounds for Two-by-Two Block Hermitian Matrices

We consider eigenvalue perturbation bounds for Hermitian matrices, which are associated with problems arising in various computational science and engineering applications. New bounds are discussed that are sharper than some existing ones, including the well-known Weyl bound. Two numerical examples are investigated, to illustrate our theoretical presentation.     

基于K-近邻隶属度模糊支持向量机的再造抽油杆损伤等级磁记忆定量识别

针对磁记忆技术在再造抽油杆损伤等级定量评价中小样本和分散性的难题,从再造抽油杆疲劳损伤实验出发,通过获取损伤演化过程的磁记忆特征规律,提取五维磁记忆特征向量,首次引入基于K-近邻隶属度的模糊支持向量机多分类算法,结合参数组合寻优方法,建立再造抽油杆损伤等级的多分类磁记忆定量识别模型。结果表明:利用K-近邻隶属度将分散性和模糊性加以量化,结合支持向量机的小样本优势,构造的K-近邻隶属度模糊支持向量机多分类磁记忆模型,可以进行再造抽油杆损伤等级的磁记忆定量识别,并进一步进行参数组合寻优,避免了盲目选择固定参数导致模型精度过低,具有较好的抗噪性和鲁棒性,为再造抽油杆损伤等级定量评价提供了一种新的方法。     

Aroma components at various stages of litchi juice processing

BACKGROUND: Considering the importance of flavour on the quality of litchi juice, a study was conducted on how processing and operating stages influence the aroma components of clear litchi juice during processing. RESULTS: The aroma fractions isolated by solid‐phase micro‐extraction were analysed by capillary gas chromatography–mass spectrometry. According to statistical analyses, the amount of total and seven characteristic aroma compounds (geraniol, citronellol, phenylethyl alcohol, D ‐limonene, nonanal, geranial and linalool) increased significantly after enzyme hydrolysis, but decreased significantly during the process of enzyme inactivation, ultra‐filtration and sterilisation. CONCLUSION: The aromatic fraction of litchi juice decreased greatly during processing. The major losses in aromatic composition of clear litchi juice were related to the ultra‐filtration and sterilisation processes. With regard to the retention of aroma, an ultra‐filtration membrane with a larger pore size is better than a membrane with a smaller pore size, and a high‐voltage pulsed electric field was better than thermal sterilisation. Copyright © 2009 Society of Chemical Industry     

聚丙烯纤维网混凝土的性能及工程应用

本文介绍了一种新型建筑材料——聚丙烯纤维网混凝土的性能、特性及施工方法。     

Data-mining based fault detection

This paper presents a fault-detection method based on the phase space reconstruction and data mining approaches for the complex electronic system. The approach for the phase space reconstruction of chaotic time series is a combination algorithm of multiple autocorrelation and Г-test, by which the quasi-optimal embedding dimension and time delay can be obtained. The data mining algorithm, which calculates the radius of gyration of unit-mass point around the centre of mass in the phase space, can distinguish the fault parameter from the chaotic time series output by the tested system. The experimental results depict that this fault detection method can correctly detect the fault phenomena of electronic system.