基于去噪卷积神经网络的雷达信号调制类型识别

针对低截获概率雷达(LPI)信号处理复杂,低信噪比条件下识别率低的问题,该文提出一种基于去噪卷积神经网络和Inception网络的信号分类识别系统.首先对8种LPI雷达信号进行Choi-Williams分布(CWD)时频变换,得到2维时频图像,然后使用去噪卷积神经网络进行时频图像去噪处理,最后将图像发送到Incepti...     

面向电网业务质量保障的5G高可靠低时延通信资源调度方法

该文研究面向电网业务质量保障的5G 高可靠低时延通信(URLLC)的资源调度机制,以高效利用低频段蜂窝通信系统内有限的频谱和功率资源来兼顾电力终端传输速率和调度时延、调度公平性,保障不同电力业务的通信质量（QoS）。首先,基于URLLC的高可靠低时延传输特性,建立电力终端多小区下行传输模型。然后,提出面向系统下行吞吐量最大化的资源分配问题模型并对其进行分步求解,分别提出基于定价机制与非合作博弈的功率分配算法和基于调度时延要求的改进比例公平算法（DPF）动态调度信道资源。仿真结果表明,提出的资源调度方法能在保证一定传输可靠性和公平性的条件下降低电力终端调度时延,满足不同业务等级的QoS需求,与已知算法对比有一定的优越性。     

H2 In Situ Inducing Strategy on Pt Surface Segregation Over Low Pt Doped PtNi5 Nanoalloy with Superhigh Alkaline HER Activity

Surface segregation constitutes an efficient approach to enhance the alkaline hydrogen evolution reaction (HER) activity of bimetallic Pt_xNi_y nanoalloys. Herein, a new strategy is proposed by utilizing the small gas molecule of H₂ as the structure directing agent (SDA) to in situ induce Pt surface segregations over a series of PtNi₅-n samples with extremely low Pt doping (Pt/Ni = 0.2). Impressively, the sample of PtNi₅-0.3 synthesized under 0.3 MPa H₂ delivers an extremely low overpotential of 26.8 mV (−10 mA cm⁻²) and Tafel slope of 19.2 mV dec⁻¹, which is superior to most of the previously reported Pt_xNi_y electrocatalysts. This is substantially related to the strong H₂ in situ inducing effect to generate Pt-rich@Ni-rich core-shell nanostructure of PtNi₅-0.3 with an ultrahigh Pt surface content of 46%. The specific mechanistic effects of H₂ during the PtNi₅-n synthesis process are well illustrated based on the combined experimental and theoretical studies. The density functional theory mechanism simulations further unravel that the evolved active site of PtNi₅-n can efficiently reduce the reaction Gibbs free energies; especially for the scenario of PtNi₅-0.3, the downward-shifted d band center of the Pt active site significantly reduces the Pt H bond strength, eventually resulting in the lowest absolute value of ΔG_H.     

High Mobility 3D Dirac Semimetal (Cd3As2) for Ultrafast Photoactive Terahertz Photonics

The Dirac semimetal cadmium arsenide (Cd₃As₂), a 3D electronic analog of graphene, has sparked renewed research interests for its novel topological phases and excellent optoelectronic properties. The gapless nature of its 3D electronic band facilitates strong optical nonlinearity and supports Dirac plasmons that are of particular interest to realize high-performance electronic and photonic devices at terahertz (1 THz = 4.1 meV) frequencies, where the performance of most dynamic materials are limited by the tradeoff between power-efficiency and switching speed. Here, all-optical, low-power, ultrafast broadband modulation of terahertz waves using an ultrathin film (100 nm, λ/3000) of Cd₃As₂ are experimentally demonstrated through active tailoring of the photoconductivity. The measurements reveal the photosensitive metallic behavior of Cd₃As₂ with high terahertz electron mobility of 7200 cm² (Vs)⁻¹. In addition, optical fluence dependent ultrafast charge carrier relaxation (15.5 ps), terahertz mobility, and long momentum scattering time (157 fs) comparable to superconductors that invoke kinetic inductance at terahertz frequencies are demonstrated. These remarkable properties of 3D Dirac topological semimetal envision a new class of power-efficient, high speed, compact, tunable electronic, and photonic devices.     

空间激光通信中精跟踪系统的实现与优化

简述了空间激光通信中精跟踪系统的组成和控制结构,分析了捕获、跟踪、瞄准系统精跟踪探测器使用质心算法进行信标光斑定位时的误差来源,对精跟踪探测器信标光斑定位过程进行傅里叶频域分析.推导得到消除质心算法系统误差的理论方案,即信标光波长和精跟踪系统的F数乘积需大于精跟踪探测器的像元尺寸.分析了精跟踪系统实现过程中关键参数的选取过程,结合精跟踪系统的系统参数耦合关系,为了不损失精跟踪视场,在精跟踪探测器镜头前添加孔径光阑进行精跟踪系统优化,以消除精跟踪探测器光斑定位时的系统误差.理论计算和实验证明:当孔径光阑的直径小于9.32 mm时,精跟踪系统的相对孔径小于0.045,精跟踪误差仅为0.03 pixel,相比优化前的精跟踪系统,跟踪精度提高了1.9倍.     

A Type of 1 nm Molybdenum Carbide Confined within Carbon Nanomesh as Highly Efficient Bifunctional Electrocatalyst

Highly efficient platinum‐alternative bifunctional catalysts by using abundant non‐noble metal species are of critical importance to the future sustainable energy reserves. Unfortunately, current electrocatalysts toward hydrogen evolution reaction (HER) and oxygen reduction reaction (ORR) are far from satisfactory because of lacking reasonable design and assembly protocols. A type of 1‐nm molybdenum carbide nanoparticles confined in mesh‐like nitrogen‐doped carbon (Mo₂C@NC nanomesh) with high specific surface area is reported here. In addition to the superior ORR performance comparable to platinum, the catalyst offers a high HER activity with small Tafel slope of 33.7 mV dec^?1 and low overpotential of 36 mV to reach ?10 mA cm^?2. Theoretical calculations indicate that the active sites of the catalyst are mainly located at Mo atoms adjacent to the N‐doped carbon layer, which contributes the high HER activity. These findings show the great potential of Mo₂C species in wide electrocatalysis applications.     

Solution‐Processed High‐Performance Tetrathienothiophene‐Based Small Molecular Blends for Ambipolar Charge Transport

Four soluble dialkylated tetrathienoacene ( TTAR) ‐based small molecular semiconductors featuring the combination of a TTAR central core, π‐conjugated spacers comprising bithiophene ( bT ) or thiophene ( T ), and with/without cyanoacrylate ( CA ) end‐capping moieties are synthesized and characterized. The molecule DbT‐TTAR exhibits a promising hole mobility up to 0.36 cm² V^?1 s^?1 due to the enhanced crystallinity of the microribbon‐like films. Binary blends of the p‐type DbT‐TTAR and the n‐type dicyanomethylene substituted dithienothiophene‐quinoid ( DTTQ‐11 ) are investigated in terms of film morphology, microstructure, and organic field‐effect transistor (OFET) performance. The data indicate that as the DbT‐TTAR content in the blend film increases, the charge transport characteristics vary from unipolar (electron‐only) to ambipolar and then back to unipolar (hole‐only). With a 1:1 weight ratio of DbT‐TTAR DTTQ‐11 in the blend, well‐defined pathways for both charge carriers are achieved and resulted in ambipolar transport with high hole and electron mobilities of 0.83 and 0.37 cm² V^?1 s^?1, respectively. This study provides a viable way for tuning microstructure and charge carrier transport in small molecules and their blends to achieve high‐performance solution‐processable OFETs.     

Thin,Millimeter Scale Fingernail Sensors for Thermal Characterization of Nail Bed Tissue

Thin, flexible, body‐worn technologies that allow precise, quantitative monitoring of physiological status are of broad current interest due to their potential to improve the cost and effectiveness of healthcare. Although the surface of the skin represents one of the most widely explored points of integration, recently developed millimeter scale wireless sensor platforms allow deployment on alternative surfaces of the body, such as the finger/toenails and the teeth. The work described here introduces a collection of ideas in materials science, device engineering and computational techniques that enables precise characterization of the thermal transport characteristics of the nail bed tissue from measurements on the surface of the nail. Systematic in vitro studies demonstrate the underlying measurement principles, the theoretical models for optimized sensor design and the associated experimental procedures for determining the thermal conductivity of the tissue. Measurements performed on human subjects highlight capabilities in tracking changes in perfusion of the nail bed tissues in response to various external stimuli.