Lactic acid production from dining‐hall food waste by Lactobacillus plantarum using response surface methodology

BACKGROUND: Food waste generally has a high starch content and is rich in nutritional compounds, including lipids and proteins. It therefore represents a potential renewable resource. In this study, dining‐hall food waste was used as a substrate for lactic acid production, and response surface methodology was employed to optimise the fermentation conditions. RESULTS: Lactic acid biosynthesis was significantly affected by the interaction of protease and temperature. Protease, temperature and CaCO₃ had significant linear effects on lactic acid production, while α‐amylase and yeast extract had insignificant effects. The optimal conditions were found to be an α‐amylase activity of 13.86 U g^?1 dried food waste, a protease activity of 2.12 U g^?1 dried food waste, a temperature of 29.31 °C and a CaCO₃ concentration of 62.67 g L^?1, which resulted in a maximum lactic acid concentration of 98.51 g L^?1 (88.75% yield). An increase in inoculum size would be appropriate for accelerating the depletion of initial soluble carbohydrate to enhance the efficiency of α‐amylase in dining‐hall food waste fermentation. CONCLUSION: A suitable regression model for lactic acid production was developed based on the experimental results. Dining‐hall food waste was found to be a good substrate for lactic acid fermentation with high product yield and without nutrient supplementation. Copyright © 2008 Society of Chemical Industry     

Influence of post‐treatments on the properties of porous poly(vinyl alcohol) membranes

Porous poly(vinyl alcohol) (PVA) membranes were prepared by a phase‐inversion method. The influence of chemical crosslinking and heat treatments on the swelling degree, resistance to compaction, mechanical strength, and morphology of porous PVA membranes was extensively studied. The crosslinking degree and crystallinity of the membranes, calculated from IR spectra, increased with the treatment time. The porosity, calculated on the basis of swelling experiments, showed a decreasing trend for heat‐treated membranes but remained almost at a constant value for crosslinked membranes. Such a change was further proved with scanning electron microscopy pictures. The behavior was explained by the rearrangement of PVA chains during the heat‐treatment process, which led to morphological changes in the membranes. The mechanical properties of the porous membranes in dry and wet states were measured, and a great difference was observed between crosslinked and heat‐treated membranes in the dry and wet states. The crosslinked membranes showed good mechanical properties in the dry state but became fragile in the wet state. On the contrary, the heat‐treated membranes were more flexible in the wet state than in the dry state. This change was explained by the turnaround of inner stress in the systems during the swelling process. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

Viscoelastic properties of polyarylene ether nitriles/thermotropic liquid crystalline polymer blend

Polyarylene ether nitriles (PEN)/thermotropic liquid crystalline polymer (TLCP) blend was prepared via melt mixing. The immiscible phase morphologies, linear and nonlinear, as well as transient viscoelastic properties of the blend were studied using SEM, rheometer, and DMA. The linear dynamic viscoelastic behavior of the blend shows temperature dependence due to further evolution of the immiscible morphology and, as a result, the principle of time‐temperature superposition (TTS) is invalid. In the steady shear flow, the discrete TLCP phase is difficult to be broken up because of the high viscosity ratio of the blend systems, while is easy to be coarsened and followed by elongation, and finally, to form fibrous morphology at high TLCP content and high shear level. During this morphological evolution process, the transient stress response presents step increase and nonzero residual relaxation behavior, leading to increase of the dynamic viscoelastic responses after steady preshear. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

虚拟企业模型并行仿真研究

随着各种全新的制造理念,特别是虚拟企业的出现,企业模型的规模不断扩大,使目前存在的大多数企业模型仿真系统的效率大大下降。该文针对此问题,通过深入分析虚拟企业模型结构,并在已有的构件化企业建模体系CEMS及其仿真系统的基础上,结合异步仿真技术和多线程技术提出了一种分层式企业模型仿真体系结构,为虚拟企业模型的快速高效的仿真提供了一种有效的方法。     

Modeling the effect of pigment morphology on the dynamic compression of coating layers using DEM

In the present paper, discrete element method (DEM) was employed to investigate the effect of pigment morphology on packing dynamics and compressive behavior of paper coating layers in calendering process. Spherical, platy, and needle-like particles, representing GCC, delaminated clay, and aragonite PCC pigments, were considered in this study. For each particle shape, the compression of coating structures formed by mono-sized and poly-dispersed pigments were modeled. Stress–strain behavior of the coating layers and in-plane and out-of-plane movements of the pigment particles during the compression were computed under the same maximum compressive stress. Simulation results revealed that the in-plane movements of the pigment particles during compression in the calender nip were small in magnitude (<0.35 μm). These findings help to better understand the smoothening phenomena of coating structures during the calendering process.     

转炉冶炼20CrMo钢的生产实践

介绍了石家庄钢铁有限公司转炉生产20CrMo钢的工艺技术及其产品质量状况和这一新工艺所带来的显著效益。     

Thermokinetics of Liquid-Liquid Reaction of Dy（NO3 ）3 with Histidine

The thermokinetics of liquid-liquid reaction of dysprosium nitrate with histidine were studied using a microcalorimeter. On the basis of experimental and calculated results, threethermodynamic parameters (the activation enthalpy, the activation entropy and the activation free enegy),the rate constant, three kinetic parameters (the activation energy, the pre-exponential constant and the reaction order) wereobtained. On the basis of thermodynamics and kinetics, the for marion reaction of the complex was discussed.     

30t转炉三位一体护炉实践

以转炉终点高拉碳操作法及降低出钢温度等操作护炉为根本护炉手段，溅渣为主要护炉方法，贴砖作为护炉的辅助措施，有效地提高了转炉炉龄，达到了1万炉以上，实现了根据设备检修计划下炉。     

固体超强酸S_2O_8~(2-)/SnO_2-SiO_2催化合成环己酮1,2-丙二醇缩酮

采用沉淀-浸渍法制备了固体超强酸S2O28-/SnO2-SiO2,以它为催化剂催化环己酮和1,2-丙二醇合成了环己酮1,2-丙二醇缩酮;考察了带水剂种类及用量、酮醇摩尔比、催化剂用量、反应时间对产品收率的影响,并用正交实验对反应条件进行了优化。实验结果表明,适宜的反应条件为:n(环己酮)∶n(1,2-丙二醇)=1∶1.6、催化剂用量为反应物料总质量的2.0%、带水剂环己烷用量5.0mL、反应时间50min。在此条件下,环己酮1,2-丙二醇缩酮收率达到91.47%;催化剂的稳定性良好,在重复使用5次后环己酮1,2-丙二醇缩酮收率为82.20%,活性下降的主要原因为催化剂表面积碳和吸附了有机物;经傅里叶变换红外光谱和气相色谱质谱分析表明,产物为环己酮1,2-丙二醇缩酮,纯度为100%。     

管内覆丝网强化对流换热及阻力特性的实验研究

通过实验对管内覆丝网管进行了强迫对流换热和阻力特性研究。结果表明：管内覆丝网使换热明显增强，阻力也相应增长。菱形丝网对角线距离与平行边距离之比对换热效果有决定作用，丝网厚度对换热的影响比较小，而丝网网格的大小对换热几乎没有影响，在相同的泵功率和几何条件下，换热系数最大增加２１％。