新型不锈钢化学抛光剂工艺研究

叙述了一般不锈钢化学抛光溶液的基本类型和在实际应用中存在的问题。着重论述MW－6不锈钢化学抛光剂的工艺研究过程、工艺条件、质量指标及检测方法，同时介绍了它与传统不锈钢化学抛光剂的比较，经验价值，表面质量控制，应用领域及应用前景。     

Study on esterification of acrylic phenolic resin by maleic anhydride and photocrosslinking properties of the alkali‐soluble product

An alkali‐soluble, photocrosslinkable polymer was synthesized by esterification of OH groups of acrylic phenolic resin with maleic anhydride. The OH groups were formed by the ring‐opening reaction of epoxy groups of epoxy phenolic resin with acrylic acid. The esterification conditions were studied. The results showed that it is better to use tetramethyl ammonium bromide as catalyst than N,N‐dimethylbenzylamine. The conversion of maleic anhydride in acetone can reach about 80% at 56°C for 4 h. The purified product was characterized by IR, DSC, and TGA. The product containing acrylate and maleic acid monoester groups, above a certain content, can be dissolved in 1% Na₂CO₃ solution. The photocrosslinkable properties of the product were investigated through selection of photoinitiator, accelarator, crosslinkable diluent monomer, etc. The acrylate and maleic acid monoester group‐containing phenolic resin exhibited very good photocrosslinking behavior, since it contains double bonds from both acrylate groups and maleic acid monoester groups. The activity of photoinitiator decreases in the order: isopropylthioanthraquinone > benzoin ethyl ether (BE) > anthraquinone (AQ) > benzophenone > Michel ketone (MK) > 2,2‐diethoxyacetophenone. The combination of some photoinitiators showed synergistic effects. The order of increasing activity for the accelerator is as follows: MK > ethyl p‐(dimethylamino)benzoate > N,N‐dimethylaniline > triethanolamine. The optimum diluent monomer is trimethylolpropane trimethacrylate. The gel content of the mixture of the resin and trimethylolpropane trimethacrylate could reach 85% using the combined photoinitiators of BE and AQ under UV exposure for 120 s. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 98: 1607–1614, 2005     

提高φ5m×11.5m生料磨产量的措施

针对粘土资源枯竭问题,江苏巨龙水泥集团实施了以粉煤灰和硅石代替粘土的技改工程。但改造后因原料的变更,导致入房物料易磨性变差而影响了φ5m×11.5m生料磨的产质量,并进一步影响察系统的运行。因此该厂在工艺分析的基础上,采取了调整钢球级配、用高铬球替代合金刚球、改造选粉机、加强石灰石二破的管理和减少系统是否是“漏风”等技术措施,效果显著。改造后的生料磨台时产量比调整前提高了12t/h,且节电效果显著。     

资源型城镇环境生态建设

我国资源型城镇面临严峻的环境问题和生态问题,许多小城镇生态绿化体系尚未建立。文章通过对国内外资源型城镇环境和绿化现状以及资源型城镇的分析,结合政府的生态管理职能和景观规划理论,提出环境生态建设的建议与措施,为实现资源型城镇的可持续发展奠定一定的理论基础。     

关联规则算法在法规备案审查工作中的应用

根据宪法和有关法律规定,全国人大常委会监督宪法和法律实施可以采取多种形式,法规备案审查正是其中一个重要的监督方式.我国的法规备案审查制度包含着违宪性审查和违法性审查两个层次的内容,其最高层次的法律渊源是宪法.现行宪法规定,全国人大常委会有权撤销国务院制定的同宪法、法律相抵触的行政法规、决定和命令,撤销省、自治区、直辖市国家权力机关制定的同宪法、法律和行政法规相抵触的地方性法规和决议.法规审查是一个复杂的过程,对具体负责审查工作的人员有极高的法律法规知识要求.因此,提高法规审查的科学性、客观性和准确性,是当前法规审查工作重要的课题.本文结合当前法规备案审查的实际,提出了法规关联分析评价指标体系,应用于法规审查工作中,并在此基础上设计并实现了法规备案审查系统.     

Surface Modification of Titania Nanoparticles Using Ultrathin Ceramic Films

Surface modification of titania nanoparticles was achieved by coating them with ultrathin alumina films using atomic layer deposition. The coating process was performed in a fluidized bed reactor at low pressure and under mechanical vibration. Films were deposited using self-limiting, sequential surface reactions of trimethylaluminum and water. The composition of alumina-coated particles was verified using infrared spectroscopy. The deposited films had an average growth rate of 0.2 nm/coating cycle and were highly uniform and conformal as demonstrated by transmission electron microscopy and X-ray spectroscopy. Deposited alumina films were amorphous as verified through X-ray diffraction and high-resolution electron microscopy. The coating process did not promote particle sintering as validated via particle size and surface area analysis.     

Preparation and properties of T300 carbon fiber‐reinforced thermoplastic polyimide composites

In this study, a series of T300 carbon fiber‐reinforced polyimide (CFRPI) composites were prepared by laminating premolding polyimide (PI) films with unidirectional carbon fiber (CF) layers. On the basis of PI systems design, the effect of CF volume fraction, processing conditions, and PI molecular structure on the properties of CFRPI composites was studied in detail. In addition, two kinds of nano‐particles, including carbon nano‐tube (CNT) and SiO₂ were filled into the premolding PI films with different concentrations. And the effect of nano‐particles on the properties of CFRPI composites was also investigated. The surface characteristic of T300 CF was measured by X‐ray photoelectron spectroscopy (XPS) and Fourier transform infrared spectroscopy (FTIR). The properties of premolding PI film and CFRPI composites were measured by dynamic mechanical analysis (DMTA), SANS testing machine, scanning electron microscopy (SEM), and so forth. These experimental results showed that the properties of CFRPI composites were mainly affected by the premolding PI film and molding condition. The change of CF volume fraction from 55% to 65% took little effect on the mechanical properties of CFRPI composites. In addition, the incorporation of nano‐particle SiO₂ could further improve the properties of CFRPI composites, but CNT hardly improved the properties of CFRPI composites. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 646–654, 2006     

千年前的求爱诗：震旦之恋·扶桑之情——《关雎》与《天皇御制歌》之比较研究

从主题、内容、形式结构、语言特色、视点、表现手法、诗歌风格等方面比较<关雎>与<天皇御制歌>的异同,探寻产生其异同的原因以及由此给日本文学发展带来的影响.     

化学教学与思想教育的融汇

本文阐述了在化学教学中要进行辩证唯物主义和爱国主义教育,要关注社会问题,要融汇政治思想教育。思想教育融汇在化学教学环节中首先要求我们对学生进行科学素养的培养;思想教育融汇在化学教学环节中要求我们的教学要与工农业生产相结合;思想教育融汇在化学教学环节中还要求我们的教学要与思想道德教育相结合,要与法制教育相结合;思想教育融汇在化学教学环节中还要求我们的教学要与现代教育技术相结合。     

A recognition method of vibration parameter image based on improved immune negative selection algorithm for rotating machinery

To overcome the limitations of traditional monitoring methods, based on vibration parameter image of rotating machinery, this paper presents an abnormality online monitoring method suitable for rotating machinery using the negative selection mechanism of biology immune system. This method uses techniques of biology clone and learning mechanism to improve the negative selection algorithm to generate detectors possessing different monitoring radius, covers the abnormality space effectively, and avoids such problems as the low efficiency of generating detectors, etc. The result of an example applying the presented monitoring method shows that this method can solve the difficulty of obtaining fault samples preferably and extract the turbine state character effectively, it also can detect abnormality by causing various fault of the turbine and obtain the degree of abnormality accurately. The exact monitoring precision of abnormality indicates that this method is feasible and has better on-line quality, accuracy and robustness.