TC11钛合金中氧铝偏析与脆性断裂

借助ＳＥＭ及ＥＤＡＸ、ＡＥＳ对某些ＴＣ１１钛合金棒材机械性能差的原因进行了研究。。结果表明材料延伸率、断面收缩率及冲击值低，显微硬度值高的拉伸和冲击断口上都呈现脆性解理断裂的断裂源，源区显微组织为条状α及空洞，且氧铝偏高。氧铝偏高造成α＋β→β相变温度和再结晶温度升高，使加工变形中形成的条状α在随后的热处理中得不到改变，并导致拉伸、冲击时的脆性断裂     

Synthesis of nano Sb-encapsulated pyrolytic polyacrylonitrile composite for anode material in lithium secondary batteries

A novel process was proposed to synthesize nano Sb-encapsulated pyrolytic polyacrylonitrile composite for anode material in lithium secondary batteries. The preparation started with the dissolution of SbCl₃ and polyacrylonitrile (PAN) in dimethylformamide (DMF) solution, followed by the addition of KBH₄ to reduce Sb³⁺ in the solution. The Sb composite was obtained by pyrolysis of the Sb/PAN mixture that precipitated out when the DMF solution was added by plentiful water. The TEM analysis showed that about 100-200 nm Sb particles were embedded by the pyrolyzed PAN, which provided a conductive matrix to relieve the morphological change of Sb during electrochemical cycling. As-prepared composite presented good cycleability for lithium storage. The proposed process paves an effective way to prepare high performance alloy based composite anode materials for high performance lithium-ion batteries.     

莫莱石－堇青石滤料滤池在生产上的应用

本文对景德镇市黄泥头水厂进行了单层莫－堇滤料滤池和双层莫－堇－煤滤料滤池的生产性试验。试验结果表明：单层莫－堇滤池和双层莫－堇－煤滤池的周期产水量分别是单层砂滤池和双层砂－煤滤池的１．４倍和１．５倍，而且前两种滤池的出水水质优于后两种滤池。     

植生混凝土在水利工程中的应用

植生混凝土是一种生态友好型工程材料。是采用特殊工艺由水泥、粗骨料和水拌制而成的,可适应植物生长的混凝土。其技术特点为具有较大的空隙率,经过碱性改良,并填充了适生材料。植生混凝土应用在水利护坡工程中,不仅能提高坡面稳定性,而且具有良好的生态效益。     

聚合反应器模型在高密度聚乙烯装置中的应用

以淤浆法高密度聚乙烯(HDPE)聚合过程为研究对象,建立了聚合反应器的数学模型方法,并把建立的模型在操作工况分析、装置能力核算和扩能改造方案确定等方面进行应用,同时还指出模型在其他方面的应用前景.     

Electrosyntheses and characterization of poly(5‐bromoindole) in boron trifluoride diethyl etherate

Poly(5‐bromoindole) (PBrI) films were synthesized electrochemically by direct oxidation of 5‐bromoindole in pure boron trifluoride diethyl etherate. The oxidation potential of 5‐bromoindole in this medium was measured to be only 0.97 V vs. saturated calomel electrode, which was lower than that determined in acetonitrile + 0.1 mol L^?1 Bu₄NBF₄ (1.08 V). PBrI films obtained from this medium showed good electrochemical behavior and good thermal stability. Structural studies showed that the polymerization of 5‐bromoindole ring occurred at 2,3 position. As‐formed PBrI films were thoroughly soluble in strong polar solvent dimethylsulfoxide and partly soluble in tetrahydrofuran. Fluorescent spectral studies indicated that PBrI was a good blue‐light emitter. The excitation and emission spectra of PBrI showed a significant shift to longer wavelength compared with that of the monomer, consistent with the greater extent of electron delocalization. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 101: 539–547, 2006     

BaTiO3基PTC陶瓷的研究现状及展望

PTC陶瓷（正温度系数热敏陶瓷）具有电阻率随温度升高而增大的特点，是近年来发展迅速的新型电子材料之一，其在低压领域的使用更是一直为各国研究者所关注。阐述了PTCR的半导电性能，并着重介绍了BaTiO3基低阻PTC陶瓷的研究现状和展望。     

氮化硅基陶瓷连接技术的研究进展

陶瓷连接技术是结构陶瓷实用化的有效手段，焊料成分对连接体的性能具有决定性作用。本文主要从焊料成分选择的角度，总结了氮化硅基陶瓷连接技术的发展现状；并重点讨论了陶瓷／玻璃复合焊料在β-Sialon陶瓷连接中的应用。     

Synthesis, morphology and photophysics of novel hybrid organic-inorganic polyhedral oligomeric silsesquioxane-tethered poly(fluorenyleneethynylene)s

A series of novel hybrid organic-inorganic light-emitting materials, polyhedral oligomeric silsesquioxane-tethered poly(fluorenyleneethynylene)s, were successfully synthesized via Sonagashira coupling reaction. The chemical structures of these copolymers were determined by ¹H NMR and FT-IR spectra. The morphologies of these copolymers were studied in details using TEM and WAXD. The WAXD data showed that POSS formed aggregation instead of crystallization in the polymer matrix, indicating the significant effect of the backbone constraint on POSS crystallization. Furthermore, it also revealed that the interchain interaction weakened and the interchain distance increased after introducing POSS groups. The TEM data indicated that POSS aggregates were well dispersed in polymer matrix. In accordance with the morphological investigation, the results of UV-vis absorption and photoluminescence emission spectra of these copolymers showed that the tendency toward planar conformation of conjugated backbones reduced to a certain extent due to weakened interchain interaction. Accordingly, these copolymers exhibited the enhanced quantum yields in the solid state. In addition, owing to the thermal and oxygen stability of hybrid POSS, the thermal spectral stability of these polymers was also improved greatly.     

提高PGC302型在线气相色谱仪的分析准确度

安阳化学工业集团有限责任公司“8·13”系统自1999年初投产以来,采用了3套PGC302型气相色谱仪分别对合成循环气、新鲜气、气柜出口半水煤气进行在线分析。但从2004年1月起,循环氢色谱仪对循环气中氢含量的分析值频繁波动,其测定准确度直接影响着系统氢氮比的调节效果以及合成氨产量的高低。为确保系统高负荷稳定生产,通过对影响色谱仪分析结果的因素进行分析,找到了引起分析值波动的主要原因,实施了切实可行的解决方案,提高了循环氢色谱仪的分析准确度。1循环氢色谱仪的配置和相关参数分析仪型号PGC302;检测器热导检测器;进样、反吹、柱…