Synthesis, structure and fluorescence properties of a highly stable indium(III)-2,5-pyridinedicarboxylate coordination polymer

The hydrothermal reaction of 2,5-pyridinedicarboxylic acid (H₂PDC), diethylene triamine and In(NO₃)₃·4.5H₂O gave rise to a two-dimensional (2D) coordination polymer In(OH)(2,5-PDC). This compound crystallizes in the orthorhombic space group Iba2, with cell parameters, a = 12.656(3) Å, b = 20.114(4) Å, c = 6.2216(1) Å, V = 1583.9(5) Å³ and Z = 8. Its structure contains one-dimensional In–O–In–O– chains, which are further linked by 2,5-PDC ligands into a 2D supramolecular neutral framework. The adjacent 2D layers are parallel with each other and construct a three-dimensional framework via hydrogen bands. At room temperature, the compound exhibits intense photoluminescence. On the basis of the results of TG/DTA analyses, the structure is thermally stable up to 390 °C.     

WCDMA的MBMS技术

主要介绍了基于WCDMA的MBMS技术,给出了其网络架构和技术难点,并对其应用给无线网络带来的影响作了一定深度的探讨。     

安徽省旱涝急转规律的认识与研究

旱涝急转是指某一地区或某一流域发生较长时间干旱时，突遇集中强降雨，引发山洪暴发、河水陡涨．客水入侵、内水难以及时外排的一种自然现象。旱涝急转极易造成人员伤亡、水库垮坝等重大经济损失。在防汛抗旱中，安徽省要充分认识旱涝急转的危害性，加强应急管理，具体包括思想上保持高度的警觉，加快防汛抗旱工程体系和预测预警体系建设，有效应对旱涝急转。     

不同压力下气层岩样m、n值变化的实验研究

胶结指数m和饱和度指数n变化规律的研究一直是岩石物理学家和测井解释分析家关注的问题。压力是影响m、n的重要因素,但迄今为止,仍未取得可使多数人接受的一般性结论。实验开展了低孔隙度低渗透率气层岩样在不同压力条件下的电阻率测量,在考虑孔隙度随压力变化的基础上建立了m、n参数随压力变化的关系,得出结论:某些地区的气层岩样在压力增大时即使考虑孔隙度变化,m值增大,n值减小。     

Densitometry determination of dioxins using gold nanoparticlemodified dioxin response element probes

This study aims to develop a rapid and sensitive densitometry bioassay of dioxins. It is known that dioxin ligand can bind heterodimeric aryl hydrocarbon receptor (AhR) and trigger the formation of the complex of dioxin-AhR, AhR nuclear translocator (Arnt), and dioxin-responsive element (DRE). We have established a rapid and sensitive method using nanoparticle-modified DRE probes based on dioxin-dependent binding of DRE to AhR complex. Dioxins can trigger the binding of nanoparticle-modified DRE probe to AhR complex. The nanoparticle-modified DRE probes in the dioxin-AhR-Arnt-DRE complexes immobilized on the microplates were detected by measuring optical density after silver enhancement. Results showed that as little as 0.01 pM of TCDD could be detected. Dioxins could be quantified accurately with the linear range from 1 nM to 0.01 pM. The coefficient of variation was 5≈8% in this bioassay. The optical density of nanoparticle-based silver enhancement was produced in a dose- and time- dependent manner. The dioxin concentrations in fly ash samples determined by this bioassay were comparable with that by the standard HRGC/HRMS. Thus this bioassay is a sensitive and convenient cell-free bioassay of dioxin that is suitable for screening of dioxins in environmental or food matrices.     

New concept of surface modification to LiCoO2

As the continuance of our series study on LiCoO₂ surface modification, the complicated traditional surface coating method is replaced with simple addition of amorphous YPO₄ and Al₂O₃ in commercial LiCoO₂ or in commercial electrolyte based on our understanding to the improvement mechanism of surface modification. Comprehensive studies by X-ray photoelectron spectroscopy (XPS), gas chromatography and mass spectroscopy (GC–MS), inductively coupled plasma (ICP) and Fourier transformed infrared (FTIR) indicate that the products of spontaneous reaction between the additive and the LiPF₆ based electrolyte are responsible for the performance improvements.     

制冷剂充灌量和毛细管长度对空调系统性能的影响

在空调器的匹配中，制冷剂充灌量和毛细管长度是两个非常关键的因素。本文采用理论与数值计算的方法，对制冷剂充灌量和毛细管长度对空调系统性能的影响进行了分析，为空调器的优化设计匹配、提高空调器的性能奠定了基础。     

基于Intel 87c196kc的某机载设备随动系统数字控制器的实现

介绍了某机载光电设备随动系统控制器的设计与实现。该控制器是基于Intel公司87c196kc的数字控制器，设计中充分利用了87c196kc较强的运算能力及其它片内功能，使得控制器设计简捷、调整灵活、体积小，提高了系统的可靠性。     

明渠湍流床面附近跃移层面颗粒浓度垂线分布

本文以动理学理论的Boltzmann方程为基础，考虑明渠湍流床面附近猝发喷射和清扫运动对跃移层内运动颗粒的不同作用，分析了明渠中泥沙颗粒浓度垂线分布问题，得到了适用于包括跃移层、悬移层在内的统一浓度垂线分布公式。文中着重研究了跃移层内运动颗粒的浓度垂线分布，并将本文结果与实测跃移层内浓度垂线分布及实测跃移层顶部浓度进行了对比，结果表明理论与实验两者符合较好。     

一种改进的同步侦破和识别过失误差的方法

将线性组合技术引入过失误差同步估计法 ,用于确定候选过失误差子集。以一个循环网为例 ,对两种算法的性能进行了比较。对一个蒸汽系统的稳态数据校正仿真结果证明了该方法的有效性