舵承干油润滑系统的国产化实践

进口的机械式舵承干油润滑系统存在成本较高、核心部件供货不及时等缺点,也存在一定安全隐患。选用标准型号电动干油站并进行技术改造,设计出完全国产化的舵承干油润滑系统,得到了用户的认可。     

Preparation of high silica microporous zeolite SSZ-13 using solid waste silica fume as silica source

Silica fume (SF) is a kind of solid waste that produced in the process of industrial silicon smelting. The disposal of SF for environmental problem is of great urgency. Here, a facile and novel one-step approach of high silica microporous materials SSZ-13 (SF-SSZ-13) were hydrothermally synthesized using silica fume (SF) as silica source. This method requires significantly shorter reaction times (48?h) compared to conventional SSZ-13. The as-synthesized SF-SSZ-13 exhibited high purity structure, popcorn-like morphology, and a large BET surface area of 545.74?m²?g^?1. Additionally, on the basis of controlled growth under different hydrothermal times, the formation mechanism of the SF-SSZ-13 outlined for further extension to other materials. The results on time- and energy-efficient of SF-based preparation of SSZ-13 pave the way for the reducing the cost of production of raw materials and decreasing environment load of solid waste, and also extend the application of silica fume.     

Fluorinated Bifunctional Solid Polymer Electrolyte Synthesized under Visible Light for Stable Lithium Deposition and Dendrite-Free All-Solid-State Batteries

Solid polymer electrolytes (SPEs) that can offer flexible processability, highly tunable chemical functionality, and cost effectiveness are regarded as attractive alternatives for liquid electrolytes (LE) to address their safety and energy density limitations. However, it remains a great challenge for SPEs to stabilize Li⁺ deposition at the electrolyte–electrode interface and impede lithium dendrite proliferation compared with LE-based systems. Herein, a design of solid-state fluorinated bifunctional SPE (FB-SPE) that covalently tethers fluorinated chains with polyether-based segments is proposed and synthesized via photo-controlled radical polymerization (photo-CRP). In contrast to the conventional non-fluorinated polyether-derived SPEs, FB-SPE is able to provide conducting Li⁺ transport pathways up to ≈5.0 V, while simultaneously forming a Li F interaction that can enhance Li anode compatibility and prevent Li dendrites growth. As a result, the FB-SPE exhibits outstanding cycling stability in Li||Li symmetrical cells of over 1500 operating hours at as high current density as 0.2 mA cm⁻². A thin and uniform Li deposition layer and LiF-rich SEI at the surface of Li anode are found, and stable cycling with average coulombic efficiencies of 99% is demonstrated in Li||LFP and Li||NCM all-solid-state batteries based on such bifunctional fluorinated SPEs. The interesting fluorine effect and effective self-suppression of lithium dendrites will inform rational molecular design of novel electrolytes and practical development of all-solid-state Li metal batteries.     

氯化十六烷基吡啶存在下硫氰酸铵—孔雀绿—水体系浮选分离锌(Ⅱ)的研究

研究了在氯化十辩烷基吡啶存在下硫氰酸铵－孔 雀绿－水体系浮选分离锌（Ⅱ）的行为及其与常见离子分离的条件，结果表明，在氯化十六烷基吡啶存在下，控制酸度条件，Zn(Ⅱ)可被硫氰酸铵－孔雀绿化－水体系浮选，而Co(Ⅱ），Ni(II),Mn(II),Fe(II),Al(Ⅲ）,Bi(Ⅲ）等离子在该体系中不被浮选，从而实现了Zn(II)与这些离子之间的定量分离。     

由硫酸锌废渣制备二氧化锗的研究

采用催化、酸浸、蒸馏等工艺，有效地回收了硫酸锌废渣中的锗，为锗的获取提供了一条经济、可行的途径。     

建筑用高阻燃型硬质聚氨酯泡沫塑料的研制

以国产聚醚多元醇、聚酯多元醇和泡沫稳定剂、催化剂、发泡剂等助剂为原料,配以液体阻燃剂制备的组合聚醚与多异氰酸酯反应制得的阻燃型聚氨酯泡沫塑料,其密度为50 kg/m~3,氧指数为32,导热系数低于30 mW/(m·K),压缩强度为310 kPa,满足了建筑阻燃要求。     

铅系复合钙钛矿Pb（Fe_（1／2）Ta_（1／2））O_3铁电陶瓷的介电弛豫

用普通合成法制备了纯钙钛矿结构相的Ｐｂ（Ｆｅ＿（１／２）＝Ｔａ＿（１／２））Ｏ＿３（ＰＦＴ）陶瓷，并进行了９００℃退火热处理。对其介电性质测试结果表明，未热处理与热处理过的ＰＦＴ陶瓷在０．１～１００ｋＨｚ频率下均表现出介电弥散性转变。未热处理的ＰＦＴ陶瓷最大介电常数对应的温度（Ｔ＿０）不随测量频率变化；热处理过的ＰＦＴ陶瓷在此频率范围Ｔ＿０值表现出明显的频率依赖性（频率色散），即ΔＴ＿０＝５℃。由此可以认为ＰＦＴ是弛豫铁电体。ＸＲＤ结果表明，未热处理的ＰＦＴ陶瓷无超晶格衍射；而热处理过的ＰＦＴ陶瓷则有较弱的（１１１）超晶格衍射。利用有序－无序转变理论及超顺电结构模型对其结构与性质进行了探讨。     

建筑地基变形计算的简易方法

目的 为了探索更为简便准确的地基变形计算方法,推动变形控制设计理念的发展.方法 在考虑地基变形经验系数的基础上,根据应力面积法原理提出了3种简单的地基变形计算方法.结果 规范法计算得到的变形大小与实测值相差较大,而所提出的3种改进计算方法均比规范法计算结果更接近实测值.结论 通过对比分析可知所提出改进公式计算地基变形更为简便,就文中算例而言,基于平均指标的计算方法优于基于当量层的计算方法优于改进的分层总和法优于规范法.     

土-桩-框架结构动力相互作用非线性有限元模拟

目的 用有限元方法研究土-桩-框架结构动力相互作用动力反应效应.方法 以AN-SYS程序为工具和平台,选用符合实际工作机理的Davidenkov地基模型并定义其参数,利用ANSYS的重启动分析方法、采用APDL参数设计语言编制程序来实现对土体材料的非线性及动力本构模型的模拟;同时利用ANSYS中Combin14单元模拟黏弹性边界,以此建立人工边界来模拟辐射阻尼效应;并提出集成阻尼矩阵的方法,解决结构和地基土阻尼不同而导致的阻尼耦合的问题.结果 通过算例对土-桩-框架结构进行ANSYS分析,考虑土的非线性、接触边界非线性以及阻尼的耦合问题,研究了不同性质地基土的非线性以及不同上部结构对整个体系动力特性的影响.并与已有实验研究结果进行对比分析.结论 结果表明提出的有限元方法能很好的模拟整个相互作用体系的非线性效应,为工程实践与设计提供重要的理论依据.