基于P2P技术的分布式PKI证书撤销列表发布

大规模PKI（Public Key Infrastructure）的核心在于数字证书的发放和管理,目前,PKI的管理机构一般采用证书撤消列表（Certificate Revocation List,简称CRL）的方式管理失效证书,但这些发布机制都不能有效地减低服务器端证书存储库的负荷。因此,在P2P技术的基础上,提出了一种分布式的CRL发布机制,该策略不仅在服务器端降低了峰值请求率,而且发挥了P2P网络中资源的版本越多越有利于资源的发现和共享的优点。     

基于多类别支持向量机的城市交通网络模式分类研究

在网络层次上进行区域交通信号控制、交通分配和路径诱导是缓解交通堵塞的有效途径之一。为进一步提高城市交通网络分类检测的准确性,将支持向量机（Support Vector Machine）应用于交通事件的模式分类研究。通过提出一种基于多类别支持向量机的交通模式分类方法,设计了适合该检测系统的网络结构。仿真结果表明：相对于其他算法,城市交通网络的状态可分为数量有限且不同类型的模式,并且这些模式不断重复出现,当系统识别出网络处于某种模式时,就可参照事先确定的优化参数及策略进行交通控制和诱导,以缓解交通拥塞,提高交通系统的运行效率。该网络结构对于小样本数据具有检测率高、误报率低的优点,完全适用于城市交通的模式分类,同时也存在不足之处,指出了今后进一步研究的方向。     

振动式微机械陀螺驱动环路数字AGC研究

对微机械陀螺系统的自激驱动环路进行了分析,并对数字处理电路中自动增益控制（AGC）模块进行了深入研究,给出了一种高控制精度的定点数字AGC算法。通过理论分析和模型仿真,结果表明AGC控制精度得到很大的提高,对陀螺驱动输出信号的幅度具有很好的控制效果,从而可以大大减小陀螺温漂及其他一些因素引起的不稳定性。最后给出了算法的直线逼近近似实现方法,能在的定点DSP当中很方便的实现。     

多小区MIMO系统中的一种主动式干扰抑制方案

针对多小区下行链路中的同频干扰问题,提出了一种新的主动式干扰抑制方案.该方案通过在各基站独立地采用预编码的方式来主动抑制本小区基站对其他相邻小区所产生的干扰.文中提出了两种实现算法:(1)迫零预编码,它可以获取和无同频干扰系统同样的性能;(2)基于干扰信道最大特征子信道的线性预编码,它能够有效地实现抑制干扰和提高本小区发遥自由度的折衷.仿真结果表明,本文方案提高了系统的性能和频谱效率.     

材料加工用激光束质量初探

本文从激光材料加工的角度讨论了以M2参数作为光束质量评价标准的可能性。指出对穿透式的加工方式,M2参数可以表示光束的实用价值,但对表面加工方式,M2参数的大小并不能反映光束实际的实用价值。     

In Situ Polymerizing Internal Encapsulation Strategy Enables Stable Perovskite Solar Cells toward Lead Leakage Suppression

Despite the outstanding power conversion efficiency (PCE) of perovskite solar cells (PSCs) achieved over the years, unsatisfactory stability and lead toxicity remain obstacles that limit their competitiveness and large-scale practical deployment. In this study, in situ polymerizing internal encapsulation (IPIE) is developed as a holistic approach to overcome these challenges. The uniform polymer internal package layer constructed by thermally triggered cross-linkable monomers not only solidifies the ionic perovskite crystalline by strong electron-withdrawing/donating chemical sites, but also acts as a water penetration and ion migration barrier to prolong shelf life under harsh environments. The optimized MAPbI₃ and FAPbI₃ devices with IPIE treatment yield impressive efficiencies of 22.29% and 24.12%, respectively, accompanied by remarkably enhanced environmental and mechanical stabilities. In addition, toxic water-soluble lead leakage is minimized by the synergetic effect of the physical encapsulation wall and chemical chelation conferred by the IPIE. Hence, this strategy provides a feasible route for preparing efficient, stable, and eco-friendly PSCs.     

Electrical and Thermal Transport Properties of Ge1–xPbxCuySbyTeSe2y

Balancing the contradictory relationship between thermoelectric parameters, such as effective mass and carrier mobility, is a challenge to optimize thermoelectric performance. Herein, the exceptional thermoelectric performance is realized in GeTe through collaboratively optimizing the carrier and phonon transport via stepwise alloying Pb and CuSbSe₂. The formation energy of Ge vacancy is efficiently bolstered by alloying Pb, which reduces carrier density and carrier scattering to maintain superior carrier mobility in GeTe. Additionally, CuSbSe₂, acting as an n-type dopant, further modulates carrier density and validly equilibrates carrier mobility and effective mass. Accordingly, the promising power factor of 45 µW cm⁻¹ K⁻² is achieved at 723 K. Meanwhile, point defects are found to significantly suppress phonons transport to descend lattice thermal conductivity by Pb and CuSbSe₂ alloying, which barely impacts the carrier mobility. A combination with superior carrier mobility and lower lattice thermal conductivity, a maximum ZT of 2.2 is attained in Ge_0.925Pb_0.075Cu_0.005Sb_0.005TeSe_0.01, which corresponds to a 100% promotion compared with that of intrinsic GeTe. This study provides a new indicator for optimizing carrier and phonon transport properties by balancing interrelated thermoelectric parameters.     

Voltage Decay of Li-Rich Layered Oxides: Mechanism,Modification Strategies,and Perspectives

Li-rich layered oxides (LLOs) have been considered as the most promising cathode materials for achieving high energy density Li-ion batteries. However, they suffer from continuous voltage decay during cycling, which seriously shortens the lifespan of the battery in practical applications. This review comprehensively elaborates and summarizes the state-of-the-art of the research in this field. It is started from the proposed mechanism of voltage decay that refers to the phase transition, microscopic defects, and oxygen redox or release. Furthermore, several strategies to mitigate the voltage decay of LLOs from different scales, such as surface modification, elemental doping, regulation of components, control of defect, and morphology design are summarized. Finally, a systematic outlook on the real root of voltage decay is provided, and more importantly, a potential solution to voltage recovery from electrochemistry. Based on this progress, some effective strategies with multiple scales will be feasible to create the conditions for their commercialization in the future.     

Air-Stable Li2S Cathode for Quasi-Solid-State Anode-Free Batteries with High Volumetric Energy

Anode-free batteries can maximize the energy density but their development is hindered by a lack of Li-rich cathodes for compensating the irreversible Li loss. Li₂S cathode is particularly appealing to this desire due to 2.6–4.7 folds more Li content and 4.2–6.8 times higher capacity than conventional intercalation cathodes. But its practical application is hindered by poor stability against moisture attacking in the air. Herein, a facile expendable polymer sheathing strategy toward air-stable Li₂S cathodes with high capacities for developing high-performance quasi-solid-state anode-free batteries without risk of cell leakage is reported. Tight protection by dense polymer barrier dramatically prolongs the lifetime of Li₂S cathode by 2,000 times at least in the air. Such air-stable Li₂S cathode allows for high compatibility of anode-free battery production with commercial schemes. More attractively, the polymer protective layer can in situ transform to multifunctional gel polymer electrolyte for releasing ionic pathways and enhancing cell performance by inhibiting LiPS loss and smoothing Li plating. With air-stable Li₂S cathode, the quasi-solid-state anode-free cells are assembled in ambient environment to deliver superb volumetric energy density of 1093 Wh L⁻¹. This study may shed new light to push the commercialization of high-energy and reliable anode-free batteries forward.