通过细乳液聚合方法制备自交联型有机硅乳液

苯乙烯与甲基丙烯酸-3-三甲氧基硅丙酯(M PS)经细乳液聚合,制得了稳定的自交联型的水分散涂料,用透射电子显微镜(TEM)、动态光散射仪(DLS)和红外光谱(IR)表征了乳胶粒的形态和结构。发现与传统乳液聚合相比,细乳液聚合法可显著提高乳液的稳定性,且M PS加入量的增加会导致乳液稳定性降低。     

Parametrized Maximum Principle Preserving Flux Limiters for High Order Schemes Solving Multi-Dimensional Scalar Hyperbolic Conservation Laws

In this paper, we will extend the strict maximum principle preserving flux limiting technique developed for one dimensional scalar hyperbolic conservation laws to the two-dimensional scalar problems. The parametrized flux limiters and their determination from decoupling maximum principle preserving constraint is presented in a compact way for two-dimensional problems. With the compact fashion that the decoupling is carried out, the technique can be easily applied to high order finite difference and finite volume schemes for multi-dimensional scalar hyperbolic problems. For the two-dimensional problem, the successively defined flux limiters are developed for the multi-stage total-variation-diminishing Runge–Kutta time-discretization to improve the efficiency of computation. The high order schemes with successive flux limiters provide high order approximation and maintain strict maximum principle with mild Courant-Friedrichs-Lewy constraint. Two dimensional numerical evidence is given to demonstrate the capability of the proposed approach.     

Poly(3‐chlorothiophene) films prepared by the direct electrochemical oxidation of 3‐chlorothiophene in mixed electrolytes of boron trifluoride diethyl etherate and sulfuric acid

3‐Chlorothiophene (CT) was electrochemically polymerized in mixed electrolytes of a boron trifluoride diethyl etherate solution containing 0–20% (by volume) sulfuric acid. The oxidation potentials of the monomer in these media were measured to be only 1.06–1.31 V (vs Ag/AgCl). These values were much lower than that of CT in acetonitrile and 0.1 mol/L (Bu)₄NBF₄ (1.92 V vs Ag/AgCl). Poly(3‐chlorothiophene) (PCT) films with conductivities of 0.1–2 S cm^?1 were obtained. The structure, morphology, and electrochemical behavior of the PCT films also were investigated. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 87: 502–509, 2003     

Water-soluble and amphiphilic polymers

Summary Three PEO-PSt-PEO triblock polymers and their parent ho-nopolystyrene have been studied by means of light scattering technique in chloroform, toluene and ethyl acetate. It has been found that the weight average molecular weights calculated by using the equation Mapp- were unbelievable negative values; and the largest deviation appeared for the sample with PEO mole content of about 50%. Data of PSt-PEO-PSt triblock polymers in literature have been quoted and discussed.     

基于Jpcap的Webmail邮件还原技术

基于Smtp和Pop3的邮件还原技术已经日臻成熟,而由于主要Webmail邮件格式不同,Webmail邮件还原技术一直是难点。通过对主要Webmail的内容格式分析,针对不同网站的Webmail建立相应的还原模块,实现对主要Webmail的内容还原。实验结果验证了该技术的有效性。     

The determination of the pore structural parameters of isoporous resins by inverse GPC

The swollen pore structure of a series of microporous isoporous resins (7.4–140 Å) are investigated with inverse GPC, n-alkylbenzenes and linear polystyrenes being used as probe molecules. The results indicated that, with the lowering of crosslinking degree of isoporous resins, the average pore diameter increased and the pore distribution curve broadened. All pore volume distribution obeyed a log-normal distribution. Based on the linear regression method, the experimental data were fitted to a monotonously declining exponential function and a normal distribution function by a computer, and some important structural parameters such as average pore diameter, pore volume distribution, specific surface area, etc. were obtained. The specific surface area of swollen gels were found much greater than those in the dry state measured by N₂ adsorption.     

Formation Mechanisms of Platelet Sr3Ti2O7 Crystals Synthesized by the Molten Salt Synthesis Method

The molten salt synthesis (MSS) method is utilized to synthesize the anisotropic platelet Sr₃Ti₂O₇ (S3T2) single-crystal particles. The aim of this study is to identify the essence of platelet Sr₃Ti₂O₇ crystal growth and guide the synthesis of anisotropic platelet SrTiO₃ crystals as well as various technologically important materials. Based on the results of X-ray diffraction, scanning electron microscopy, and high-resolution transmission electron microscopy, the formation mechanism of platelet Sr₃Ti₂O₇ crystals conforms to a nucleation–structure rearrangement–dissolution–diffusion in situ epitaxial growth mechanism model. First, SrCO₃ reacts with TiO₂ to form submicrometer SrTiO₃ nuclei. Then, most of the nuclei surrounded by salt ions aggregate and rearrange to form a large SrTiO₃ matrix. The structural rearrangement and the subsequent in situ epitaxial growth processes control the morphology, composition, and size of the final Sr₃Ti₂O₇ crystals. In the synthesis process, the conversion between SrTiO₃ and Sr₃Ti₂O₇ is as follows: and the crystallographic orientation relationship between Sr₃Ti₂O₇ and SrTiO₃ in the interface is (100)_S3T2//{100}_ST, (010)_S3T2//{010}_ST, and (001)_S3T2//{001}_ST.     

Preparation,characterization, and adsorption properties for metal ions of a novel chelating resin containing sulfoxide and diethylene glycol

A novel chelating resin containing sulfoxide and diethylene glycol, poly{4‐vinylbenzyl‐[2‐2‐(hydroxyethyl)ethoxyl]sulfoxide} (PVESO) was synthesized using chloromethylated polystyrene (PS‐Cl) as material. Its structure was characterized by elemental analysis, infrared spectra, and scanning electron microscopy (SEM). The adsorption capacities of the resin for Hg²⁺, Ag⁺, Cu²⁺, Zn²⁺, and Pb²⁺ at various pH values were determined. The maximum adsorption capacities for Hg²⁺ and Ag⁺ were 1.56 and 0.75 mmol g^?1 respectively. The resin had high selectivity for Hg²⁺ and Ag⁺ over the pH range 1.0–7.0. The adsorption capacities for Hg²⁺ and Ag⁺ under competitive condition were also determined by batch experiment method. In addition, the adsorption kinetics of the resin towards Hg²⁺ at different temperatures was also investigated. The results showed that the adsorption rate was governed by film diffusion at 20°C and 25°C, by particle diffusion at 30°C and 35°C. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 6054–6059, 2006     

钴钼系耐硫变换催化剂硫化与水解问题探讨

钴钼系耐硫变换催化剂硫化与水解问题一直受到人们的关注。许多研究人员对硫化水解做了大量的报道，但都以热力学平衡为基础，计算出的结果存在理论和实际相背离。因此，作者想从化学平衡和动力学双重角度对硫化与水解问题做一探讨。     

硫磺延伸产品的现状及展望

介绍了硫脲、甲硫醇、蛋氨酸、硫肥、含硫建筑材料、不溶性硫磺、Na-S电池等硫磺延伸产品情况.指出硫酸企业要以硫磺、CS2、SO2、SO3和硫酸为原料,构建多层次、多元化的精细硫化工产业链,使硫酸企业走上特色化工和精细化工之路.