Soap‐free emulsion copolymerization of perfluoroalkyl acrylates in the presence of a reactive surfactant

Soap‐free emulsion copolymerization of perfluoroalkyl acrylate (FA)/methyl methacrylate (MMA)/n‐butyl acrylate (n‐BA) was carried out in the presence of sodium 2‐acrylamide‐2‐methyl propanesulfonate (AMPSNa) as a reactive surfactant and potassium persulfate (KPS) as an initiator. An analysis of the effects of concentration of AMPSNa, KPS, FA as well as polymerization temperature on the kinetic features (rate of polymerization) and colloidal characteristics (mean particle diameter, particle disperse index, particle numbers, and surface charge density) was followed. NMR, FTIR, AFM, and fluorine‐selective electrode analysis were used to characterize the composition and morphology of the FA copolymers. Both AFM analysis and contact angle measurements strongly implied that the fluorinated segments migrated to the outmost surface and created films with lower surface energy. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 104: 2438–2444, 2007     

Modification of silk with aminated polyepichlorohydrin to improve dyeability with reactive dyes

Reactive dyes have almost complete exhaustion and ideal fixation on aminated polyepichlorohydrin pretreated silk without addition of salt or alkali. The effects of varying pretreatments and dyeing conditions were studied. The dyeing behaviour of CI Reactive Red 15 on modified silk under pH 6 was investigated. Dyeings of modified silk showed good wash fastness, dry and wet rub fastnesses as well as light fastness. The quality of the dyed silks obtained after pretreatment was shown to be satisfactory and the dyeing effluent was less polluted.     

Study of the amination of fatty alcohols catalyzed by Cu−Ni catalysts

Amination of fatty alcohols by hydrogenation and dehydrogenation catalysis is one of the main commercial processes for the production of dimethylalkylamines. The key factor in this process is the preparation of catalysts with high selectivity. A study of amination catalyzed by Cu−Ni catalysts supported on CaCO₃ is reported in this paper. Selectivity of the catalysts was adjustable by varying the ratio of Cu to Ni or by adding a third element (Zn or Mg). The promotion of catalyst selectivity was mainly attributable to the effect of the components on the reducibility of Ni²⁺ in the catalysts. Lower reducibility of Ni²⁻ led to higher catalyst selectivity.     

HT-730改性酚醛-丁腈胶粘剂的研制

对酚醛-丁腈胶粘剂进行改性，添加5．0％的硅烷偶联剂，改善了酚醛-丁腈胶粘剂的工艺性能，提高了粘接强度，特别是降低了酚醛-丁腈胶对环境湿度的敏感性。研制的HT-730胶在环境湿度90％时仍有很高的粘接强度，同时老化性能和适用期并没有受到影响。     

运动发酵单胞原生质球的形成和再生

运动发酵单胞(Zymomonas mobilis)ATCC29191菌株在含1～3g/L甘氨酸的液体培育12小时的菌体,用含20g/L的溶菌酶溶液处理12小时,可以稳定得到80％～90％的原生质球。原生质球稀释后在底层再生培养基上涂布,上面复盖一层半固体培养基,30℃培养5～7小时,再生率可达10~(-2)水平。     

Study of different effect on foaming process of biodegradable bionolle in supercritical carbon dioxide

Microcellular foaming of biodegradable Bionolle in supercritical CO₂ has been produced. The effects of a series of variable factors, such as saturation temperature, saturation pressure, and depressurization time and step on the foam structures and density, were studied through measurement of density and SEM observation. The experimental results show that higher saturation temperatures lead to an increase in bulk densities; and different depressurization time and step result in different product cell morphology. In addition, at some saturation temperature, the orientation of the cells can be found in the product morphology. XRD experimental results show that the foaming treatment with SC CO₂ increased the crystallinity of Bionolle. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 2901–2906, 2006     

层次约束结构的虚拟装配建模技术

为了解决虚拟环境下装配建模在信息完备性和模型复杂性等方面的问题,提出了一种基于层次约束结构的虚拟装配模型.该模型分为产品层、部件层、零件层、特征层、几何面层和面片层来表达,不同层元素之间存在层次映射关系,同一层元素之间存在约束关系.通过CAD系统和虚拟装配系统之间的数据转换,实现了虚拟装配模型的生成算法,并给出了根据虚拟装配模型生成的虚拟装配场景图的结构.基于层次约束结构的虚拟装配模型具有信息表达完备,信息集成度高,满足实时性要求等优点,同时还能与CAD系统和虚拟装配场景图实现集成.实例验证了虚拟装配建模的有效性.     

圆管层流脉动流动的数值模拟

为研究圆管层流脉动流动特性,建立了二维非稳态轴对称模型,对壁温恒定、入口速度周期性变化的流体进行数值模拟.分析了速度振幅和频率对层流流动的影响,得到了频率和振幅对压力、温度、壁面摩擦系数影响的规律.研究表明:脉动流动时,压力、温度、壁面摩擦系数围绕相同Re下稳态流动时的数值波动;压力与速度之间存在相位差;压力、壁面摩擦系数的波动与速度振幅和频率成正比;温度的波动与速度振幅成正比,与频率呈反比;当流体脉动的频率和振幅足够大时,会在近壁面处出现回流,并且出现回流的时间会随着频率和振幅的增大而增长.     

基于多特征融合的运动物体识别方法研究

为了实现运动目标的实时检测,本文基于多特征融合,提出了一种运动物体分级识别方法.首先通过对运动目标的分割,分析得到各个物体的形状矩特征、面积大小及运动速度.对上述特征,采用支持向量机方法对其矩特征进行快速的一级分类,然后对一级分类结果及各物体的面积、速度等信源根据其对分类的重要程度,采用模糊积分技术进行多特征融合分类.实验表明,本方法具有较强的学习能力及较高的识别精度,可有效地应用于道路监控等系统.     

Study on early warning index of spatial deformation for high concrete dam

Owing to the deficiency in early warning for high concrete dam,a formula was established to characterize the deformation behavior of high concrete dam as a whole.The early warning index of spatial deformation was calculated by low probability principle on the basis of the deformation entropy formula proposed.The steps were as follows.Firstly,the probability method was utilized to define the degree of order and degree of chaos for each survey point.Secondly,the weight distribution among the survey points was...