Synthesis and optimization of high-performance amine-based polymer for CO2 separation

Membrane technology features inspiring excellence from numerous separation technologies for CO₂ capture from post-combustion gas. Polyvinylamine (PVAm)-based facilitated transport membranes show significantly high separation performance, which has been proven promising for industrial scale-up. However, commercialized PVAm with low molecular weight and excessive crystallinity is not available to prepare high-performance membranes. Herein, the synthesis process of PVAm was optimized by regulating polymerization and acidic hydrolytic conditions. The membranes based on PVAm with a molecular weight of 154 kDa and crystallinity of 11.37% display high CO₂ permeance of 726 GPU and CO₂/N₂ selectivity of 55 at a feed gas pressure of 0.50 MPa. Furthermore, we established a PVAm synthesis reactor with an annual PVAm solution (1%(mass)) capacity of over 7000 kg and realized the scaled-up manufacture of both PVAm and composite membranes.     

浅析建筑智能化弱电施工管理

由于我国经济水平的与日俱增,同时建筑电气工程的整体水平也在逐步上升,促使建筑智能化弱电施工管理的普及程度越来越高。本文从建筑智能化弱电施工设计为切入点,对施工、设计建设等方面进行了分析,并对其提出注意事项与管理策略。     

带电清洗技术的机遇——电力设备绝缘护理综合方案

施行该方案具有重大宏观经济效益,而带电清洗是该方案的一个组成部分.     

EFFECT OF SURFACTANTS ON Ni-TiN NANOCOMPOSITE COATINGS PREPARED BY ULTRASONIC ELECTRODEPOSITION

Ni-TiN nanocomposite coatings were prepared by ultrasonic electrodeposition, and the effects of the surfactants on the coatings were investigated and the microstructure and micro rigidity of the coatings were characterized. Samples were also submitted to corrosion tests in 3% NaCl solution. The results showed that the surfactants had great effects on Ni-TiN nanocomposite coatings. The composite coatings prepared by ultrasonic electrodeposition with the surfactants were better than that of the coatings prepared without surfactants. The favorable properties of Ni-TiN nanocomposite coatings were prepared with the mixing of the non-ion and positive ion surfactants. The concentration of the mixing was 80 mg/L, and the ratio of the non-ion and positive ion surfactants was 1: 2.     

漂烫黄秋葵嫩果力学质地变化及评价方法的研究

为探讨漂烫黄秋葵嫩果的力学和色泽质地变化规律以及建立漂烫黄秋葵嫩果力学质地评价方法,用TA-XT2i质地分析仪对漂烫黄秋葵嫩果横切片进行了两种接触方式的硬度测定,并测定了不同漂烫温度、漂烫时间和冷却条件下黄秋葵嫩果的硬度,同时用DC-P3色差仪进行了色泽测定。实验表明,用棱接触压缩实验的压缩功评价漂烫黄秋葵硬度优于棱面接触压缩实验;黄秋葵嫩果经40、60℃漂烫后冷激能更好地保持原来硬度、色泽,且沿长度方向其硬度呈下降趋势;经80、100℃高温漂烫后,黄秋葵嫩果发生软化和褐变;综合力学和色泽质地的分析,黄秋葵嫩果最佳漂烫方法为60℃漂烫30⁶0s后冷激。本研究表明用棱接触压缩实验法评价漂烫黄秋葵力学质地变化是可行的,本实验为漂烫黄秋葵力学和色泽质地变化提供了参考。      

Scaled consensus for MASs with compound noises over Markovian switched topologies

This article aims to address the stochastic scaled consensus issue in almost surely and mean square sense of stochastic multiagent systems (SMASs) with compound noises in a Markovian switching setting. At first, based on stochastic approximation technique and nearest-neighbor interaction rules, the stochastic scaled consensus controller is built for SMASs in presence of multiplicative and additive noise by designing a time-varying gain. Meanwhile, some consensus criterions of SMASs are addressed if the union of the graph and time-varying gain fulfill some mild requirements. Furthermore, the scaled consensus means that the agents' state variables tend to a prescribed proportion rather than the common value, so this behavior can be seen as non-convergent behavior. The difference with most of excellent literatures is that the coexistence of noncooperative behavior and multiplicative noise generates that it is not easy to transform the multiplicative noise term into the form of an error equation, which means that the Lyapunov methods cannot be directly utilized in our article. To cope with this, we first demonstrate the boundedness for each agent's state, and hence the convergence can be achieved. Finally, in order to reveal the efficiency of our proposed protocol, the corresponding example is given in the simulation part.     

真空炉温度均匀性测量的数值模拟研究

采用BNi-2镍基钎料对热流道板进行真空钎焊,须根据钎焊件设定加热工艺曲线。加热工艺曲线的设定是钎焊过程最重要的环节之一,决定着钎焊的质量和效率。该文结合真空加热的特点及钎焊要求,运用Ansys有限元软件数值模拟的方法,对壁厚、体积较大的多层热流道板真空钎焊进行仿真分析,通过对比不同工艺方案及不同钎焊件的模拟结果,探究真空钎焊过程升温规律,从而调整各阶段的相关参数及制定合理的加热工艺曲线,避免了现场反复调试参数造成的资源浪费,节约了时间和成本,提高了效率。此外,通过在实际钎焊试验过程中布置热电偶对钎焊件测量温度,并与数值模拟结果对比,两者基本吻合,验证了有限元分析的准确性,能为之后其他零部件的真空钎焊提供参考。

     

Expression Patterns and Gonadotropin Regulation of the TGF-β II Receptor (Bmpr2) during Ovarian Development in the Ricefield Eel Monopterus albus

Bmpr2 plays a central role in the regulation of reproductive development in mammals, but its role during ovarian development in fish is still unclear. To ascertain the function of bmpr2 in ovarian development in the ricefield eel, we isolated and characterized the bmpr2 cDNA sequence; the localization of Bmpr2 protein was determined by immunohistochemical staining; and the expression patterns of bmpr2 in ovarian tissue incubated with FSH and hCG in vitro were analyzed. The full-length bmpr2 cDNA was 3311 bp, with 1061 amino acids encoded. Compared to other tissues, bmpr2 was abundantly expressed in the ovary and highly expressed in the early yolk accumulation (EV) stages of the ovary. In addition, a positive signal for Bmpr2 was detected in the cytoplasm of oocytes in primary growth (PG) and EV stages. In vitro, the expression level of gdf9, the ligand of bmpr2, in the 10 ng/mL FSH treatment group was significantly higher after incubation for 4 h than after incubation for different durations. However, bmpr2 expression in the 10 ng/mL FSH treatment group at 2 h, 4 h and 10 h was significantly lower. Importantly, the expression level of bmpr2 and gdf9 in the 100 IU/mL hCG group had similar changes that were significantly decreased at 4 h and 10 h. In summary, Bmpr2 might play a pivotal role in ovarian growth in the ricefield eel, and these results provide a better understanding of the function of bmpr2 in ovarian development and the basic data for further exploration of the regulatory mechanism of gdf9 in oocyte development.     

Cryogenic 3D Printing of w/o Pickering Emulsions Containing Bifunctional Drugs for Producing Hierarchically Porous Bone Tissue Engineering Scaffolds with Antibacterial Capability

How to fabricate bone tissue engineering scaffolds with excellent antibacterial and bone regeneration ability has attracted increasing attention. Herein, we produced a hierarchical porous β-tricalcium phosphate (β-TCP)/poly(lactic-co-glycolic acid)-polycaprolactone composite bone tissue engineering scaffold containing tetracycline hydrochloride (TCH) through a micro-extrusion-based cryogenic 3D printing of Pickering emulsion inks, in which the hydrophobic silica (h-SiO₂) nanoparticles were used as emulsifiers to stabilize composite Pickering emulsion inks. Hierarchically porous scaffolds with desirable antibacterial properties and bone-forming ability were obtained. Grid scaffolds with a macroscopic pore size of 250.03 ± 75.88 μm and a large number of secondary micropores with a diameter of 24.70 ± 15.56 μm can be fabricated through cryogenic 3D printing, followed by freeze-drying treatment, whereas the grid structure of scaffolds printed or dried at room temperature was discontinuous, and fewer micropores could be observed on the strut surface. Moreover, the impartment of β-TCP in scaffolds changed the shape and density of the micropores but endowed the scaffold with better osteoconductivity. Scaffolds loaded with TCH had excellent antibacterial properties and could effectively promote the adhesion, expansion, proliferation, and osteogenic differentiation of rat bone marrow-derived mesenchymal stem cells afterward. The scaffolds loaded with TCH could realize the strategy to “kill bacteria first, then induce osteogenesis”. Such hierarchically porous scaffolds with abundant micropores, excellent antibacterial property, and improved bone-forming ability display great prospects in treating bone defects with infection.