VO2·0.2H2O nanocuboids anchored onto graphene sheets as the cathode material for ultrahigh capacity aqueous zinc ion batteries

Aqueous Zinc-ion batteries (ZIBs), using zinc negative electrode and aqueous electrolyte, have attracted great attention in energy storage field due to the reliable safety and low-cost. A composite material comprised of VO₂·0.2H₂O nanocuboids anchored on graphene sheets (VOG) is synthesized through a facile and efficient microwave-assisted solvothermal strategy and is used as aqueous ZIBs cathode material. Owing to the synergistic effects between the high conductivity of graphene sheets and the desirable structural features of VO₂·0.2H₂O nanocuboids, the VOG electrode has excellent electronic and ionic transport ability, resulting in superior Zn ions storage performance. The Zn/VOG system delivers ultrahigh specific capacity of 423 mAh·g⁻¹ at 0.25 A·g⁻¹ and exhibits good cycling stability of up to 1,000 cycles at 8 A·g⁻¹ with 87% capacity retention. Systematical structural and elemental characterizations confirm that the interlayer space of VO₂·0.2H₂O nanocuboids can adapt to the reversible Zn ions insertion/extraction. The as-prepared VOG composite is a promising cathode material with remarkable electrochemical performance for low-cost and safe aqueous rechargeable ZIBs.

     

稀土永磁电机研究现状与发展

介绍了稀土永磁电机结构特点、国内外应用现状以及技术发展趋势;并着重介绍了代表未来电机发展方向之一的稀土永磁无铁心电机的结构及应用、控制技术以及推广面临的问题.     

Additive manufacturing and foundry innovation

Additive manufacturing is expected to transform and upgrade the traditional foundry industry to realize the integrated manufacturing and rapid and low-cost development of high-performance components with complex shapes. The additive manufacturing technology commonly applied in casting mold preparation (fusible molds, sand molds/cores and ceramic cores) mainly includes selective laser sintering (SLS) and binder injection three-dimensional printing (3DP). In this work, the research status of SLS/3DP-casting processes on material preparation, equipment development, process optimization, simulation and application cases in aerospace, automotive and other fields were elaborated. Finally, the developing trends of the additive manufacturing technology in the future of foundry field are introduced, including multi-material sand molds (metal core included), ceramic core-shell integration and die-casting dies with conformal cooling runners.     

Effect of ultrasonic field treatment on degassing of 2024 alloy

The 2024 aluminum alloy was prepared with different ultrasonic processes. Effects of ultrasonic treatment parameters including ultrasonic power, treatment time, treatment temperature, and frequency resonance, as well as C₂Cl₆ degasser on degassing of the 2024 aluminum alloy were investigated. Results indicate that increasing ultrasonic power at the same ultrasonic treatment time can improve the degassing effect. The optimum degassing efficiency can be obtained under the resonant ultrasound condition. With the combination of 1% C₂Cl₆ addition and 150 W ultrasonic treatment for 40 s, the hydrogen content of the alloy is decreased by 52.9%. At the same time, the tensile strength and elongation are increased by 28.3% and 92.3%, respectively, and the yield strength is slightly increased by 6.7%. The degassing mechanism is also discussed.

     

A Visual Lossless Image-Recompression Framework

In this paper, we propose a novel image recompression frame?work and image quality assessment (IQA) method to efficient?ly recompress Internet images. With this framework image size is significantly re...     

计算机技术在企业经济管理中的应用探析

随着科学技术的发展,计算机技术现在已经广泛的应用在各行各业中,在企业办公、广告设计等领域中的应用,大大的提升了工作效果以及工作质量。在企业经济管理中,计算机技术具有有重要的意义和优势,为此本文针对企业的经济管理现状、计算机技术在企业经济管理中应用的意义、优势等内容进行分析,通过对当前企业经济管理存在的问题、现状等进行研究,结合计算机技术的应用优势,得出计算机技术在企业经济管理中的应用策略,希望可以全面准确的提升企业经济管理质量,并广泛的应用计算机技术。     

棒线材连轧过程张力计算模型研究和运用

张力控制是棒线材连轧过程的关键技术,在无活套的粗中轧区域采用微张力轧制可以确保产品公差稳定。实现微张力轧制控制,需要能定性的判定连轧过程各道次之间张力大小或者变化趋势。为实现该目的,对棒线材连轧过程张力的计算模型进行研究,并通过PLC运算,将最佳张力计算模型运用到直条圆钢生产中,实现粗中轧微张力轧制的监控,提高产品精度。     

Kinetics of drug release from drug carrier of polymer/TiO2 nanotubes composite—pH dependent study

This study was to investigate the kinetics of drug release from polymer/TiO₂ nanotubes composite. Lidocaine and carprofen were selected as model drugs to represent weak base and weak acid drugs, respectively. Mathematical models used to fit the in vitro drug release experimental data indicate that at higher pH, the drug release was first order diffusion controlled. At lower pH, the release of the two drugs exhibits two staged controlled release mechanism. The first phase is due to drug diffusion and the second stage is a result of poly(lactic‐co‐glycolic acid) (PLGA) polymer degradation. The rate of drug release from polymer/TiO₂ nanotubes drug carrier was mainly controlled by three pH dependent factors: the solubility of the drug, the degree of polymer swelling/degradation, and the electrostatic force between polymer and drug. This study suggests that controlled release could be achieved for polymer/TiO₂ nanotubes drug carrier via the modulation of pK_a values of polymers and drug solubility. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 41570.     

Preparation,swelling properties,and displacement performance of functional amphiphilic microspheres

Because polymers containing benzyl chloromethyl groups are easily modified for functional production, the dispersion polymerization of acrylamide, 4‐vinylbenzyl chloride, and N,N‐methylene bisacrylamide in dimethylformamide initiated with α,α‐azobisisobutyronitrile was carried out to produce amphiphilic microspheres containing benzyl chloromethyl groups. The structure of the amphiphilic microspheres was determined by IR and ¹H‐NMR spectroscopy. The polymerization conditions, the temperature, amount of crosslinking agent, and initiator included, were optimized. The size distribution of the microspheres after swelling equilibrium ranged from 4 to 62 μm. The swelling behavior of the microspheres was also investigated. The increase in temperature and the decrease in salinity caused a gradual increase in the swelling ratio. The prepared microspheres were transported uniformly in porous media when the permeability was 0.436 μm². The oil displacement experiments indicated that amphiphilic microspheres had the ability to enhance oil recovery under homogeneous and heterogeneous conditions but was more suitable for heterogeneous formation. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 41578.