The effect of end groups of PEG on the crystallization behaviors of binary crystalline polymer blends PEG/PLLA

The effect of end groups (2OH, 1OH, 1CH₃ and 2CH₃) of poly(ethylene glycol) (PEG) on the miscibility and crystallization behaviors of binary crystalline blends of PEG/poly(l-lactic acid) (PLLA) were investigated by differential scanning calorimetry (DSC) and polarizing optical microscopy (POM). A single glass-transition temperature was observed in the DSC scanning trace of the blend with a weight ratio of 10/90. Besides, the equilibrium melting point of PLLA decreased with the increasing PEG. A negative Flory interaction parameter, χ₁₂, indicated that the PEG/PLLA blends were thermodynamically miscible. The spherulitic growth rate and isothermal crystallization rate of PEG or PLLA were influenced when the other component was added. This could cause by the change of glass transition temperature, T_g and equilibrium melting point, T⁰_m. The end groups of PEG influenced the miscibility and crystallization behaviors of PEG/PLLA blends. PLLA blended with PEG whose two end groups were CH₃ exhibited the greatest melting point depression, the most negative Flory interaction parameter, the least fold surface free energy, the lowest isothermal crystallization rate and spherulitic growth rate, which meant better miscibility. On the other hand, PLLA blended with PEG whose two end groups were OH exhibited the least melting point depression, the least negative Flory interaction parameter, the greatest fold surface free energy, the greatest isothermal crystallization rate and spherulitic growth rate.     

Windows Server操作系统课程教学模式改革探索

从Windows Server操作系统课程的教学现状出发,提出了在Windows Server操作系统课程的教学中引入项目驱动教学模式及设计原则,并阐述了此模式下具体的教学环节设计,为Windows Server操作系统课程的教学在计算机网络技术专业技能训练与职业能力培养方面提供了新的视角,具有一定的实用和推广意义。     

纳米材料的制备进展

介绍了目前国内外纳米材料的物理和化学制备方法，介绍了纳米材料的研究新进展和纳米材料的开发和应用前景。     

基于VB的球面网壳施工控制系统设计

根据球面网壳的施工特点,采用VB6.0编制了球面网壳施工控制系统。根据系统的数据特点,采用MicrosoftExcel作为数据库。使用OLE控件调用AutoCAD软件,绘制三维结构模型图。使用Image控件和Line控件设计工具栏。系统根据施工误差对施工时可能出现的问题进行预警,有利于提高球面网壳的施工质量。     

Spherical Aluminum Nitride Fillers for Heat-Conducting Plastic Packages

It is necessary for encapsulants to have not only a suitable coefficient of thermal expansion (CTE) compatible to IC devices and a low dielectric constant to reduce the device propagation delay, but also a high thermal conductivity to dissipate large amounts of heat from power-hungry, high-speed IC and high-density packages. Fillers such as silica have been mixed with polymers to improve their properties. Aluminum nitride (AlN) is considered as an alternative one, because it has a higher theoretical thermal conductivity of ∼320 W/mK¹, a compatible CTE with silicon chips and a low dielectric constant. Commercial AlN fillers are angular in shape, because they are prepared via grinding coarse AlN powders synthesized by direct nitridation of aluminum metal and classification. The angular AlN are not expected to have high fluidity when mixed with polymers and hence low packing density. Recently, we successfully obtained single-crystalline spherical AlN fillers. Furthermore, polymer composites filled with the spherical AlN showed excellent thermal conductivity (>8 W/mK) as encapsulants for dissipating the heat generated in electronic devices.     

浅析无线网现状及相关技术

无线网作为一种现代化的技术手段,随着网络信息技术的不断发展完善,在实际中的应用越来越广泛和普遍,对于无线网技术的研究与关注内容也越来越多,进行无线网现状以及相关技术的研究分析,有利于促进无线网在实际应用中的改进和提升,具有积极的作用和意义。下文将结合无线网在实际网络通信传输中的应用现状,以网络建设中的安全管理为例,对其安全保护现状以及存在的问题、解决措施等进行分析论述。     

Study of the miscibility and crystallization behavior of poly(ethylene oxide)/poly(vinyl alcohol) blends

The miscibility and crystallization behavior of poly(ethylene oxide)/poly(vinyl alcohol) (PEO/PVA) blends were investigated by differential scanning calorimetry (DSC), dynamic mechanical analysis (DMA), and polarizing optical microscopy. Because the glass‐transition temperature of PVA was near the melting point of PEO crystalline, an uncommon DSC procedure was used to determine the glass‐transition temperature of the PVA‐rich phase. From the DSC and DMA results, two glass‐transition temperatures, which corresponded to the PEO‐rich phase and the PVA‐rich phase, were observed. It was an important criterion to indicate that a blend was immiscible. It was also found that the preparation method of samples influenced the morphology and crystallization behaviors of PEO/PVA blends. The domain size of the disperse phase (PVA‐rich) for the solution‐cast blends was much larger than that for the coprecipitated blends. The crystallinity, spherulitic morphology, and isothermal crystallization behavior of PEO in the solution‐cast blends were similar to those of the neat PEO. On the contrary, these properties in the coprecipitated blends were different from those of the neat PEO. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 92: 1562–1568, 2004     

Comprehensive assessment on dynamic roof instability under fractured rock mass conditions in the excavation disturbed zone

The damage process of fractured rock mass showed that the fracture in rocks induced roof collapse in Yangchangwan Coal Mine,China.The rock mass was particularly weak and fractured.There occurred 6 large-scale dynamical roof falls in the excavation disturbed zone (EDZ) with the collapsing volume of 216 m3.First,the field detailed geological environment,regional seismic dy-namics,and dynamic instability of roadways were generally investigated.Second,the field multiple-index monitoring measurements for detecting the deep delamination of the roof,convergence deformation,bolt-cable load,acoustic emission (AE) characteristic pa-rameters,total AE events,AE energy-releasing rate,rock mass fracture,and damage were arranged.Finally,according to the time-space-strength relations,a quantitative assessment of the influence of rock-mass damage on the dynamic roof instability was accomplished.     

Synthesis and characterization of CdS nanocrystals embedded on solid electrolyte films

In this article nano‐sized CdS crystal embedded in a PEO matrix was successfully prepared by a complex transformation method that is universal for preparing nanosized compounds containing transition metals. The size of embedded CdS particles was in the nanoscale from 2 to 10 nm determined by X‐ray diffusion. The nanosized CdS displayed the expected blue shift of the onset absorbance in the UV spectrum. The amount of blue shift depends upon the dipping time of the PEO–cadmium complex film in a sodium sulfide solution as well as its concentration. The most effective means for adjusting the size of CdS nanocrystals is to change the ratio of the oxygen along with the PEO chain to the cadmium ion in the complex film. The alkali salt in the film would contribute to the conductivity of the composite film. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 84: 1263–1268, 2002; DOI 10.1002/app.10459     

三维编织复合材料编织工艺过程仿真研究

总结了四步编织工艺的运动规律。对纱线的空间坐标进行三次B样条曲线拟合得到拟合坐标;设计实现了纱线实体的静态模型算法,根据拟合坐标得到纱线空间网格坐标并建立了纱线实体的静态模型;实现了纱线轨迹的动态展示以及实体生成过程的动态展示;构建了GUI界面并编译成了可脱离Matlab环境的独立运行程序。