高效节能水力旋流器研究进展

综合介绍了国内外高效节能水力旋流器的研究进展,分析了影响旋流器分离性能和能耗的主要因素,介绍了针对不同问题提出的相应解决办法.对其迄今的研究成果进行了简要评述,并对其发展进行了展望。     

电化学界面处离子分布、静电势和ξ势的研究

Density functional theory is applied to predicting the structures and electrostatic potentials of planar electrochemical surfaces within the framework of the restricted primitive model where small ions are represented by charged hard spheres of equal diameter and the solvent is assumed to be a continuous dielectric medium. The hard-sphere contribution to the excess Helmholtz energy functional is evaluated using the modified fundamentalmeasure theory and the electrostatic contribution is obtained from the quadratic functional Taylor expansion using the second-order direct correlation function from the mean-spherical approximation. Numerical results for the ionic density profiles and the mean electrostatic potentials near a planar surface of various charge densities are in excellent agreement with molecular simulations. In contrast to the modified Gouy-Chapman theory, the present density functional theory correctly predicts the second layer formation and charge inversion of charged surfaces as observed in simulations and in experiments. The theory has also been tested with the zeta potentials of positively charged polystyrene particles in aqueous solutions of KBr. Good agreement is achieved between the calculated and experimental results.     

多媒体技术在英语教学中的应用

论文对多媒体技术在英语教学中的应用了做了分析,比较了多媒体技术使用和传统模式的英语教学的不同特点,突出了多媒体技术的使用给英语教学改革带来了巨大的推动作用,并且根据教学经验,提出了多媒体技术在英语教学中使用要注意的一些问题。     

浅析化工企业信息化建设中的问题和对策

加入WTO后,为了提高化工企业的核心竞争力,企业信息化建设已势在必行。本文简要介绍了我国化工企业目前在信息化建设中存在的主要问题以及应采取的对策。     

纳米尺度AgBr／Ⅰ乳剂颗粒的光电子衰减行为

本文以鱼明胶为保护介质,在不同的鱼明胶 溴化银比值下,采用双注法制备AgBr/I纳米颗粒乳剂,以TEM观测颗粒形态,据此统计得出该乳剂中AgBr/I纳米颗粒平均粒径(d)及粒径分布系数(|±σ|/d).鱼明胶 溴化银比值在0.31g/mmol—0.62g/mmol范围内,颗粒平均粒径仅有微小变化,但粒径分布系数随该比值的增大而减小,表明颗粒均一性提高.采用微波光导法对该纳米尺度AgBr/I乳剂颗粒的光电子衰减过程进行测试,结果表明,纳米尺度Ag Br/I乳剂颗粒的光电子衰减过程为双组分,即初始快衰减和随后慢衰减,其衰减过程皆符合一级动力学规律.该纳米尺度乳剂颗粒光电子寿命较常规乳剂颗粒明显缩短.     

Electrode–Ceramic Inter-Diffusion of Ba(Ti,Zr)O3-Based Y5V MLCCs with Ni Electrodes

The Ba(Ti,Zr)O₃-based multilayer ceramic capacitors (MLCCs) with Ni electrodes, which meet the Electronic Industry Association Y5V standard (from −30° to 85°C, at a temperature capacitance coefficient between −82% and 22%), have been studied in view of the electrode-ceramic inter-diffusion by several microstructual techniques (scanning electron microscopy/transmission electron microscopy/high-resolution transmission electron microscopy (HRTEM)) with an energy-dispersive X-ray spectrometer (EDS). The EDS analysis shows that the elements' inter-diffusion took place along the metal–dielectric interface and the migration of Ni toward the dielectric layers dominated this process. The incorporation of Ni did not transform the crystal structure but introduced lattice distortions, which were characterized by HRTEM, X-ray diffraction, and EDS. The degree of Ni diffusion in the sample with the thinner dielectric layer was more severe. It was concluded from the results that the Ni diffusion is related to the formation of oxygen vacancies after the annealing process, which should be a noticeable factor in the degradation behavior and reliability of base metal electrode MLCCs. The factors influencing the inter-diffusion are also discussed.     

金属离子掺杂二氧化钛及水体光催化脱氮研究

采用溶胶-凝胶法制备了掺杂Ce^3＋、La^3＋、Ag^＋、Fe^3＋的TiO2光催化剂，以考察其薄膜和粉体形式对水中无机氮的光催化去除效果和活性．用所制备的催化剂对含氨氮-亚硝酸氮的混合液进行了光催化脱氮研究．本文利用UV—Vis吸收光谱、XRD和TEM对催化剂进行了表征．同时，对影响TiO2光催化效率的因素：如掺杂金属离子的种类、浓度、涂膜层数、反应液中有无Fe^2＋、不锈钢和玻璃载体、反应器的构型等进行了探讨，并对今后的研究进行展望．经过2h紫外光照射反应，实验最佳脱氮效果：金属离子掺杂TiO2薄膜型催化剂总氮去除率在30％左右，金属离子掺杂粉末型催化剂光催化最高总氮去除率可达41．7％．     

流化床电化学反应器研究进展

流化床电化学反应器是一种三维颗粒电极反应器,以其比表面积大、传质速率高而备受关注。就流化床电化学反应器在导电机理、数学模型、结构放大以及应用领域的研究现状和进展进行了综述,阐明了该类反应器开发、设计和模型化方面存在的问题,并提出了研究方向。     

细长钢管内壁涂塑工艺

采用流化床和热喷涂方法喷涂直径小于２０ｍｍ的长钢管内壁。叙述了工艺过程和涂层检测方法。     

PVC基热塑性弹性体的制备

采用机械共混法制备PVC基弹性体，研究了聚合物的质量配比、增塑剂的用量及增塑剂的配合使用对体系性能的影响，并考察了填料对体系性能的影响。结果表明，通过不同的聚合物质量配比、增塑剂的选择以及不同填料的选用，可制得不同性能的热塑性弹性体。