Application of electrometric technique in the kinetic study of iodination of cinnamaldehyde and furfuraldehyde with hydrated monopositive iodine

The kinetic study of the iodination of cinnamaldehyde and furfuraldehyde with hydrated monopositive iodine, produced by the interaction of aqueous I₂ solution and Ag⁺ at μ = 0.3 (NaClO₄) was followed potentiometrically by using platinum gauge and saturated calomel electrode assembly. The reactions are of the first order with respect to both the substrate concentration (cinnamaldehyde and furfuraldehyde). They are also first order with respect to hydrated monopositive iodine, the iodinating agent. The reactions are independent of [Ag⁺] and [H⁺] in the solution in which the reactions have been studied.     

Effect of Cu and Li Contents on the Serrated Flow Behavior of Al-Cu-Li Based Alloys

Metallurgical and Materials Transactions A - The serrated flow behavior of Al-Li, Al-Cu and Al-Cu-Li alloys was studied in solution-treated condition under a range of strain rates at ambient...     

Sub-zero Temperature Dependence of Tensile Response of Friction Stir Welded Al-Cu-Li (AA2198) Alloy

Mechanical properties at ambient and cryogenic temperatures of Al-Cu-Li alloy are required for design and fabrication of liquid hydrogen and liquid oxygen tanks of satellite launch vehicles. In the present work, bead-on-sheet, friction stir welding was carried out with three different rotation speeds. The yield and strain hardening behaviors of the welds were evaluated in temperature range of 20 K to 298 K. Both yield stress and strain hardening ability in the specimen increased with decrease in testing temperature. The dependence of yield stress on temperature was modeled on the basis of thermally activated dislocation mobility, while that of strain hardening was modeled on the temperature dependence of dynamic recovery rate parameter. The recovery parameter followed an Arrhenius-type relationship with temperature. The model parameters determined from the experimental data were further used to simulate the stress–strain curves at different sub-zero temperatures for the friction stir welds.

     

α‐l‐Rhamnosidase from Aspergillus flavus MTCC‐9606 isolated from lemon fruit peel

An α‐l ‐rhamnosidase producing fungal strain has been isolated from decaying lemon fruit. The fungal strain has been identified as Aspergillus flavus. The α‐l ‐rhamnosidase has been purified from the culture filtrate of the fungal strain using ultra filtration and cation exchange chromatography on carboxy methyl (CM) cellulose. The molecular mass of the purified enzyme determined by SDS–PAGE analysis was 41 kDa. The K_m values of the enzyme using p‐nitrophenyl‐α‐l ‐rhamnopyranoside and naringin as the substrates were 1.89 and 1.6 mm respectively. The pH and temperature optima of the enzyme were 11.0 and 50 °C respectively. The effects of various chemical species present in grape fruit juice and wine on the activity of the enzyme have been determined.     

Deformation behaviour of Al–Cu–Li alloy containing T1 precipitates

In the present work, a systematic investigation of crystallographic texture evolution and strain hardening behaviour was undertaken to comprehend the deformation behaviour in the presence of T₁ (Al₂CuLi) precipitates. Characteristic texture components symbolising multiple slip condition such as Copper and S were observed upon rolling which is in contrast with other Al alloys containing shearable precipitates. Strain hardening ability was also observed to be remarkably high in the presence of T₁ precipitates. The texture and strain hardening results are compared with another age hardenable Al alloy (Al–Mg–Si alloy) containing shearable precipitates to clearly bring out the difference in the nature of T₁ precipitates.     

Modeling and simulation of cylindrical electro-chemical magnetic abrasive machining of AISI-420 magnetic steel

The objective of the present research is to simulate cylindrical electro-chemical magnetic abrasive machining (C-EMAM) process for magnetic stainless steel (AISI-420). C-EMAM is a new hybrid machining process used for high efficiency finishing of cylindrical jobs made of advanced engineering materials. The material is removed from the workpiece surface due to simultaneous effect of abrasion and electrochemical dissolution. Finite element method is used to calculate the distribution of magnetic field between the magnetic poles in which cylindrical shaped workpiece is placed. The cutting forces responsible for abrasion are calculated from the magnetic forces due to gradient of magnetic field in the working gap. The effect of electrochemical dissolution and abrasion-assisted dissolution are incorporated into the C-EMAM process model using empirical relation for average anodic current. The empirical relation is correlated with the input parameters in the present system based on experimental results. Finally a surface roughness model is developed by considering total volume of material removed with the assumption of triangular surface profile. The simulation results for material removal and surface roughness are validated using experimental results. The simulated results agree with experimental observations.     

Equivalent refractive index of multilayer films of different materials

The variation of the equivalent refractive index with composition of multilayer films of ZnS-MgF₂-SiO, ZnS-Na₃AlF₆ and Ge-ZnS, prepared by depositing alternate layers of different materials, has been investigated. It has been established that, for small step thicknesses (much less than the wavelength of light to be used for measurements) of each layer, the composite multilayer films are optically equivalent to homogeneously mixed films of the same materials of corresponding relative compositions. Further, the results show that the indices of the multilayer films of ZnS-MgF₂-SiO and ZnS-Na₃AlF₆ are in good agreement with the values predicted on the basis of the Lorentz-Lorenz theory. The refractive index of Ge-ZnS multilayer films is in agreement with the Drude theory. Our studies also show that the refractive index of a multilayer film composed of three materials, two of which react chemically in the molten and vapour states, as, for example, ZnS and SiO in ZnS-MgF₂-SiO films, is equivalent to that expected theoretically for a homogeneously mixed film of the same materials. The controlled and predictable equivalent behaviour of multilayer films suggests their use to produce variable refractive index optical coatings by selecting any number of materials which may or may not react with each other chemically.