不锈钢丝包芯纱针织物电磁屏蔽性能研究

采用涤纶长丝、棉粗纱和超细316L不锈钢丝在HN32-04型棉纺花式捻线机上纺制不锈钢丝包芯纱,并在龙星LXC-252SCV型电脑横机上编织纬平针织物及浮线添纱针织物。介绍纺纱原理及编织工艺,并测试不锈钢丝包芯纱的拉伸性能以及针织物的电磁屏蔽效能。结果表明,不锈钢丝包芯纱的平均拉伸断裂强力为38.96 N,位移为124.30 mm,其拉伸过程分为不锈钢丝断裂、纱线中纤维抽拔、纱线断裂过程。随着电磁波频率的不断增强,纬平针织物和浮线添纱针织物的电磁屏蔽效能下降。针织物结构不同,织物紧密程度和线圈大小不同,对不同频段电磁波的屏蔽能力也不同。     

Isolation and identification of two major acylated anthocyanins from purple sweet potato (Ipomoea batatas L. cultivar Eshu No. 8) by UPLC‐QTOF‐MS/MS and NMR

In recent years, researches on the isolation and preparation of monomeric anthocyanins have intensified because of the requirements of quantitative and structure–bioactivity relationship analyses. However, simple and effective methods about the scale of monomeric anthocyanins from the natural purple sweet potato powder are rarely reported. In this study, high molecular weight acylated monomeric anthocyanins were isolated from purple sweet potato (Ipomoea batatas L. cultivar Eshu No. 8) via the combination of column chromatography and semi‐preparative HPLC technology and identified mainly by ultra‐high‐performance liquid chromatography quadrupole time‐of‐flight tandem mass spectrometry/mass spectrometry (UPLC‐QTOF‐MS/MS) and ¹H and ¹³C nuclear magnetic resonance (NMR). Two major acylated anthocyanins were unambiguously determined as peonidin 3‐O‐(6‐O‐(E)‐caffeoyl‐(2‐O‐(6‐O‐p‐hydroxybenzoyl)‐β‐D‐glucopyranosyl)‐β‐D‐glucopyranoside)‐5‐O‐(β‐D‐glucopyranoside) and peonidin 3‐O‐(6‐O‐(E)‐caffeoyl‐(2‐O‐(6‐O‐(E)‐feruloyl)‐β‐D‐ glucopyranosyl)‐β‐D‐glucopyranoside)‐5‐O‐(β‐D‐glucopyranoside). The results of this study may help promote the purification of high molecular weight acylated anthocyanins from purple sweet potato as well as from other plant materials in nature.     

基于弧形电容器的浆纱回潮率在线测量

为提高上浆质量以及解决使用接触式电阻含水率测量仪会破坏浆膜的问题,设计开发了基于弧形电容器的浆纱回潮率在线测量系统。根据浆纱在弧形电容器中的电场模型和电容法测量原理,利用指数回归算法建立电容差与回潮率的函数模型。上浆时,浆纱穿过弧形电容器,电感、电容、电阻(LCR)电桥测试仪将测量的电容值数据传到上位机,上位机根据模型计算出实时浆纱回潮率。讨论了弧形电容器结构、LCR电桥测试仪测试参数、环境温湿度、浆液含固率、浆纱线密度、回潮率对测量电容值的影响。实验结果表明：电容值受LCR电桥测试仪测试频率的影响较大;电容值随电容器结构参数极板长度、极板包角的增大而增大,与极板曲率半径呈负相关;环境温湿度会对电容值产生复杂影响,因此要求在恒温恒湿条件下进行测量;浆纱回潮率对电容值的影响显著,且回潮率与电容差呈指数函数关系。在上浆机上使用电容式回潮率在线检测系统进行测试,得到的浆纱回潮率与烘箱法测量结果相比平均误差小于5%,本文系统具有一定的工程实用价值。     

Preparation of a Novel Thermoplastic Starch (TPS) Material using Ethylenebisformamide as the Plasticizer

In this paper, ethylenebisformamide was synthesized and used as a novel plasticizer for corn starch to prepare thermoplastic starch (EPTPS). FT‐IR spectra showed that the absorption bands of the C‐O groups of the starch molecules were shifted to lower wavenumbers, which indicated that a strong and stable hydrogen bond had been formed between ethylenebisformamide and starch. By scanning electron microscope (SEM) native individual corn starch granules were proved to transfer to a continuous phase. The crystallinity of native corn starch, GPTPS (glycerol plasticized corn starch) and EPTPS was characterized by X‐ray diffraction (XRD). Water resistance of EPTPS was better than that of GPTPS. It decreased from 50.2% for GPTPS to 37.8% for EPTPS. The mechanical analysis showed that elongation at break increased markedly, being 260% for the EPTPS containing 35% (w/w) ethylenebisformamide. Thermal stability of GPTPSs and EPTPSs was also determined by thermogravimetric analysis (TGA). The glass transition temperature T_g, as measured by dynamic mechanical thermal analysis (DMTA), of EPTPS was higher than that of GPTPS.     

实木地板基材选用方法研究

以3种树种为例探讨了选用实木地板基材时需要检测的项目,以期提出一种较为实用的实木地板基材选用方法。     

具有双层效果的提花-印花-剪花织物的设计

为给多重效果组合的织物提供创新设计思路,针对提花-印花织物效果单一,且现有的提花-印花织物设计方法无法适用于剪花、烂花等特殊工艺面料设计的问题,将双层效果提花织物、提花-印花织物与剪花织物的设计方法相结合,提出具有双层效果的提花-印花-剪花织物的设计原理和方法。将目标织物分为提花层、印花层和剪花层3个部分,从图案色彩和组织结构2个方面进行设计分析,提出可行性技术方案。研究结果表明:在提花-印花的基础上,可实现具有双层效果的提花-印花-剪花结合织物的设计,并可构建起提花-印花-剪花织物的设计体系,使织物集双层、织花、印花和剪花4种效果于一体,在织物表面呈现4种静态、3种动态的丰富组合效果。     

红曲菌Monacolin K合成基因的研究进展

聚酮化合物Monacolin K是一种高效的降胆固醇药物,由红曲菌和土曲霉次级代谢产生。早期以土曲霉为研究对象,揭示了相关的生物合成基因簇及其功能。近年来的研究发现,虽然Monacolin K在这2种产生菌中的生物合成途径完全相同,但红曲菌中Monacolin K相关的生物合成基因和土曲霉并不完全一致。对红曲菌功能基因组的深入研究,以及相应遗传转化体系的建立与完善,对进一步开发生产更多的聚酮化合物必将出现新的契机。     

纬编复合防刺织物的防刺性能研究

详细介绍纬编复合防刺织物的设计理念、设计方法、防刺性能测试及防刺性能研究。结果表明,单一的传统纬编织物、纬编双轴向织物、机织物以及无纺布等均可用于防刺织物,但经过复合设计之后,不但可以充分利用各种结构织物的性能优势,而且其防刺性能也得到有效提高,同时减轻产品质量。