Development of a universal modeling tool for rechargeable lithium batteries

An interesting universal modeling tool for rechargeable lithium batteries is presented in this paper. The generic model is based on an equivalent circuit technique commonly used in electrochemical impedance characterization. Therefore, the parameters used in the model can be easily parameterized from the electrochemical impedance derivations, which provide a convenient integration with experimental cell characterizations. Such integration offers the universality in this modeling approach.     

Model independent assertions for integration of heterogeneous schemas

Due to the proliferation of database applications, the integration of existing databases into a distributed or federated system is one of the major challenges in responding to enterprises' information requirements. Some proposed integration techniques aim at providing database administrators (DBAs) with a view definition language they can use to build the desired integrated schema. These techniques leave to the DBA the responsibility of appropriately restructuring schema elements from existing local schemas and of solving inter-schema conflicts. This paper investigates theassertion-based approach, in which the DBA's action is limited to pointing out corresponding elements in the schemas and to defining the nature of the correspondence in between. This methodology is capable of: ensuring better integration by taking into account additional semantic information (assertions about links); automatically solving structural conflicts; building the integrated schema without requiring conforming of initial schemas; applying integration rules to a variety of data models; and performing view as well as database integration. This paper presents the basic ideas underlying our approach and focuses on resolution of structural conflicts.     

Analytical models of composite material drilling

Drilling of composite material structures is widely used for aeronautical assemblies. When drilling, damage to the composite laminate is directly related to the cutter geometry and the cutting conditions. Delamination of the composite materials at the hole exit as directly related to the axial force (F _Z) of the cutter is considered to be the major such defect. To address this issue, an orthotropic analytical model is developed in order to calculate the critical force of delamination during drilling and a number of hypotheses for loading are proposed. This critical axial load is related to the delamination conditions (propagation of cracks in the last layers) and the mechanical characteristics of the composite material machined. A numerical model is also drawn up to allow for numerical validation of the analytical approach. A comparison between these analytical and numerical modellings and experimental results from quasi-static punch tests led to the choice of the loading hypothesis closest to the experimental conditions. The selection of corresponding load permits to model the drilling critical thrust force on delamination and then to optimise the cutting conditions. The dimensions and geometrical shape of the cutter are of considerable importance when it comes to choosing this load. The present article focuses on the case of the twist drill, which is commonly used to drill thick plates. However, this work can be adapted to different cutter geometries.     

Inductive modeling of lithium-ion cells

Sandia National Laboratories has conducted a sequence of studies on the performance of lithium ion and other types of electrochemical cells using inductive models. The objectives of some of these investigations are: (1) to develop procedures to rapidly determine performance degradation rates while these cells undergo life tests; (2) to model cell voltage and capacity in order to simulate cell output under variable load and temperature conditions; (3) to model rechargeable battery degradation under conditions of cyclic charge/discharge, and many others. Among the uses for the models are: (1) to enable efficient predictions of battery life; (2) to characterize system behavior.

Inductive models seek to characterize system behavior using experimentally or analytically obtained data in an efficient and robust framework that does not require phenomenological development. There are certain advantages to this. Among these advantages is the ability to avoid making measurements of hard to determine physical parameters or having to understand cell processes sufficiently to write mathematical functions describing their behavior. We have used artificial neural networks (ANNs) for inductive modeling, along with ancillary mathematical tools to improve their accuracy.

This paper summarizes efforts to use inductive tools for cell and battery modeling. Examples of numerical results are presented.     

Synthesis and magnetic properties of an iron 1,2-bisthienyl perfluorocyclopentene photochromic coordination compound

The coordination compound Fe(BM-4-PTP)₂(NCS)₂⋅2MeOH (1) including the photoisomerizable ligand BM-4-PTP (1,2-bis(2′-methyl-5′-(pyrid-4″-yl)thien-3′-yl)perfluorocyclopentene) was obtained as an orange powder. The powder turns blue upon photocyclization of the 1,2-bisthienyl photochromic ligand induced by UV light irradiation at room temperature. Photocycloreversion is obtained by visible light irradiation of the material in the solid state. The orange and blue powders were investigated over the temperature range (5-293 K) and pressure range (1 bar-12 kbar) by magnetic susceptibility measurements and variable temperature ⁵⁷Fe Mössbauer spectroscopy. The photo-induced colour change is accompanied by a distinct magnetic variation at room temperature. Potentialities of this functional optical material for display and data recording are introduced.     

Study on the transformer equivalent circuit of eddy current nondestructive evaluation

The modeling of a practical configuration of nondestructive evaluation (NDE) by eddy currents (EC) generally requires extended analytical or numerical developments. This is a drawback to any understanding of the EC NDE principle and of its basic features. Nevertheless, it is possible to exploit a simple equivalent circuit based on an analogy with the operation of an electrical transformer. In this model the EC sensor constitutes the primary of the transformer whereas the evaluated conductive plate forms the transformer secondary and its electrical load. In this paper, thanks to the transformer analogy, the author obtains a simple analytical expression of the impedance of the EC sensor by using a distributed constant representation of the evaluated plate. This expression allows to exhibit some fundamental features of the EC NDE method.     

NX210c Peptide Promotes Glutamatergic Receptor-Mediated Synaptic Transmission and Signaling in the Mouse Central Nervous System

NX210c is a disease-modifying dodecapeptide derived from the subcommissural organ-spondin that is under preclinical and clinical development for the treatment of neurological disorders. Here, using whole-cell patch-clamp recordings, we demonstrate that NX210c increased α-amino-3-hydroxy-5-methyl-4-isoxazolepropionic acid receptor (AMPAR)- and GluN2A-containing N-methyl-D-aspartate receptor (GluN2A-NMDAR)-mediated excitatory postsynaptic currents in the brain. Accordingly, using extracellular field excitatory postsynaptic potential recordings, an enhancement of synaptic transmission was shown in the presence of NX210c in two different neuronal circuits. Furthermore, the modulation of synaptic transmission and GluN2A-NMDAR-driven signaling by NX210c restored memory in mice chronically treated with the NMDAR antagonist phencyclidine. Overall, by promoting glutamatergic receptor-related neurotransmission and signaling, NX210c represents an innovative therapeutic opportunity for patients suffering from CNS disorders, injuries, and states with crippling synaptic dysfunctions.