Modular Functionalization of Electrodes by Cross‐Coupling Reactions at Their Surfaces

Due to the increasing importance of modified electrodes for many applications in nanotechnology, including molecular electronics, bioelectronics, and sensors, there is a need to find ways to chemically attach suitable molecular films onto the electrodes. Combining the electroreduction of aryl diazonium salts with the Sonogashira cross‐coupling reaction, a new modular technique to modify electrodes is presented. The new technique allows a wide range of functional groups to be introduced onto electrode surfaces with high surface coverage by the functional subunit. Various organic subunits, including redox chromophores, are successfully attached to platinum electrodes. The corresponding films are characterized using cyclic voltammetry, X‐ray photoelectron spectroscopy, atomic force microscopy, and contact‐angle measurements. The electroreduction of diazonium salts is successfully achieved on a broad variety of conducting and semiconducting surfaces, which shows that the technique is applicable to a broad variety of substrates.     

Digital three-dimensional image correlation by use of computer-reconstructed integral imaging

We use integral images of a three-dimensional (3D) scene to estimate the longitudinal depth of multiple objects present in the scene. With this information, we digitally reconstruct the objects in three dimensions and compute 3D correlations of input objects. We investigate the use of nonlinear techniques for 3D correlations. We present experimental results for 3D reconstruction and correlation of 3D objects. We demonstrate that it is possible to perform 3D segmentation of 3D objects in a scene. We finally present experiments to demonstrate that the 3D correlation is more discriminant than the two-dimensional correlation.     

RF CMOS body-effect circuits

After a theoretical and analytical study of the body effect in MOS transistors, this paper offers two useful models of this parasitic phenomenon. Thanks to these models, a design methodology, which takes advantage of the bulk terminal, allows to turn this well-known body-effect drawback into an analog advantage, giving thus an efficient alternative to overcome the design constraints of the CMOS VLSI wireless mass market. To illustrate the approach, four RF building blocks are presented. First, a 0.9 V 10 dB gain LNA, covering a frequency range 1.8-2.4 GHz, thanks to a body-effect common mode feedback, is detailed. Secondly, a body-effect linearity controlled pre-power amplifier is presented exhibiting a 5 dB m input compression point (ICP1) variation under 1.8 V power supply for half the current consumption. Lastly, two mixers based on body-effect mixing are presented, which achieve a 10 dB conversion gain under 1.4 V for a −52 dB LO-to-RF isolation. Well suited for low-power/low-voltage applications, these circuits implemented in a 0.18 μm CMOS VLSI technology are dedicated to multi-standard architectures and system-on-chip implementations.     

Positive expiratory pressure as a method for preventing the impairment of attentional processes by hypoxia

This study investigated the effects of hypoxia on parallel/preattentional and serial/attentional processes in early vision, and the use of a positive-end-expiratory-pressure (PEEP) to prevent the impairment in performance. Twenty-one subjects were submitted to an 8-h hypoxia exposure in a hypobaric chamber (4500 m, 589 hPa, 22 degrees C), both with and without a 5-cm H2O PEEP. Subjects carried out a visual search task consisting of detecting a target among distractors in normoxia, in acute and in prolonged hypoxia. Conjointly their sensitivity to acute mountain sickness (AMS) was scored through the Lake Louise AMS scoring system. Results showed that prolonged hypoxia slowed serial/attentional processing whereas parallel/preattentional processes were not impaired either by acute or by prolonged hypoxia. PEEP prevented serial/attentional processes from slowing and those effects were more clearly observed in the AMS sensitive subjects with respect to the AMS insensitive subjects. These results suggest that the slowing induced by prolonged hypoxia is specific to an early visual process that pilots the scanning of an attentional spotlight throughout the visual field.     

Study and experimental validation of the calculation of the ECT signal induced by a minute crack using a FEM–BIM combination

A combination of the boundary integral (BIM) and finite element (FEM) methods is presented for the calculation of the signal induced by small cracks. This approach—by preserving the attractive properties of both methods—allows considering a large variety of probe structures while the computation time remains low, especially if the signal of a complete scan is calculated. To validate the calculation results, experiments are carried out using a large number of minute cracks. The good agreement obtained between the measured and calculated data shows the applicability of the presented method.     

PREDICTOL: a computer program to determine the thermophysiological duration limited exposures in various climatic conditions

PREDICTOL is a PC program used to determine the thermophysiological duration limited exposures (DLE) in humans, nude or clothed, submitted to various climatic conditions (hot and cold climates) at rest or during a physical exercise. DLE are determined following different standards of the International Standardization Organization (ISO), especially ISO 7933 for hot environment and ISO-TR 11079 for cold environment. The original aspect of this program is that it can be used whatever the climatic conditions. The program presents two modes: an educational interactive mode and a scenario mode. The educational interactive mode demonstrates the thermophysiological effects, expressed as DLE, of different parameter changes (temperature, humidity, wind speed, metabolic heat production by physical exercise, clothing insulation and water vapor permeability). The scenario mode determines DLE for given various linked sequences as encountered in occupational, military or even recreational activities, each sequence being characterized by its climatic conditions, physical activities performed and by physical clothing properties. DLE given by PREDICTOL are correlated to those obtained in various controlled climatic laboratory conditions (r = 0.86; P < 0.001). PREDICTOL is written in Visual Basic 6.0. A "help menu" is provided to explain the use of the program and give information concerning the equations used to calculate both the thermal balance and DLE.     

Preparation par transport en phase vapeur et caracterisation de monocristaux d' oxyde ternaire V1−xNbxOw(0 ⩽ x ⩽ 0,33)

Single crystals of V_1?xNb_xO₂ ternary oxide (0 ? x ? 0,33) are prepared by chemical transport using TeCl₄. The compositions are determined by thermogravimétric analysis under oxygen, X-ray diffraction measurements and evaluation of the insulator-metal transition temperature.     

A feasibility study on the use of anthropometric variables to make muscle–computer interface more practical

High classification accuracy has been achieved for muscle–computer interfaces (MCIs) based on surface electromyography (EMG) recognition in many recent works with an increasing number of discriminated movements. However, there are many limitations to use these interfaces in the real-world contexts. One of the major problems is compatibility. Designing and training the classification EMG system for a particular individual user is needed in order to reach high accuracy. If the system can calibrate itself automatically/semi-automatically, the development of standard interfaces that are compatible with almost any user could be possible. Twelve anthropometric variables, a measurement of body dimensions, have been proposed and used to calibrate the system in two different ways: a weighting factor for a classifier and a normalizing value for EMG features. The experimental results showed that a number of relationships between anthropometric variables and EMG time-domain features from upper-limb muscles and movements are statistically strong (average r=0.71?0.80) and significant (p<0.05). In this paper, the feasibility to use anthropometric variables to calibrate the EMG classification system is shown obviously and the proposed calibration technique is suggested to further improve the robustness and practical use of MCIs based on EMG pattern recognition.