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111.
Zihao Zhang Zirong He Nan Wang Fengmei Wang Chongyu Du Jiafeng Ruan Qin Li Dalin Sun Fang Fang Fei Wang 《Advanced functional materials》2023,33(27):2214648
Rechargeable aqueous zinc batteries are promising energy storage devices because of their low cost, high safety, and high energy density. However, their performance is plagued by the unsatisfied cyclability due to the dendrite growth and hydrogen evolution reaction (HER) at the Zn anode. Herein, it is demonstrated that the concentrated hybrid aqueous/non-aqueous ZnCl2 electrolytes constitute a peculiar chemical environment for not only the Zn-ions but also water molecules. The high concentration of chloride ions substitutes the H2O molecular in the solvation structure of Zn2+, while the acetonitrile further interacts with H2O to decrease its activity. The hybrid electrolytes both inhibit the dendrite formation and HER, enabling an ultrahigh average Coulombic efficiency of 99.9% in the Zn||Cu half-cell and a highly reversible Zn plating/stripping with a low overpotential of 21 mV. Using this hybrid electrolyte, the Zn||polytriphenylamine (PTPAn) full cell deliveres a high discharge capacity of 110 mAh g−1, a high power density of 9200 W kg−1 at 100 °C and maintains 85% of the capacity for over 6000 cycles at 10 °C. This study provides a deep understanding between the solvation structure and columbic efficiency of Zn anode, thus inspiring the development for stable Zn batteries. 相似文献
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纳秒激光加工石英微通道的实验与理论研究 总被引:1,自引:0,他引:1
利用调Q Nd…YAG激光器输出的1064nm纳秒脉冲激光聚焦在石英上,分别采用激光热加工法和激光诱导等离子体法加工微通道。热加工的通道长度可控,通道周围产生热裂纹;诱导等离子体加工的微通道内壁光滑,通道深度可达4mm。研究了激光热加工微通道时的温度场和热应力分布,分析了激光诱导等离子体加工微通道的过程。研究表明,激光热加工时温度场的存在导致热应力的产生,热应力超过石英断裂阈值使石英发生炸裂,导致微通道的形成及热裂纹的产生;激光诱导等离子体法由于等离子体屏蔽效应产生的高温等离子体烧蚀石英形成微通道,避免了热裂纹的产生。 相似文献
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Due to the proliferation of diverse network devices with multimedia capabilities, there is an increasing need for Quality of Service (QoS) provisioning in wireless networks. The MAC layer protocol with enhanced distributed channel access (EDCA) in the IEEE 802.11-2007 is able to provide differentiated QoS for different traffic types in wireless networks through varying the Arbitration Inter-Frame Spaces (AIFS) and contention window sizes. However, the performance of high priority traffic can be seriously degraded in the presence of strong noise over the wireless channels. Schemes utilizing adaptive modulation and coding (AMC) technique have also been proposed for the provisioning of QoS. They can provide limited protection in the presence of noise but are ineffective in a high noise scenario. Although multiple non-overlapped channels exist in the 2.4 and 5?GHz spectrum, most IEEE 802.11-based multi-hop ad hoc networks today use only a single channel at anytime. As a result, these networks cannot fully exploit the aggregate bandwidth available in the radio spectrum provisioned by the standards. By identifying vacant channels through the use of cognitive radios technique, the noise problem can be mitigated by distributing network traffic across multiple vacant channels to reduce the node density per transmission channel. In this paper, we propose the MAC-Layer QoS Provisioning Protocol (MQPP) for 802.11-based cognitive radio networks (CRNs) which combines adaptive modulation and coding with dynamic spectrum access. Simulation results demonstrate that MQPP can achieve better performance in terms of lower delay and higher throughput. 相似文献
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Jianfei Yan Quanzhong Li Qi Zhang Liang Yang Jiayin Qin 《International Journal of Communication Systems》2020,33(1)
In this paper, we investigate the secrecy sum rate optimization problem for a multiple‐input single‐output (MISO) nonorthogonal multiple access (NOMA) system with orthogonal space‐time block codes (OSTBC). This system consists of a transmitter, two users, and a potential eavesdropper. The transmitter sends information by orthogonal space‐time block codes. The transmitter's precoder and the power allocation scheme are designed to maximize achievable secrecy sum rate subject to the power constraint at the transmitter and the minimum transmission rate requirement of the weak user. We consider two cases of the eavesdropper's channel condition to obtain positive secrecy sum rate. The first case is the eavesdropper's equivalent channel is the weakest, and the other is the eavesdropper's equivalent channel between the strong user and weak user. For the former case, we employ the constrained concave convex procedure (CCCP)‐based iterative algorithm with one‐dimensional search. While for the latter, we adopt the method of alternating optimization (AO) between precoder and power allocation. We solve a semidefinite programming to optimize the precoder and drive a closed‐form expression of power allocation. The simulation results obtained by our method demonstrate the superiority of our proposed scheme. 相似文献
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Wireless Networks - With the dynamic voltage scaling (DVS) technology, the terminal node (TN) can dynamically adjust its computational speed, thus providing a new way to save energy during task... 相似文献
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