Numerical simulation of atomic layer deposition for thin deposit formation in a mesoporous substrate

ZnO deposition in porous γ-Al₂O₃ via atomic layer deposition (ALD) is the critical first step for the fabrication of zeolitic imidazolate framework membranes using the ligand-induced perm-selectivation process (Science, 361 (2018), 1008–1011). A detailed computational fluid dynamics (CFD) model of the ALD reactor is developed using a finite-volume-based code and validated. It accounts for the transport processes within the feeding system and reaction chamber. The simulated precursor spatiotemporal profiles assuming no ALD reaction were used as boundary conditions in modeling diethylzinc reaction/diffusion in porous γ-Al₂O₃, the predictions of which agreed with experimental electron microscopy measurements. Further simulations confirmed that the present deposition flux is much less than the upper limit of flux, below which the decoupling of reactor/substrate is an accurate assumption. The modeling approach demonstrated here allows for the design of ALD processes for thin-film membrane formation including the synthesis of metal–organic framework membranes.     

Enhanced luminescence and thermal stability of (Sr,Ca)AlSiN3:Eu2+ via superficial organic carbon modification

The Eu²⁺-activated nitride phosphors have been widely used in solid-state lighting, but the applications in high-power white-light-emitting diodes (wLEDs) field require higher thermal stability of luminescent materials. The oxidation of Eu²⁺ and the damage of nitride host in the Eu²⁺-activated nitride phosphors are the two crucial reasons for the luminescence loss while operating. A superficial organic carbon modification is performed on the red-emitting (Sr,Ca)AlSiN₃:Eu²⁺ phosphor via the incorporation of organic carbon by solution mixing and thermal post-treatment under the N₂-H₂ atmosphere. After the superficial organic carbon modification, the oxidation of Eu²⁺ and the formation of impurity phases on the phosphor surface are effectively reduced. When the superficial organic carbon modified sample was treated in the 2 wt.% sucrose solutions, the relative brightness is strengthened by 2.15%, the thermal quenching characteristic is improved by 8.9% at 300℃, and the aging test results show an excellent thermal stability. All above indicate that the superficial organic carbon modification is a promising technique to enhance the thermal stability of analogous Eu²⁺-activated nirtide phosphors.     

钢的回火过程中应力演化的数值模拟

本文提出了一种模拟钢的回火过程中应力演化的数学模型。其中着重进行了蠕变方面的试验研究。在淬火过程数值模拟基础上，用据此模型开发的有限元软件对２６Ｃｒ２Ｎｉ４ＭｏＶ钢圆筒形试件的回火过程进行了计算。结果表明，由本模型预测的回火效果与实测吻合较好。此外还计算分析了回火规范对残余应力的影响，进一步验证了模型的有效性。     

Temperature Dependence of the Magnetocrystalline Anisotropy in Nd_2Co_(14)B Compound

Easy and hard magnetization curves of Nd_2Co_(14)B compound have been measured withextracting-sample-magnetometer(μ_0H_(max)=6T)at 10～300 K.Magnetic anisotropy constants K_1 and K_2have been determined by fitting the hard magnetization curves,in which only K_1 ,K_2 and misalignment anglehave been taken as fitting parameters.The values of K_1 and K_2 at 4.2 K were derived by extrapolation.Anisotropy coefficients,x_2~° and x_4~°were derived from the anisotropy constants.The anisotropy constant K_2increases rapidly with increasing temperature when TT_(sr).The temperature depen-dence of the magnetic anisotropy coefficient x_2~° was fitted with the formula.The anisotropy coefficients x_2~°can be well described by the tenth-power law from 4.2 K to T_(sr)and by the sixth-power law from T_(sr_ to 300 K.     

汽轮机缸体用钢高温时效韧性与组织研究

本文采用仪器化冲击试验方法及微观组织分析方法，对汽轮机缸体用钢在593℃不同时间时效条件下的动态断裂韧性及显微组织进行了研究。动态断裂试验结果表明，经过438h时效，K1d值比未时效试样下降了9．5％；时效2105h与时效438h相比，K1d值差异不大，趋于稳定。断口分析表明，剪切唇厚度和侧膨胀值随时效时间的变化趋势与K1d值随时效时间变化趋势相一致。SEM微观组织形貌和能谱分析表明，时效438h后，晶内与晶界均析出少量碳化物，且部分碳化物颗粒发生聚集和长大；时效438h至2105h，碳化物尺寸及数量变化不大，显微组织趋于稳定。     

含铁铜基陶瓷复合材料高温氧化行为与耐磨性研究

在25,250,350和450℃高温摩擦磨损实验条件下,对两种不同铁含量的Cu基摩擦材料进行高温氧化行为及耐磨性研究。结果表明:Fe在Cu基体中的尺寸、分布影响Cu基摩擦材料的高温抗氧化性和耐磨性,随实验温度升高,Cu基摩擦材料试样中Cu氧化产物为Cu2O,Fe从Fe2O3转变为Fe3O4,金属氧化膜厚度逐渐增加;Fe以小尺寸、均匀分布于Cu基体时,更有利于提高Cu基体整体的抗氧化性能,在350~450℃可形成稳定的氧化膜降低粘着磨损,展现出了较好的高温耐磨性能;而Fe以较大尺寸分布在Cu基体中时,则使Cu基体出现氧化不均匀现象,不利于高温耐磨性能的提高。     

AZ91D合金Ni-Ce-P化学镀层耐磨性的研究

在AZ91D化学镀镍的镀液中添加CeO2微粒，获得Ni-Ce-P化学镀层，并对其组成和耐磨性进行了研究。实验结果表明，CeO2的添加量为0．06-0．1g／L时，在AZ91D合金表面获得了均匀致密的Ni-Ce-P镀层：热处理后镀层中形成了Mg17Ce2、Ni3P、Ce2Ni7新相，耐磨性提高25．78倍。     

N503萃淋树脂分离富集金

研究了N_(503)萃淋树脂的合成方法及其分离富集金的条件.N_(503)萃淋树脂是萃取色层分离富集金的新固定相.2%硫脲、1%亚硫酸钠水溶液均可以定量解脱柱床上的金.经矿样验证,金的测定结果与717离子交换树脂吸附法一致.红外光谱表明该萃取色层与N_(503)液液萃取金有相同的机理.     

太阳能电池自动封装系统的研究

为了保证太阳能电池在恶劣的太空环境下能可靠运行，在太阳能电池布贴前，必须进行抗辐照玻璃盖片的封装操作，以达到保护太阳能电池的目的。抗辐照特性是空间太阳能电池区别于地面应用的太阳能电池的重要特征之一。抗辐照玻璃盖片的封装操作是空间太阳能电池方阵制造过程的重要环节。本文通过机器人技术与滴胶技术的结合，设计出一套太阳能电池自动封装系统，实现太阳能电池片的高精度定量喷涂和抗辐照玻璃盖片的非真空环境下的精确封装。文章详细介绍了设计要求、设计思想、系统组成、工作原理和实现过程，并分析了系统的技术特点。     

35CrMo钢的临界区热处理

研究了３５ＣｒＭｏ钢经不同温度临界区热处理后的显微组织与性能，并着重探讨了对其低温韧性的影响，试验结果得出：３５ＣｒＭｏ钢经临界区淬火并４７０℃中温回火后，与常规热处理态在保持等强度的同时，低温韧性有明显提高，－２０℃的冲击值提高８０％。