Design for improved adhesion of fluorine-incorporated hydrogenated amorphous carbon on metallic stent: Three-layered structure with controlled surface free energy

Hydrogenated amorphous carbon (a-C:H) or element-incorporated a-C:H have attracted much attention as coating materials on coronary artery stents owing to their outstanding properties. However, their applications have been limited because of poor adhesion to metallic materials. The present work was thus aimed at improving the adhesive property of a-C:H-based film on a stent by introducing interlayers with controlled surface free energies.Here we propose a three-layered coating for a SUS316L stent, comprising fluorine-incorporated a-C:H (a-C:H:F), silicon-incorporated a-C:H (a-C:H:Si), and hydrogenated amorphous silicon carbide (a-SiC:H) layers (from top to bottom). Each layer was deposited using a radio frequency plasma enhanced chemical vapor deposition (RF-PECVD) method, and the surface free energy of each layer was controlled by the experimental parameters. Thereafter, the three-layer-coated stent was expanded and evaluated under a scanning electron microscope (SEM) in order to determine whether or not cracking or delamination had occurred. It can be seen from the SEM images that the occurrence of cracks or delamination was markedly suppressed even in the bent region of the stent after expansion, where the plastic deformation is highly localized when stents are expanded. This indicates that the method we applied in this work can serve as one approach to overcoming the limitation described above.     

Voting for highway construction in economic geography

This paper investigates the efficiency of voting for provision of transportation infrastructure such as highways, and discusses the effect on regional structure. The salient conclusions of this study show that voting and political competition engender overprovision of large-scale transportation infrastructure. In addition, consideration of industrial location reveals that the provision of transportation infrastructure exerts a negative effect on development of rural areas.     

A prototype safety system for new on-the-job training (OJT) in an anthropocentric cell manufacturing system

The anthropocentric cell manufacturing system (ACMS) discussed consists of a skill-based manufacturing scheduling system, a new on-the-job training (New OJT) system and a safety system. The New OJT was developed using e-learning and automated guided vehicle (AGV)-arm robot as a teacher for CNC machine training. Since the machines and the AGV-arm robot are automatic devices, controlled by computer programs, the dangers might arise during training. Therefore, the safety system is required to ensure that a learner will be safe. We propose a prototype of safety system with designed machine-protection in order to protect the learner from dangerous behaviours during a level 1 training of a New OJT in ACMS. The machine-protection focused on protection from danger using image processing with a background subtraction technique and comparison of objects' position. We also evaluated safety assessments of the learners, consisting of human error probabilities (HEP) and a human error rate (HER). The prototype of this developed safety system showed that the machine-protection certainly raises a warning alarm when the learner rises into dangerous zones during the training. The evaluated safety assessments showed that our designed New OJT training level 1 course performed more efficient safety performance for self-training of the learner.     

Water/Oil Emulsions Prepared by the Membrane Emulsification Method and Their Stability

We developed and tested a simple method to measure dispersed droplet size of W/O emulsions. Then, using a microporous glass membrane treated with oil phase, we produced a W/O emulsion with high water content (40% w/w) at a high emulsification rate by the membrane emulsification method, and assessed its stability. In comparison with emulsions by the stirring methods, variations in dispersed droplet size and viscosity of emulsions by membrane method were small and the emulsions were more stable. Droplet size was not related to the stability of the W/O emulsion prepared by membrane emulsification.