1-(5-乙基-1,3,4-噻二唑基)-3-苯基硫脲的合成及生物活性

研究了 1 - ( 5 -乙基 - 1 ,3,4-噻二唑基 ) - 3-苯基硫脲的合成及抗菌活性。以 5 -乙基 - 2 -氨基 - 1 ,3,4-噻二唑和异硫氰酸苯酯为原料 ,在十六烷基三甲基溴化铵催化下 ,合成 1 - ( 5 -乙基 - 1 ,3,4-噻二唑基 ) - 3-苯基硫脲 ,找到了较好的合成工艺条件 ,结果表明 :5 -乙基 - 2 -氨基 - 1 ,3,4-噻二唑和异硫氰酸苯酯的摩尔比为 1∶ 1 .8,乙腈为溶剂 ,水浴加热回流 4.0 h,十六烷基三甲基溴化铵为 2 g,1 - ( 5 -乙基 - 1 ,3,4-噻二唑基 ) - 3-苯基硫脲的产率为 5 9.76%。同时发现 1 - ( 5 -乙基 - 1 ,3,4-噻二唑基 ) - 3-苯基硫脲有较强的抗菌活性     

Learning to Rank with Extreme Learning Machine

Relevance ranking has been a popular and interesting topic over the years, which has a large variety of applications. A number of machine learning techniques were successfully applied as the learning algorithms for relevance ranking, including neural network, regularized least square, support vector machine and so on. From machine learning point of view, extreme learning machine actually provides a unified framework where the aforementioned algorithms can be considered as special cases. In this paper, pointwise ELM and pairwise ELM are proposed to learn relevance ranking problems for the first time. In particular, ELM type of linear random node is newly proposed together with kernel version of ELM to be linear as well. The famous publicly available dataset collection LETOR is tested to compare ELM-based ranking algorithms with state-of-art linear ranking algorithms.     

Identification of organochlorines and organobromines in coals

Four Chinese bituminous coals were extracted with CS₂, n-hexane, benzene, methanol, acetone, tetrahydrofuran (THF) and THF/methanol (1: 3 vol/vol) mixed solvent sequentially. The resulting 28 extracts were analyzed with GC/MS. Six organochlorines (OCs) and two organobromines (OBs) were identified in eight extracts from the coals. Our experiments provide, for the first time, the information on the molecular structure of OCs and OBs in coals.     

永乐宫壁画艺术对我国当代工笔人物画的影响

永乐宫壁画是中国古代壁画的奇葩,它代表了传统工笔重彩绘画在元代取得的最高成就。从宏伟的构图、绚丽的色彩和高超的线描技巧等方面分析了永乐宫壁画对当代工笔人物画的影响。当代工笔人物画要继承和发扬永乐宫壁画的优良传统．拓宽和创造出更多的表现手法．复兴和推动中国重彩人物画的发展。     

俄罗斯减压渣油超临界萃取残渣的催化加氢反应研究

以高压反应釜为反应器、环己烷为溶剂,选用分子筛、金属及舍金3大类共6种催化剂,对俄罗斯减压渣油超临界萃取所得残渣的非催化及催化加氢反应进行研究。结果表明,采用NKF-β型和Y型分子筛作为催化剂,残渣加氢反应产物中芳烃的相对含量超过55％;采用金属Fe、Ni以及合金Co—Fe、Pd—C作为催化剂,残渣加氢反应产物中正构烷烃的相对含量超过70％;除采用Fe和Pd—C作为催化剂的残渣加氢反应产物之外,在其他各组产物中均检测到少量含氧化合物,而在以NKF-β型分子筛作为催化剂的加氢反应产物中还检测出含氮化合物。针对各组加氢反应产物中化合物相对含量的差异,推测了残渣在不同类型催化剂作用下可能存在的反应途径。     

试析冷战后中日关系中安全困境的成因

安全困境是现实主义解释国际政治的一个基本概念。从安全困境在国际政治学中的一般定义着手,结合中日地缘政治利益、实力对比、历史积怨及美国的介入等问题分析了中日安全困境的成因。     

Ultralow frequency wave characteristics extracted from particle data: Application of IGSO observations

Interaction between ultralow frequency (ULF) waves and charged particles plays an important role in the acceleration of particles in the Van Allen radiation belts. The strong wave-particle interaction predicts an energy-dependent observational signature of particle flux variations during different stages of the ULF wave evolution. In this paper, we find that the energetic particle data newly available from an IGSO spacecraft are quite consistent with theoretical predictions, which enables the application of a best-fit procedure to quantitatively extract key parameters of the ULF waves from the particle data. The general agreement between observations and the best-fit results validates the scenario of wave-particle drift resonance within the entire ULF life span, and provides a new technique to understand the ULF wave characteristics in the absence of electromagnetic field data. We also examine the minor differences between observations and the best-fit results, and propose that the differences may result from a longitudinal dependence of the ULF wave power to be considered in a future study.     

城中村改造中的社会治理困境与民生需求满足

在我国城市化工业化双引擎作用下,大量农村剩余劳动力进入城市。高速发展的城镇化造成了城市发展的不平衡,城中村就是诸多不平衡发展的形式之一,成了城市中的"补丁"。建立城中村改造的长效机制,不能是政府单方面的推动,还要介入社会力量,且应该充分体现以人为本的思想,尊重村民集体的意愿进行城中村的改造。唯此,才能使改造惠及民生,让城市化进程中的这部分地区人口获得相关制度的有效衔接,提高生活质量。     

Preparation and properties of a long-life cementbased mortar used on metal oilcans

Organic-based materials are often used as the coating of metal oilcans. But they need to be sprayed several times in the whole life of oilcans because of the short-life of organic components. To overcome this problem, a type of long-life flexible cement-based anti-corrosion material used on the surface of metal oilcans was developed according to the principle that the steel reinforced concrete can remain the same life with buildings. The materials with different formulas composed of acrylic ~nulsion, cement and other additives were prepared. Because the ratios of polymer to cement played the decisive role in the adhesion and anti-corrosion characteristics, their effects on the physical performances were investigated by comparing the mechanical properties, anti-corrosion and anti-aging properties. The relationship between microstructure and macroscopic properties was also discussed.     

基于BP神经网络的模糊PID风量控制

针对煤矿主风机通风系统多变量、非线性、时变滞后性等问题,提出一种基于BP神经网络的模糊PID算法。该算法综合神经网络、模糊控制与PID调节的各自优点,既具有神经网络的自学习和自适应能力,又具有模糊控制的非线性控制作用,同时兼备PID调节的广泛性。仿真结果表明,该算法的响应速度、稳态精度均优于传统的PID调节,取得比较理想的控制效果。