相容剂对聚丙烯／滑石粉增容作用研究

作者采用熔融接技方法制备PP-g-AA和PP-g-MAH,并比较了这两种相容剂对PP/滑石粉体系的增容效果。着重研究了引发剂含量、单体含量对PP-g-AA增容作用的影响以及PP-g-AA用量对PP/滑石粉体系力学强度的影响。     

室温固化双组分水性木器涂料

一种新颖的室温固化双组分水性木器涂料与相应的单组分涂料相比,其显著特点涂膜有极好的附着力、更高的硬度、优异的耐水、耐烫、耐溶剂和抗粘连及耐污渍性等。其配漆后的适用期室温下可达30d以上,涂料的综合性能可与溶剂型漆相媲美。     

氢化可的松母液错流萃取行为研究

将氢化可的松母液解析为氢化可的松、表氢化可的松和６α－羟基ＲＳ三种组分，模拟了母液的表观分配系数。拟合结果与实验值符合较好，平均相对误差＜５．５％。     

Micromechanical properties on the surface of PVC/SBR blends spatially resolved by a nanoindentation technique

The microhardness and micromodulus on the surface of poly(vinyl chloride) (PVC)/styrene‐butadiene rubber (SBR) blends were determined using a nanoindenter. A flat surface was obtained by microtoming the sample at ?100°C in liquid nitrogen. Dozens of indents along a line with a spatial interval of 0.5 μm were performed. From the loading and unloading curves of each indentation, the stiffnesses of the unloading curve and the contact area between the sample and the indenter were evaluated, and the local modulus and hardness were calculated. Profiles of the local hardness and modulus were obtained from the lines of indents. Pure PVC and a miscible PVC/acrylonitrile‐butadiene rubber (NBR) (40/10) blend showed constant modulus and hardness values. In the case of an immiscible PVC/SBR (50/50) blend, which has a morphology of elongated PVC droplets in the SBR matrix, the hardness and modulus profiles showed regions of the different phases. At the interface between the SBR and PVC phases, a step change in the modulus and hardness profiles was observed. The force required to deform the material at the same displacement increased systematically across the interface from the SBR to the PVC phase because of the increasing contribution of the PVC phase. Polym. Eng. Sci. 44:609–614, 2004. © 2004 Society of Plastics Engineers.     

PTC型BaTiO3陶瓷的孪晶和孪晶界

用透射电镜和高分辨电镜观察研究了PTC型BaTiO_3陶瓷的孪晶和孪晶界结构,并提出了可能的{111}孪晶及孪晶界的原子结构模型。结果表明,{111}孪晶形成氧八面体共面的共格倾斜孪晶界,在孪晶界处可能存在一定量的A空位且原子密度要低于孪晶体内。同时还发现两种其它特征的孪晶现象。     

基于计划值理论的互联网专线投资管理策略研究

计划值管理是一种有计划、高效率支撑企业生产运营的独特管理模式。借鉴其在钢铁行业成功应用的经验,结合互联网专线业务的特点,将计划值理论引入通信企业互联网专线投资管理工作中,构建科学、合理、灵活的互联网专线计划值管理指标体系。     

一种基于来电平台的新型提醒类业务

随着电信技术以及互联网应用的飞速发展,越来越多的新兴业务出现,给传统电信业务,尤其是各类手机业务带来了巨大挑战,同时,也对传统运营商的创新能力以及满足用户各类需求的能力提出了更高要求。本文介绍的换号提醒业务就是从用户需求的角度出发,对用户进行各种细节的关心,提升手机用户的业务体验。     

现代陶艺在环境空间中的应用

空间对于现代陶艺和环境建筑同样重要。陶艺空间和建筑空间因功能要求而定。现代陶艺以各种形式置身于环境空间之中,需要和它相适应的装饰语言。空间意识的改变,会产生一种全新的公共空间。增强人们对建筑与人文环境认识,将建筑的规模缩小为自然与人的空间。现代陶艺不仅构筑的是结构形体的空间,更表现的是一种博大的容纳品性。     

Polyimide foams with ultralow dielectric constants

To explore ultralow dielectric constant polyimide, the crosslinked polyimide foams (PIFs) were prepared from 3,3′,4,4′‐benzophenonetetracarboxylic dianhydride (BTDA), 4,4′‐oxydianiline (ODA), and 2,4,6‐triaminopyrimidine (TAP) via a poly(ester–amine salt) (PEAS) process. FTIR measurements indicated that TAP did not yield a negative effect on imidization of PEAS precursors. SEM measurement revealed the homogeneous cell structure. Through using TAP as a crosslinking monomer, the mechanical properties of PIFs could be improved in comparison with uncrosslinked BTDA/ODA based PIF. The crosslinked PIFs still exhibited excellent thermal stability with 5% weight loss temperatures higher than 520°C. In the field with frequency higher than 100 Hz, the dielectric constants of the obtained PIFs ranged from 1.77 to 2.4, and the dielectric losses were smaller than 3 × 10^?2 at 25–150°C. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 1734–1740, 2006