Propylene epoxidation in a microreactor with electric heating

Gas phase propylene epoxidation on gold catalysts has attracted wide attention from industry and academia due to its high selectivity. However, it suffers from low propylene conversion and rapid catalyst deactivation. Experiments showed that propylene conversion could be increased by raising H₂, O₂, or C₃H₆ concentration in the feed, but the feed compositions were within the explosion limit. It was also shown that the activity of the used catalyst could be fully recovered, but the regeneration temperature was 280 °C, much higher than that for reaction. Therefore a microchannel reactor was devised to suppress explosion and was constructed with Fecralloy, to raise the temperature rapidly for catalyst regeneration by electric heating. In two minutes the temperature of the reactor could be raised from 50 to 300 °C. Catalysts were coated on the alloy belt by dip coating, and the performance of the reactor was evaluated under different operating conditions. Results showed that in the microreactor the overall reaction rate was controlled mainly by the intrinsic reaction rate, and also influenced by film diffusion to a certain extent. The deactivated catalyst was regenerated in the microchannel reactor and the activity was fully recovered.     

CO2在绿色化学合成中的应用

研究了CO2在绿色化学合成中的应用.CO2作为酸碱调节剂和惰性气体,在β-胡萝卜素催化氧化合成角黄素反应中,可以控制反应体系酸性,保护原料中的双键,减少副反应发生,提高催化氧化反应的选择性;异戊二烯氯醇化生成1-氯-2-甲基-3-丁烯-2-醇和1-氯-2-甲基-3-丁唏-4-醇反应中,CO2代替有机酸作酸碱调节剂,控制次氯酸的生成速度,达到调控反应的目的,反应条件温和,不副产固体.     

Preparation and self‐assembly of poly(diglycidyl maleate‐co‐stearyl methacrylate)

Poly(diglycidyl maleate‐co‐stearyl methacrylate) (P(DGMA‐co‐SMA)) with reactive epoxy groups was synthesized by reaction of poly(maleic anhydride‐co‐stearyl methacrylate) (P(MA‐co‐SMA)) and epichlorohydrin. The effect of precipitant on self‐assembly behaviors of the resultant copolymer was investigated. It was found that vesicles and nanotubule liked aggregates can be obtained through self‐assembly of P(DGMA‐co‐SMA) in THF solution using CH₃CH₂OH (EtOH) as precipitant while spheral aggregates can be obtained using H₂O as precipitant. The mechanism of the self‐assembly behavior was discussed. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2007     

Trusted Integrated Circuits: The Problem and Challenges

Hardware security has become more and more important in current information security architecture. Recently collected reports have shown that there may have been considerable hardware attacks prepared for possible military usage from all over the world. Due to the intrinsic difference from software security, hardware security has some special features and challenges. In order to guarantee hardware security, academia has proposed the concept of trusted integrated circuits, which aims at a secure circulation of IC design, manufacture and chip using. This paper reviews the main problems of trusted integrated circuits, and concludes four key domains of the trusted IC, namely the trusted IC design, trusted manufacture, trusted IP protection, and trusted chip authentication. The main challenges in those domains are also analyzed based on the current known techniques. Finally, the main limitations of the current techniques and possible future trends are discussed.     

掺锰BaTiO3 PTCR陶瓷的电子顺磁共振研究

利用电子顺磁共振（EPR）方法对Mn掺杂的BaTiO3 PTCR陶瓷在120－450K的温度范围内进行了研究，研究结果表明：高自旋Mn^2 离子的6重谱线非常明显，表征谱线位置的g因子为2．009 9,Mn^2 离子信号弱弱与BaTiO3晶体结构密切相关，Mn^2 离子信号的温度分布呈U型，即在三方相和立方相时，信号强度较强，而在四方相和斜方相时信号很弱，这是因为在四方相和斜方相中，由于BaTiO3晶体结构的扭曲和畸变，导致Mn^2 和Vo空位缔合生成Mn^2 -Vo复合缺陷，未成对电子的消失以及复合缺陷n^2 -Vo的生成最Mn^2 在四方相和斜方相（200－380K）消失的主因，实验中没有发现Mn^3 和Mn^4 的信号，而与实验的环境条件一致，掺Mn后样品Curie点的漂移可能是Mn进入晶格的一个判据，此外，由于试样的n(Ba)/n(Ti)=1，因而没有发现钡空位VBa及其它的复合缺陷（如：VBa-Mn^2 ,Mn^3 -Vo,La^3 -Mn^3 等），Mn^2 离子等电子陷阱的生长是Curie温度处电阻骤然增加的主要原因。     

高炉用氮化硅结合碳化硅制品化学分析方法的研究

确定了高氧化铝含量（０．５％－２０％）的高炉用氮化硅结合碳化硅制品中Ｓｉ３Ｎ４、ＳｉＣ、ｆＳｉ、ＳｉＯ２、Ｆｅ２Ｏ３、Ａｌ２Ｏ３六种化学成分的化学分析方法试验条件．并按条件试验选择了分析方法，进行了精密度、准确度和实际工作的考核，证明了本分析方法可靠、切实可行，能满足科研工作和生产的要求。     

一种基于过零点的时延测量方法

信号传输时间（时延）的测量,是雷达、声纳系统的关键技术之一。本文研究了一种基于过零点的时延测量方法,在建立过零点搜索模型的基础上推导得出时延测量的测量结果表达式;定量分析了高斯白噪声条件下过零点时延测量的测量精度,得到测量误差的理论表达式。仿真与实验表明,过零点时延测量精度与信号频率、过零点数目、信噪比密切相关,当信噪比较高时,其测量精度与经典FFT法相当,而优势在于过零点时延测量的算法简单、计算量小,适用于对实时性要求较高的测量场合。     

网络化雷达协同抗欺骗式干扰技术研究进展

网络化雷达在战场上可以构成全方位、立体化、多层次的战斗体系,因 此对欺骗式干扰对抗具有很大的优越性。本文首先简要介绍了网络化雷达概念,并分析了其 抗干扰优势。根据网络化雷达融合结构不同,将现有协同抗干扰方法分为数据级融合抗欺骗 式干扰和信号级融合抗欺骗式干扰两大类,其中,数据级融合方法进一步分类为点迹关联和 航迹关联两类。本文对各类方法进行了详细介绍,在此基础上,比较分析了数据级融合和信 号级融合两类方法的抗干扰性能及算法复杂度,为抗干扰措施的选择提供依据。最后,针对 现有方法中存在的问题,对网络化雷达协同抗欺骗式干扰的发展趋势进行展望,指出下一步 的研究方向。     

年产200吨4，4’-二氟二苯甲酮（DFBP）的工业化设计及可行性研究

本文在大量实验数据基础上，对4，4’-二氟二苯甲酮(DFBP)进行了年产200吨规模的工业化设计，从技术关键、工艺流程、设备选材、三废治理及成本核算等方面对DFBP工业化设计的可行性进行了评价，该设计有如下特点：工艺简单、合理，操作稳定、安全，三废治理有效，原材料及设备投资少，见效快，适合工业化大生产。     

突发GMSK混和信号混合位置估计迭代算法

针对GMSK混合信号的混合位置估计问题,提出了一种基于参数估计与混合位置估计的迭代算法。混合信号混合部位和未混合部位在幅度和频率上存在明显差异,通过混合部位信号过零点和极值点得到混合的信号和幅度估计后,可以对采样点是否混合进行判断,同时混合起点对应着相对时延,当混合信号的相对时延较大时,利用未混合部位信号来进行迭代时,其估计精度更高。对混合起点估计的克拉美罗界进行了推导,仿真表明,本文算法估计精度高,所需的数据量小,适用于突发通信,且对参数变化不敏感,具有较强的鲁棒性,在高信噪比下混合位置估计精度接近克拉美罗界。