PPNCast：一种基于对等交换的应用层组播方法*

针对高码率和实时性要求不高的大规模媒体分发应用,提出一种新的应用层组播PPNCast。PPNCast基于对等交换的思想对应用层组播系统进行了优化,可以支持多种片的分发模型。通过仿真实验与Yoid、NICE应用层组播协议对比,结果显示PPNCast可以明显改善系统的链路压力均衡度和节点公平度。     

Synthesis and characterization of triclinic structural LiVPO4F as possible 4.2 V cathode materials for lithium ion batteries

A potential 4.2 V cathode material LiVPO4F for lithium batteries was prepared by two-step reaction method based on a carbon-thermal reduction （CTR） process. Firstly, V2O5, NH4H2PO4 and acetylene black are reacted under an Ar atmosphere to yield VPO4. The transition-metal reduction is facilitated by the CTR based on C→CO transition. These CTR conditions favor stabilization of the vanadium as V^3＋ as well as leaving residual carbon, which is useful in the subsequent electrode processing. Secondly, VPO4 reacts with ElF to yield LiVPO4F product. The property of the LiVPO4F was investigated by X-ray diffractometry （XRD）, scanning electron microscopy （SEM） and electrochemical measurement. XRD studies show that LiVPO4F synthesized has triclinic structure（space group p I ）, isostructural with the naturally occurring mineral tavorite, EiFePO4-OH. SEM image exhibits that the particle size is about 2μm together with homogenous distribution. Electrochemical test shows that the initial discharge capacity of LiVPO4F powder is 119 mA·h/g at the rate of 0.2C with an average discharge voltage of 4.2V （vs Ei/Li^＋）, and the capacity retains 89 mA·h/g after 30 cycles.     

基于VSM的文本相似度计算的研究*

文本相似度的计算作为其他文本信息处理的基础和关键,其计算准确率和效率直接影响其他文本信息处理的结果。提出改进的DF算法和TDIDF算法,一方面利用了DF算法具有线性的时间复杂度,比较适合大规模文本处理的特点,并通过适当增加关键词的方法,弥补了其对个别有用信息错误过滤的不足;另一方面,利用特征项在特征选择阶段的权重对TDIDF方法进行加权处理,在不增加开销的情况下扩大了文档集的规模,还提高了相似度计算的精确度。     

对一类代理盲签名的攻击与改进

为了解决XUE-CAO代理盲签名方案的可伪造性问题,首先对XUE-CAO方案进行了安全性分析,在此基础上,提出一种改进的抗伪造攻击的代理盲签名方案。新方案克服了原方案中两处设计缺陷,防止了广泛伪造和原始签名者的伪造攻击,而且还保留了原方案的可验证性、强不可否认性、强可注销性和不可连接性等安全特性,从而可以用于构造安全的代理盲签名系统。     

基于分块的大规模地形实时渲染方法

将地形数据分块技术、层次细节模型（LOD） 技术、改进的ROAM 算法和数据预取技术等相结合,提出了一种超大规模地形数据实时渲染方法.通过分块策略对规则网格进行区域分割,采用空间填充曲线对分块网格进行多分辨率排列,并建立三角形节点顺序与剖分点之间对应关系的快速检索,实现数据快速调度;视见体投影简化分块裁剪算法降低可见性判断的复杂度,提高了计算效率;改进的四队列ROAM实时构网算法,很好地利用了相邻帧的相关性,有效地提高了渲染速度;基于视点预测、部分数据常驻内存的多线程数据预取实现了场景规模基本不相关的连续LOD实时渲染.实验结果表明,该算法高效可行,适合于海量地形场景的快速渲染和交互漫游应用.     

一种基于产生式的流程模型分析方法*

在深入分析业务流程模型和合理的抽象业务活动基础上,提出了一种基于产生式的流程模型形式化分析方法,并提供了一种从一般流程描述到该模型的转换方法;在此基础上,推导了一系列行之有效的流程属性验证规则,并通过应用实际例子证明了所提出方法的有效性。     

Phase diagrams and thermodynamics of the systems ZrO2-CaO and ZrO2-MgO

The partial phase diagrams of the systems ZrO₂-CaO and ZrO₂-MgO were determined using precision lattice parameter measurements in order to check uncertainties reported in the literature. The results are in general agreement with the previous investigations by Hellmann and Stubican [83HeI], Grain [67Gra], and Sim and Stubican [87Sim]. Enthalpies of formation of the fluorite cubic solid solution and the Ca₂6Zr₁₉O₄₄ ordered phase, with reference to the monoclinic zirconia and the periclase forms of CaO and MgO, were measured calorimetrically. Assessment of the thermodynamic properties of these two systems shows that it is appropriate to model the systems with a simple single cation sublattice model. The eutectoid of the cubic phase in ZrO₂-CaO, according to both the optimization and the experimental results, is located at 1412 ± 50 K and 16.2 ±1.0 mol% CaO and in the ZrO₂-MgO binary at 1678 ± 5 K and 13.1 ± 0.5 mol% MgO. The calculated phase diagrams are presented for comparison with the experimental results.     

环氧类玻璃高分子材料的热回收性能研究

采用动态交联技术制备了环氧类玻璃高分子材料（EPV）,将其制得的片材在不同模压条件下进行重复加工,考察了模压温度、模压时间和模压压力对EPV回收材料性能的影响。结果表明：重复加工没有造成EPV回收材料的降解;模压温度越高,模压时间越长,模压压力越大,越有利于EPV的愈合和重塑;在模压温度为180℃,模压压力为20 MPa,模压时间为10 min的较佳条件下,重复加工的EPV回收材料力学性能与初始EPV片材的接近。     

Mechanical nondiscoloring and antistretching photonic crystal films based on Zn2+ coordination and hydroxypropyl methylcellulose

Mechanical nondiscoloring and antistretching photonic crystal (PC) films, especially those with stable structure colors during deformation, have great potential applications in wearable display devices, decoration, and packaging. Here, PC films with antistretching and invariant structural colors during deformation were prepared, by combining Zn²⁺ coordinated elastic material and hydroxypropyl methylcellulose (HPMC) with polystyrene@silica (PS@SiO₂) colloidal crystals. The PC films release energy by forming local fractures at a microscopic level during the straining process but the lattice spacing and effective refractive index of the local array do not change. According to the Bragg law, the structure color remains unchanged. The introduction of HPMC gave the PC films excellent tensile properties, and the maximum tensile strength reached 10 MPa. And after 100 times of stretching, bending and compression cycles, the structural color remained unchanged.     

Synthesis and characterization of poly(hexamethylene terephthalate/hexamethylene oxamide) alternating copolyamide (alt-PA6T/62)

As a representative polyoxamide, poly(hexamethylene oxamide) (PA62) has good comprehensive performance. However, the high T_m (330°C) creates an obstacle for processing. To improve the processability of PA62, poly(hexamethylene terephthalate/hexamethylene oxamide) alternating copolyamide (alt-PA6T/62) was synthesized by hexamethylene diamine-terminated 6T6-diamine and dibutyl oxalate via solution/solid state polycondensation. Random copolyamide (ran-PA6T/62) was also synthesized for comparison. The structure and properties of the copolymer were analyzed by Fourier transform infrared spectroscopy (FT-IR), nuclear magnetic resonance (NMR) spectroscopy, differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), Wide-angle X-ray diffraction (WAXD) and the saturated water absorption test. The NMR results confirm the alternating structure of alt-PA6T/62. The DSC and TGA results demonstrate that the novel alternating copolyamide alt-PA6T/62 (T_m = 321°C, T₅ = 420°C) exhibited better thermal properties than those of ran-PA6T/62 (T_m = 294°C, T₅ = 412°C). The saturated water absorption of alt-PA6T/62 was found to be 3.2 wt%. These results revealed that the novel alt-PA6T/62 had an alternating sequence distribution, showed a high melting point as well as good processability and thermal stability, and possessed low saturated water absorption and excellent dimensional stability.