Anchoring single Pt atoms on hollow Ag3VO4 spheres for improved activity towards photocatalytic H2 evolution reaction

The high cost of noble metal catalysts has been a great bottleneck for the catalyst industry. Using the noble metal at a single-atom level for catalytic applications could dramatically decrease the cost. The impacts of single Pt atoms on the photocatalytic performance of Ag₃VO₄ have been investigated and reported. In this report, single Pt atoms were anchored on the surface of Ag₃VO₄ (AVO) as a cocatalyst, and the resultant composite photocatalyst has been studied for photocatalytic H₂ production from water driven by visible light. The as-prepared AVO particles are hollow nanospheres in the monoclinic phase with a bandgap of 2.20 eV. The light absorption edge of AVO/Pt is slightly red-shifted compared to that of the pristine AVO, indicating more visible light absorption of AVO/Pt. The XPS peaks of Ag, V, and Pt exhibit a significant shift after AVO and Pt get into contact, suggesting the strong interaction between the surface Ag and V atoms, and single Pt atoms. After 3-h illumination, the photocatalytic H₂ evolution amount from AVO/Pt is improved up to 1400 μmol, which is 2.8 times that on the bare AVO. Such efficient photocatalytic H₂ evolution on AVO/Pt is still maintained after five reaction cycles. The better photocatalytic performance of AVO/Pt has been attributed to the more efficient visible light utilization and the lower interfacial charge transfer resistance, as demonstrated in the DRS and EIS spectra. The presence of the surface Pt atoms also leads to a higher amount of reactive radicals, which could efficiently promote the surface redox reactions.     

Polymers dynamics of the nonfluoro,nano-brush repelling agent with self-stratifying property in water-based coatings

While perfluoroalkyl acids (PFAAs), also known as C8s, are used extensively in textile repellent coatings, concerns have arisen for their carcinogenicity and hazardous effects on the environment. In this study, a novel water-based, nonfluoro, and nanobrush textile repelling agent was prepared by conventional sol–gel chemistry using amorphous fumed silica and n-octyltriethoxysilane as the starting materials. Minimal interaction between the designed repelling agent and marketed water-based resins was confirmed using linear viscosity region (LVR) analysis and asymmetric-flow field-flow fractionation (AF4), suggesting the self-stratification potential of the repelling agent. More specifically, the repelling agent exhibited excellent compatibility and self-stratifying ability with a force-emulsified acrylic-based resin, affording a water contact angle of 104.3° when incorporated at 7% solid content. Performance tests carried out on thermoplastic polyurethane (TPU) revealed excellent adhesion (100/100) of a final formulation, and a significant increase in water contact angle from 80.1° to 103.8° after treatment. In addition, the fouling area after the removal of a submerged sample from a mixture of slurry, polymer, and oil decreased from 48 to 1% when the repelling agent was added. Moreover, the sludge-fouling property remained unchanged after 1000 cycles of abrasion. These findings demonstrate the potential of the described nonfluoro, nanobrush repelling agent as an environmentally safe alternative for use with commercial resins, in turn realizing a fully water-based hydrophobic coating. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136, 48003.     

一种基于Spark的不确定数据集频繁模式挖掘算法

如何在海量不确定数据集中提高频繁模式挖掘性能是目前研究的热点.传统算法大多是以期望、概率或者权重等单一指标为数据项集支持度，在大数据背景下，同时考虑概率和权重支持度的算法难以兼顾其执行效率.为此，本文提出一种基于Spark的不确定数据集频繁模式挖掘算法（UWEFP），首先，为了同时兼顾数据项的概率和权重，计算一项集的最大概率权重值并进行剪枝；然后，为了减少对数据集的多次扫描，结合Spark框架的优点，设计了一种具有FP-tree特征的新颖的UWEFP-tree结构进行模式树的构建及挖掘；最后在Spark环境下，以UCI数据集进行实验验证.实验结果表明本文的方法在保证挖掘结果的同时，提高了效率.     

IDS告警融合与关联模型的研究

入侵检测是保障网络安全的重要手段,针对现有入侵检测系统中告警数量多、协调性差等问题,论文提出了一种具有告警融合与关联功能的告警处理系统模型,该模型冗余告警量少、整体检测能力强,并能进行攻击企图的预测,能有效提高入侵检测的效率,有助于进一步增强网络的健壮性。     

2G/3G网络漫游的思考

在充分考虑目前移动网络发展现状的基础上,对我国发展3G网络时与2G网络漫游的优势进行了深入的讨论,并提出漫游的解决方案。     

铁塔加工中型材零件优化下料管理系统

介绍了铁塔加工中角钢零件优化下料管理系统,阐明了系统的模块化结构及工作原理。建立的面向角钢加工工艺的优化下料管理系统可以将生产管理与下料优化两大功能整合为一体,使用极为方便。该系统在铁塔生产中,可节省大量材料,有效地提高了企业的经济效益。     

钱塘江景观与文化关系初析

我国进入经济高速发展期后,人们在防洪抗旱得到安全保障、开发资源和治理江道等对河流的基本需求得到满足后,逐渐重视河流的景观和生态功能.从分析研究钱塘江下游河流景观特征、地理水文及人类活动对形成丰富多彩的景观的作用,以及一些以钱塘江为吟颂对象的诗词出发,初步探讨钱塘江景观多样性对人的性格、文学家风格的影响,最后从景观角度探讨河流治理的一些原则.     

四川盆地上三叠统划分对比研究

四川盆地上三叠统对比长期存在混乱，给盆地整体评价带来困难。通过岩石地层、地震地层、事件地层及高分辨率旋回地层等多种方法讨论了须家河组与香溪群各岩性段的对比关系，得出了全盆地上三叠统的对比关系；指出须四段底可近似看成等时界面；须家河组下部地层自西向东、向南逐层超覆在雷口坡组之上，上部地层在盆地西北部自东南向西北方向剥蚀层位渐次变老。文章建议四川盆地上三叠统废除“香溪群”，统一使用“须家河组”，以利于对全盆地上三叠统进行油气资源整体评价与深化研究。     

Tracing of the 1st IEC Secretariat Assumed by China

Introduction The IEC central office informed in 7/543/AC that the secretariat of TC 7 would be taken over by the Chinese National Committee on January 10, 2003 and affirmed subsequently in 7/544/AC that the secretariat of TC 7 has been taken over by the Chinese National Committee which appointing secretary in Shanghai Electric Cable Research Institute as no objection has been raised by the Standardization Management Board members. It's the first IEC secretariat that assumed by China, with great significance, just as commented by the media that the commitment indicate undoubtedly China is to play a much more active and important role in the world especially after its entry into world trade organization as well as the trend of global economic integration.