Synthesis of chiral polymers having camphanediol moieties and their applications on the optical resolution of some racemates

Optically active exo-exo-2,3-camphanediol (CPO) (3) was synthesized from (+)-camphor. Chiral polymers poly(CPO-co-TDI) ( 6 ) and poly(CPO-co-IPDI) ( 7 ) were synthesized by the step polymerization of chiral compound CPO ( 3 ) with toluene-2,4-diisocyanate (TDI) and isophorone diisocyanate (IPDI). To investigate the stereo structure of the chiral polymers, two kinds of model compounds, exo-exo-2,3-di[(phenylamido)oxy]camphane ( 4 ) and exo-exo-2,3-di[(propylamido)oxy]camphane ( 5 ), related to polymers ( 6 ) and ( 7 ) were synthesized. Chiroptical characteristics and stereo structures of the chiral polymers were investigated using a circular dichroic spectrometer. The results obtained in this investigation suggest that the chiral polymers ( 6 ) and ( 7 ) have no one-handed helix conformation. The optical resolution ability as chiral adsorbent for HPLC of the chiral polymers was investigated. It was found that chiral polymers ( 6 ) and ( 7 ) are effective for the optical resolution of some racemates. © 1995 John Wiley & Sons, Inc.     

表面测温技术在毫米波隐身中的应用

提出了一种通过实时获取环境与装备表面温度实现自适应调节的毫米波隐身的方法及其系统实现.给出了表面测温电路的硬件接口与软件流程图.     

三元合金靶择优溅射稳定态的表面化学成分

基于多元素靶溅射的Andersen-Sigmund关系式，在分析了大量的二、三元素合金溅射稳定态靶表面化学成分的变化之后，发现各元素之间表面结合能之比几乎与靶体化学成分无关。只要给各元素之间设定适当的表面结合能比，就可以很容易地计算出三元合金靶稳定态表面化学成分，至少对于用2keV氩离子轰击的Ag-Pd-Au三元合金靶系来说，其计算结果都与实验值一致。所分析的实验数据是在常温下取得的，所以可不考虑离子轰击诱发的Gibbs偏析，其结论很可能是多元合金靶溅射的一般规律。此外，由Gaidikas等最近所提出的所谓择优溅射中的“基体效应”理论是无实验依据的。     

Sn-9Zn-3Bi/Cu钎焊接头在170℃时效过程中的显微结构

采用ST50润湿实验仪完成了钎焊并研究分析了Sn-9Zn-3Bi/Cu接头在170℃下长期时效的显微结构变化.结果表明:Sn-9Zn-3Bi/Cn接头时效至200 h后在界面处形成单一连续的Cu5Zn8化合物层;时效至500 h和1000 h后,界面处形成了3层化合物层,从铜母材侧起,分别为Cu-Sn化合物层,Cu-Zn化合物层和Sn-Cu化合物层;随着时效时间的增加,整个金属化合物层变厚,而Cu-Zn化合物层减薄,表明Cu-Zn化合物层在时效过程中具有不稳定性.     

ZG20MnMo焊接后热工艺

用插销法研究了后热对ZG20MnMo低合金高强钢焊接热影响区冷裂倾向和强韧性的影响规律。试验结果表明低温后热可以防止ZG20MnMo焊后氢致延迟裂纹的产生,其过热区显微组织主要为板条状马氏体和少量析出碳化物。低温后热时不能有效地改善过热区的组织性能,后热的作用主要通过氢的扩散逸出来体现。     

从化吕田地区围屋平面布局研究

该文以从化吕田地区现存广府围屋和客家围屋田野调查所取得的资料为基础,归纳总结了此两类型围屋的平面布局特征,并初步分析了其流变过程。     

Ni74.5Pd2Al23.5有序合金中的超点阵内禀层错

应用ＴＥＭ研究了Ｌ１２长程有序结构Ｎｉ７４．５Ｐｄ２Ａｌ２３．５合金的室温变形组织。研究结果表明：添加Ｐｄ元素韧化的Ｎｉ７４．５Ｐｄ２Ａｌ２３．５合金的变形组织中存在着大量超点阵内禀层错。绝大部分层错的边界位错是沿〈０１１〉分布的肖克莱偏位错环,其中３０°的ａ／３〈１１２〉超肖克莱位错处于固定状态。这类位错的可动性较差,但其固定程度较合金中普遍存在的ＫｅａｒＷｉｌｓｄｏｒｆ固定位错要弱。     

基于DSP的小型捷联惯性航姿系统研究

针对微小型应用场合,设计了基于DSP的导航计算机,成功构建了低成本小型捷联航姿系统.重点描述了DSP导航计算机的硬件设计思路,特别是"数字信号处理器(DSP)+单片机(MCU)"的特殊的主从式双CPU结构.扼要介绍了系统软件的框架结构.实验表明基于DSP的捷联惯性航姿系统,性能稳定、达到了设计精度,降低了成本,成功的实现了系统的小型化.DSP导航计算机体积仅为65mm×80mm×10mm,对导航系统在小型化领域推广应用具有实际意义.     

单─银精矿提取银的技术

某单─银矿经浮选所得精矿（％）：Ａｇｌ～２，Ｃｕ≈１，Ｐｂ４～７，ＣａＯ＋ＭｇＯ３０～３５，Ｓ４～７，Ｃ８～９。研究了氰化、硫脲、氨浸等方案对该精矿浸出效果，并从浸出指标等因素进行比较，认为焙烧─预浸─氨浸方案较好，银浸出率＞９７％，铜浸出率９５％。     

Stability analysis of chatter vibration for a thin-wall cylindrical workpiece

The vibration characteristics and the vibration direction angle between the beam mode and shell mode of the three-jaw clamped thin-wall cylindrical workpiece will change according to the relative position of the cutting tool to the chucking jaws. This will induce parametric vibration and cause the chatter characteristics of a thin-wall cylindrical workpiece to become more complicated than those of a solid workpiece. In this study, the three-jaw clamped thin-wall cylindrical workpiece was considered as a parametrically excited vibration system. Initially, the relationship between the parametric vibration and the workpiece system structure was investigated, and then the equivalent stability cutting depth of the thin-wall cylindrical workpiece was analyzed by a numerical calculation method. When the three-jaw clamped thin-wall cylindrical workpiece was considered as a parametric vibration system, the analytical results were consistent with the experimental results.