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71.
Masayuki Asada Yoshinari Miura Akiyoshi Osaka Katsutoshi Oukami Seishiro Nakamura 《Journal of Materials Science》1988,23(9):3202-3205
Calcium hydroxyapatite (Ca-HAP) ceramics containing tricalcium phosphate (TCP) were soaked in three solutions: phosphate buffer, tris buffer, and simulated body fluid (SBF). Petal-like crystals of Ca-HAP were deposited on the Ca-HAP ceramics when (i) Ca-HAP ceramics contained -TCP, (ii) the soaking solution contained phosphate ion and (iii) the pH of soaking solution was higher than 7.3. These conditions facilitate the presence of HPO
4
2–
and Ca2+ ions, the latter from dissolution of -TCP. A well-defined X-ray diffraction pattern for the deposited Ca-HAP crystals indicates preferred growth of {002} planes. Slower crystal growth of Ca-HAP was found for SBF (pH=7.5) than in the phosphate buffer, due possibly to the lower phosphate ion content in SBF. 相似文献
72.
Thermophysical properties of molten semiconductors are reviewed. Published data for viscosity, thermal conductivity, surface tension, and other properties are presented. Several measurement methods often used for molten semiconductors are described. Recommended values of thermophysical properties are tabulated for Si, Ge, GaAs, InP, InSb, GaSb, and other compounds. This review shows that further measurements of thermophysical properties of GaAs and InP in the molten state are required. It is also indicated that a very limited amount of data on emissivity is available. Space experiments relating to thermophysical property measurements are described briefly.Nomenclature
Density
-
C
p
Specific heat
-
Kinematic viscosity
-
Dynamic viscosity=
-
Thermal diffusivity
-
Thermal conductivity=Cp
-
Volumetric thermal expansion coefficient
-
Surface tension
-
d/dT
Temperature coefficient of surface tension
-
g
Gravitational acceleration
-
T
Temperature
-
T
Temperature difference
-
L
Characteristic dimension 相似文献
73.
Yoshiro Nakamura Akira Watanabe Kunio Mori Kosaku Tamura Michio Inagaki 《Journal of Materials Science》1986,21(12):4485-4488
A binary blend which consists of two incompatible polymers such as poly(vinyl chloride) and polyethylene has been performed through a partial co-crosslinking reaction with peroxide to give a co-crosslinked blend with a uniform dispersion of small polyethylene particles and with an improved mechanical property. The results are obtained through the formation of a co-crosslinked product which acts as a potential solid phase dispersant as well as a well-bonded reinforcing interlayer on polyethylene particles uniformly dispersed in poly(vinyl chloride) matrix. The resulting blends (PVC/PE=10/90 wt) give carbon spherules of 0.5 to 1m diameter through pressure-carbonization at 650° C for 1 h. 相似文献
74.
Dr. Daisuke Fujiwara Kousuke Mihara Ryo Takayama Yusuke Nakamura Prof. Mitsuhiro Ueda Prof. Takeshi Tsumuraya Prof. Ikuo Fujii 《Chembiochem : a European journal of chemical biology》2021,22(24):3406-3409
Conformationally constrained peptides hold promise as molecular tools in chemical biology and as a new modality in drug discovery. The construction and screening of a target-focused library could be a promising approach for the generation of de novo ligands or inhibitors against target proteins. Here, we have prepared a protein kinase-focused library by chemically modifying helix-loop-helix (HLH) peptides displayed on phage and subsequently tethered to adenosine. The library was screened against aurora kinase A (AurA). The selected HLH peptide Bip - 3 retained the α-helical structure and bound to AurA with a KD value of 13.7 μM. Bip - 3 and the adenosine-tethered peptide Bip - 3 - Adc provided IC50 values of 103 μM and 7.7 μM, respectively, suggesting that Bip - 3 - Adc bivalently inhibited AurA. In addition, the selectivity of Bip - 3 - Adc to several protein kinases was tested, and was highest against AurA. These results demonstrate that chemical modification can enable the construction of a kinase-focused library of phage-displayed HLH peptides. 相似文献
75.
Decomposition of t-butylhydroperoxide was retarded by triazine thiols and their zinc salts, but accelerated by the copper salts of triazine thiols as well as sulfur compounds such as dithiocarbamates and mercaptobenzothiazolates. Triazine thiols and their zine salts are effective antioxidants for polyethylene crosslinked with peroxide and containing copper, and for protecting epichlorohydrin vulcanizates against attack by “sour” or hydroperoxide-containing gasoline. 相似文献
76.
Zhongwen Wu Yubin Zheng Hongmao Yan Tomoki Nakamura Takafumi Nozawa Ryutoku Yosomiya 《大分子材料与工程》1989,173(1):163-181
Polymer blends of PEEK with PES were prepared by the solution blending method. Copolymers composed of PEEK and PES components were synthesized from these oligomers. The formation conditions exerted an influence over the molecular aggregation and the crystallization behaviors of the blend films and block copolymers which were examined by X-ray diffractometry and DSC analysis. As a result, phase-separation in the blend films was found when the formation temperature was high. The blend films formed at 340°C, quenched and annealed at 180°C, exhibited the same crystallization behavior as those of PEEK. In the case of the blend films formed at 300°C, the annealing of the films at 250°C was required to crystallize the blend films. The Tg of a copolymer with a PEEK component content of more than 50% tends to shift toward a higher temperature than the Tg of PEEK itself, and the Tm of the copolymer toward a lower temperature than that of PEEK ist. 相似文献
77.
Yo Jin Kim 《Electrochimica acta》2004,49(19):3227-3234
Palladinized Nafion™ was prepared via ion-exchange and chemical reduction method. Palladium precursors and solvent systems determined the efficiency of the incorporation and distribution of nanoparticles. The tortuous thin Pd film was formed on the surface of membrane when Na+-Nafion™ and water were used. Pd nanoparticles enhanced the water uptake of Nafion™ and reduced its methanol uptake. And dispersed Pd nanoparticles in Nafion™ disturbed the proton conduction and methanol permeation simultaneously in Nafion™ cluster. In order to reduce methanol permeation of Nafion™ and keep its high conductivity, it was more efficient for Pd nanoparticles to distribute near the surface of membrane. Palladinized Nafion™ improved the performance of DMFC single cell operation by reducing the methanol permeation. 相似文献
78.
Yoshitoshi Nakamura Tatsuro Sawada Akihiro Komatsu 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2002,77(10):1101-1106
In order to develop a method for converting raw starch into ethanol efficiently, direct fermentation of ozonized raw starch using a recombinant yeast was investigated. Ozonolysis was carried out as a pretreatment to convert raw starch into ethanol rapidly and efficiently, and then the effect of the ozone degradation conditions on the degree of polymerization and the amount of amylose in a raw starch was determined. Since the degree of polymerization was low and the amount of amylose was high, raw starch treated with an ozone concentration of 40 gm?3 and an ozonation time of 30 min was the material chosen for alcohol fermentation. Though the recombinant yeast could not convert the untreated raw starch, it converted the soluble starch and the ozonized raw starch at a comparatively high yield into ethanol. About 56% of the ozonized raw starch decomposed, and the ethanol concentration obtained from the ozonized raw starch was markedly greater than that obtained from untreated raw starch. The dynamic behavior of cell growth, substrate degradation, and ethanol production was examined in a continuous culture under various dilution rates, and the optimal dilution rate, ie 0.15 h?1, was determined for maximizing the ethanol productivity (amount of ethanol produced per unit time). © 2002 Society of Chemical Industry 相似文献
79.
Atsushi Takahashi Isao Nakamura Masaaki Haneda Tadahiro Fujitani Hideaki Hamada 《Catalysis Letters》2006,106(3-4):133-138
Catalytic hydrogenation of naphthalene to decalin was studied over a carbon-supported rhodium catalyst in supercritical carbon
dioxide solvent at 333 K, and the results were compared with those in an organic solvent. cis-, trans-Decalin and tetralin were formed from the beginning of the reaction in supercritical carbon dioxide. Higher concentration
of hydrogen in carbon dioxide solvent and on the active site, and also the suppression of desorption of partially hydrogenated
tetralin molecules from the active site would be responsible for higher selectivity to cis-decalin in supercritical carbon dioxide than that in an organic solvent. 相似文献
80.
Solid circulation characteristics in an internally circulating fluidized bed with orifice-type draft tube 总被引:1,自引:0,他引:1
Sang Done Kim Yo Han Kim Seon Ah Roh Dong Hyun Lee 《Korean Journal of Chemical Engineering》2002,19(5):911-916
Effects of superficial gas velocities to a draft tube, to an annulus section and particle size on the solid circulation rate
(G,) have been determined in an internally circulating fluidized bed (0.28 m I.D. × 2m high) with an orifice type draft tube.
The solid circulation rate from the draft tube to an annulus section increases with increasing gas velocities to the draft
tube(U
d
) and annulus section (Ua) and consequent increase in pressure drop across the orifice (ΔPor). However, the values ofG
s
decrease by 7–21% with increasing particle size from 86 to 288 μm. The pressure drop across the orifice increases with increasingU
d
andU
a
. However, ΔPor decreases by 5–23% with increasing particle size. To predictG
s
in an internally circulating fluidized bed, a correlation is proposed as a function of ΔPor
This paper is dedicated to Professor Dong Sup Doh on the occasion of his retirement Korea University. 相似文献