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排序方式: 共有237条查询结果,搜索用时 15 毫秒
21.
Miyuki Ikeda Yoshihumi Kusumoto Yohei Yakushijin Shouichi Somekawa Pascaline Ngweniform Bashir Ahmmad 《Catalysis communications》2007,8(12):1943-1946
The photocatalytic production of hydrogen gas from aqueous methanol solution was performed using powdered mixtures of graphite silica (GS) and platinized TiO2 (Pt/TiO2) or those of GS, Pt and TiO2. The addition of GS to Pt/TiO2 resulted in the decrease of the amount of H2 gas, whereas the addition of GS to mixtures of TiO2 and Pt led to the incremental production of H2 gas. This effect is attributed to the aggregation of GS, TiO2 and Pt in suspension. The new additional electron transfer process of TiO2 → Pt → GS caused the increment of the amount of hydrogen gas. 相似文献
22.
In this paper, the synthesis and solid-state structures of β-alkyl-substituted dipyrrolyldiketone BF2 complexes are discussed; these complexes can function as π-conjugated acyclic anion receptors (“molecular flippers”) and are potential building subunits of anion-responsive π-conjugated oligomers or polymers. Modes of the solid-state assemblies in these complexes determined by performing single-crystal X-ray analysis are found to depend on the lengths of the alkyl chains at the β-positions. A β-methyl-substituted receptor has a highly planar structure, which efficiently forms stacking assemblies in the core π-plane in the solid state, while a β-ethyl-substituted receptor shows no stacking assemblies due to the presence of bulky ethyl moieties, which form only dimeric structures by hydrogen bonding. β-Alkyl-substituted anion receptors can be used not only as monomer units of stimuli-responsive polymeric macromolecules but also as components of solid-state electronic materials. 相似文献
23.
A flexible circular saw, which can be used in a novel machining process for high-speed carbon fiber-reinforced plastic (CFRP) plate cutting, was developed. In this process, the saw is deflected like a bowl-like shape. A cross-section of the saw body then forms a circular arc. A curved line can therefore be cut without interference by the bowl-like deflection. In addition, the radius of the cross-section of the saw body can be controlled by adjusting the deflection. This process therefore allows curves to be cut with a varied radius using a single saw. This process can carry out high-speed curved-line cutting with a feed rate of 3 m/min on a CFRP plate. However, it is difficult to cut free-form curves using a flexible circular saw. Therefore, in this research, a new technique that can cut free-form curves using a flexible circular saw was proposed. Then, a cutting test applying the technique was carried out. 相似文献
24.
Railway Engineering Science - Three-dimensional compressible flow simulations were conducted to develop a Hyperloop pod. The novelty is the usage of Gamma transition model, in which the transition... 相似文献
25.
Tetsuya Yamamoto Azamat Zhumagazin Takuma Furusawa Ryoji Tanaka Tetsu Yamakawa Yohei Oe Tetsuo Ohta 《Advanced Synthesis \u0026amp; Catalysis》2014,356(17):3525-3529
Cyclometallated NHC palladium complexes prepared from palladium(II) acetate [Pd(OAc)2] and unsymmetrical 1,3‐diarylimidazolinium salts catalyzed the hydroxymethylation of (hetero)arylboronic acids using an excess amount of formalin to afford (hetero)arylmethanols in good to satisfactory yields.
26.
Photocarrier generation in organic thin-film solar cells with an organic heterojunction 总被引:1,自引:0,他引:1
Takahiro Osasa Shuhei Yamamoto Yohei Iwasaki Michio Matsumura 《Solar Energy Materials & Solar Cells》2006,90(10):1519-1526
Photocurrent–voltage characteristics for organic solar cells with a heterojunction formed between copper phthalocyanine and a perylene derivative (or C60) were studied. The photocurrent was observed under both reverse and forward biases. From the analysis of the photocurrent action spectra, the origin of the reverse photocurrent was attributed to the excitons formed in both the organic layers, whereas that of the forward photocurrent was attributed to the excitons formed in the perylene derivative (or C60) layer. The photocurrent density under reverse bias increased at higher temperatures, suggesting that the charge recombination possibility was lowered at higher temperatures. On the basis of the time responses of the photocurrents observed after pulsed photoirradiation, the charge separation and transport processes are discussed. 相似文献
27.
28.
Study on shock wave and turbulent boundary layer interactions in a square duct at Mach 2 and 4 总被引:2,自引:0,他引:2
In this paper, the outline of the Mach 4 supersonic wind tunnel for the investigation of the supersonic internal flows in ducts was firstly described. Secondly, the location, structure and characteristics of the Mach 2 and Mach 4 pseudo-shock waves in a square duct were investigated by color schlieren photographs and duct wall pressure fluctuation measurements. Finally, the wall shear stress distributions on the side, top and bottom walls of the square duct with the Mach 4 pseudo-shock wave were investigated qualitatively by the shear stress-sensitive liquid crystal visualization method. The side wall boundary layer separation region under the first shock is narrow near the top wall, while the side wall boundary layer separation region under the first shock is very wide near the bottom wall. 相似文献
29.
Deokho Lee Yohei Tomita Yukihiro Miwa Heonuk Jeong Ari Shinojima Norimitsu Ban Shintaro Yamaguchi Ken Nishioka Kazuno Negishi Jun Yoshino Toshihide Kurihara 《International journal of molecular sciences》2022,23(23)
Cardiovascular abnormality-mediated retinal ischemia causes severe visual impairment. Retinal ischemia is involved in enormous pathological processes including oxidative stress, reactive gliosis, and retinal functional deficits. Thus, maintaining retinal function by modulating those pathological processes may prevent or protect against vision loss. Over the decades, nicotinamide mononucleotide (NMN), a crucial nicotinamide adenine dinucleotide (NAD+) intermediate, has been nominated as a promising therapeutic target in retinal diseases. Nonetheless, a protective effect of NMN has not been examined in cardiovascular diseases-induced retinal ischemia. In our study, we aimed to investigate its promising effect of NMN in the ischemic retina of a murine model of carotid artery occlusion. After surgical unilateral common carotid artery occlusion (UCCAO) in adult male C57BL/6 mice, NMN (500 mg/kg/day) was intraperitoneally injected to mice every day until the end of experiments. Electroretinography and biomolecular assays were utilized to measure ocular functional and further molecular alterations in the retina. We found that UCCAO-induced retinal dysfunction was suppressed, pathological gliosis was reduced, retinal NAD+ levels were preserved, and the expression of an antioxidant molecule (nuclear factor erythroid-2-related factor 2; Nrf2) was upregulated by consecutive administration of NMN. Our present outcomes first suggest a promising NMN therapy for the suppression of cardiovascular diseases-mediated retinal ischemic dysfunction. 相似文献
30.
We have developed a genetic selection module which enables us to select for positive and negative expression of a gene by controlling the expression of two antibiotic resistance genes. This module can be used to tune the performance of genetic circuits that yield simple ON/OFF gene expression outputs depending on the environment (input). We have demonstrated the utility of the module by selecting a genetic inverter from a 200 fold excess of nonfunctional inverters in two rounds. 相似文献