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51.
Circular data are those for which the natural support is the unit circle and its toroidal extensions. Numerous constructions have been proposed which can be used to generate models for such data. We propose a new, very general, one based on the normalization of the spectra of complex-valued stationary processes. As illustrations of the new construction's application, we study models for univariate circular data obtained from the spectra of autoregressive moving average models and relate them to existing models in the literature. We also propose and investigate multivariate circular models obtained from the high-order spectra of stationary stochastic processes generated using linear filtering with an autoregressive moving average response function. A new family of distributions for a Markov process on the circle is also introduced. Results for asymptotically optimal inference for dependent observations on the circle are presented which provide a new paradigm for inference with circular models. The application of one of the new families of spectra-generated models is illustrated in an analysis of wind direction data. 相似文献
52.
Kazuo Hasue Shoji Nakahara Jun Morimoto Tetsuo Yamagami Yoichi Okamoto Toru Miyakawa 《Propellants, Explosives, Pyrotechnics》1995,20(4):187-191
To find an effective laser source to ignite energetic materials, the absorption spectra of some energetic materials are obtained by means of a photoacoustic spectroscopy (PAS). In this experiment, PAS covers the wavelength region of 400 nm-1600 nm in which no other conventional method can take absorption spectra for powdered energetic materials. Photoacoustic spectra of 18 energetic materials are reported. In general, energetic materials tested showed peaks in 600 nm–800 nm and 1400 nm–1600 nm ranges. It is found that the energy required to initiate explosives in the case of ruby laser initiation were correlated with their photoacoustic signal intensities. 相似文献
53.
Abnormalities in the Metabolism of Fatty Acids and Triacylglycerols in the Liver of the Goto-Kakizaki Rat: A Model for Non-Obese Type 2 Diabetes
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54.
Yoichi Tominaga 《Polymer》2005,46(19):8113-8118
We have measured ionic conductivity of PEO-LiX [anion X=N(CF3SO2)2 (TFSI), ClO4, CF3SO3, BF4, NO3, and CH3SO3] polymer electrolytes in CO2 at pressures varied from 0.1 to 20 MPa. From the temperature dependence in supercritical CO2, a large increase in the conductivity for PEO-LiBF4 and LiCF3SO3 electrolytes has been observed. Permeation of the CO2 molecules gave rise to the plasticization for crystal domains in the electrolytes, which is related to the reduction in transition point of the Arrhenius plot corresponding to the melting of crystal PEO. Relation between the conductivity and CO2 reduced density revealed that the electrolytes containing fluorinated anions such as ‘CO2-philic’ BF4 and CF3SO3 increase in the conductivity with increasing the density. This indicates that the salt dissociation was promoted by the CO2 permeation and the Lewis acid-base interactions between fluorinated anions and CO2 molecules. 相似文献
55.
Masatomo Yashima Yoichi Kawaike Masahiko Tanaka 《Journal of the American Ceramic Society》2007,90(1):272-274
Unit-cell parameters of the α-tricalcium phosphate [TCP; Ca3 (PO4 )2 ] were investigated using high-resolution synchrotron powder diffraction and the Rietveld method. The diffraction experiment was conducted at 29°C at the BL-15XU experimental station of SPring-8, Japan. Precise unit-cell parameters of the α-TCP were obtained; a =12.87271 (9), b =27.28034(8), c =15.21275(12) Å, α=γ=90°, and β=126.2078(4)°. The calculated density of α-TCP (2.8677 g/cm3 ) is smaller than that of β-TCP, indicating the "looser" structure of α-TCP. 相似文献
56.
Noriaki Ikenaga Yoichi Kishi Zenjiro Yajima Noriyuki Sakudo Shizuka Nakano Hisato Ogiso 《Nuclear instruments & methods in physics research. Section B, Beam interactions with materials and atoms》2009,267(8-9):1509-1513
TiNi alloy samples implanted with various fluences of 3 MeV Cu2+ ions were characterized by transmission electron microscope (TEM) and X-ray diffractometer. Cross-sectional TEM images of the samples showed that amorphous region was seen at the fluence of 1014 ions cm?2 in case of ion implantation at 300 K of the substrate temperature, but in case of ion implantation at 100 K it did not appear even at 1015 ions cm?2. These results were also confirmed by X-ray diffraction profiles of the same samples. Consequently, the extent of microstructure change of TiNi alloy by ion implantation was different depending on the substrate temperature. 相似文献
57.
A novel substrate {Galβ1,4GlcNAcβ1,4GlcNAc-β-pNP [Gal(GlcNAc)2-β-pNP]} for assaying lysozyme activity has been designed using docking simulations and enzymatic synthesis via β-1,4-galactosyltransferase-mediated transglycosylation from UDP-Gal as the donor to (GlcNAc)2-β-pNP as the acceptor. Hydrolysis of the synthesized Gal(GlcNAc)2-β-pNP and related compounds using hen egg-white lysozyme (HEWL) demonstrated that the substrate was specifically cleaved to Gal(GlcNAc)2 and p-nitrophenol (pNP). A combination of kinetic studies and docking simulation was further conducted to elucidate the mode of substrate binding. The results demonstrate that Gal(GlcNAc)2-β-pNP selectively binds to a subsite of lysozyme to liberate the Gal(GlcNAc)2 and pNP products. The work therefore describes a new colorimetric method for quantifying lysozyme on the basis of the determination of pNP liberated from the substrate. 相似文献
58.
Motoyuki Ozaki Toshimitsu Higashi Taiki Ogata Tatsunori Hara Jose Ildefonso Udang Rubrico 《Advanced Robotics》2016,30(22):1446-1457
Distribution centers, which are essential to our society, are becoming increasingly important. Although the efficiency of an AVS/RS (Autonomous vehicle storage and retrieval system) makes it a promising system, there is still much to be studied regarding its effective use and design. This paper proposes a method of designing AVS/RSs through a quantitative consideration of group constraint by utilizing probability theory. The proposed algorithm also deals with the problem of designing the sizes of several buffers, and considers the effect of load fluctuations, which are important for real-world operation, by use of queuing network theory. Effectiveness of the proposed algorithm is shown with simulations of various number of groups, those of various safety factors for fluctuations, and those of various evasion rates for buffer overflow. The design results are shown to be much different from those which do not consider those factors. The results prove that the proposed method provides an accurate quantitative assessment of the AVS/RS’s constraints. 相似文献
59.
Mohammad Kamruzzaman Yutaka Kuwahara Tomonari Ogata Seiji Ujiie Seiji Kurihara 《Polymer International》2011,60(5):730-737
A new class of liquid‐crystalline poly(ethylene imine)s (PEIs) having four differently substituted (? CN,? C4H9,? OCH3 and? NO2) azobenzene side‐chain groups attached through alkyl spacer groups were successfully synthesized using a solution polycondensation reaction. The synthesized polymers were characterized using differential scanning calorimetry, polarized optical microscopy and X‐ray diffraction. The photochemical, thermo‐optical and photo‐orientational behavior of the polymers were investigated in detail. Spin‐coated films of PEIs with azobenzene groups having? C4H9,? OCH3 and? NO2 substituents showed out‐of‐plane molecular orientation on annealing. Except for the PEI with an azobenzene group having ? NO2 substituent, all polymers exhibited good photoresponsive properties upon irradiation with UV and visible light. Films of PEIs with azobenzene side groups having? CN,? C4H9 and? OCH3 substituents showed reversible alignment behavior from random state to out‐of‐plane and from out‐of‐plane to random state on annealing and on irradiation with UV and non‐polarized visible light. The reversibility of the molecular orientation of PEIs from random state to out‐of‐plane and from out‐of‐plane to random state greatly depended on the substituent attached to the azobenzene side‐chain group. Copyright © 2010 Society of Chemical Industry 相似文献
60.
We apply a new framework of a finite-element method (FEM) analysis with constitutive relations based on density functional theory (DFT), as an efficient method to characterize the nonlinear and anisotropic elastic deformation of single-crystal diamond. In our scheme, the stress-strain relations are obtained during FEM analysis on the fly based on the plane-wave-based DFT total-energy calculations and their numerical database is simultaneously constructed, which enables us to obtain high-precision stress without any empirical parameters even under finite strained conditions. To check its validity and accuracy, the shear deformation behavior of diamond crystal is analyzed under the strained condition. Then we examine the nonlinear effects on the indentation deformation of diamond single crystal, by comparing the results from the DFT-based constitutive relations with those from the linear elastic ones. 相似文献