Atomic‐Scale CoOx Species in Metal–Organic Frameworks for Oxygen Evolution Reaction

The activity of electrocatalysts strongly depends on the number of active sites, which can be increased by downsizing electrocatalysts. Single‐atom catalysts have attracted special attention due to atomic‐scale active sites. However, it is a huge challenge to obtain atomic‐scale CoO_x catalysts. The Co‐based metal–organic frameworks (MOFs) own atomically dispersed Co ions, which motivates to design a possible pathway to partially on‐site transform these Co ions to active atomic‐scale CoO_x species, while reserving the highly porous features of MOFs. In this work, for the first time, the targeted on‐site formation of atomic‐scale CoO_x species is realized in ZIF‐67 by O₂ plasma. The abundant pores in ZIF‐67 provide channels for O₂ plasma to activate the Co ions in MOFs to on‐site produce atomic‐scale CoO_x species, which act as the active sites to catalyze the oxygen evolution reaction with an even better activity than RuO₂.     

A 1.8-V distributed voltage-controlled oscillator module for 5.8-GHz ISM band

This letter presents the design and implementation of a 1.8-V 5.8-GHz distributed voltage-controlled oscillator module based on bipolar transistors. The oscillator delivered -2-dBm-output power with a current consumption of 11.5 mA. The tuning range achieved was 650 MHz. The measured phase noise was -100 dBc/Hz at 1-MHz offset. The circuit construction was simple and robust and no buffer amplifier was needed. The design can be used for 5.8-GHz ISM band wireless LAN applications.     

Virus‐Tethered Magnetic Gold Microspheres with Biomimetic Architectures for Enhanced Immunoassays

In immunoassays, non‐specific bindings to biosensing surfaces can be effectively prevented by formation of biocompatible and hydrophilic self‐assembled monolayer (SAM) on the surfaces. A thin gold (Au) layer on magnetic microspheres, 15 μm in diameter, enables facile SAM formation and thereby accepts second layer of filamentous virus scaffolds for the immobilization of functional proteins. The merger of the virus and SAM‐Au protected microspheres not only provides exceptionlly dense antibody loading, but also resembles biological cellular structures that enhance ligand‐receptor interactions. Site‐specific biotinylation of filamenous viruses allows formation of free‐standing virus threads (>1.0 × 10¹⁰) on streptavidin‐modified SAM‐Au microspheres. The augmented yield of antibody loading, due to the increased surface to volume ratio, on virus‐modified Au microspheres is confirmed by measuring fluorescence intensities. The bead‐based immunoassays for the detection of cardiac marker proteins exhibit increased sensitivity of virus‐Au microspheres, as low as 20 pg mL^?1 of cardiac troponin I in serum, and extremely low non‐specific adsorption when compared with bare polymer beads. This increased sensitivity due to filamentous morphology and SAM‐Au layer demonstrates the feasibility of merging viruses with non‐biological materials to yield biomimetic tools for the enhanced bead‐based immunoassays.     

High output impedance current-mode first-order allpass networks with four grounded components and two CCIIs

Eight current-mode first-order allpass networks using second-generation current conveyors (CCII) are presented. Each of the proposed circuits employs two CCIIs, two grounded capacitors and two grounded resistors. The networks offer high output impedances. Experimental results are also included.     

Er-doped glass ridge-waveguide amplifiers fabricated with a collimated sputter deposition technique

We report a new fabrication process for Er-doped glass ridge waveguides. The process does not require etching of an Er-doped film in defining the lateral dimension of a waveguide, but involves a liftoff process using polyimide as a sacrificial layer. An Er-doped soda-lime silicate glass film (1.5 /spl mu/m thick) was deposited at 350/spl deg/C using a collimated sputtering technique. Conventional sputtering techniques have been known to be incompatible with a liftoff process. The collimated sputtering, however, allowed us easy liftoff of Er-doped films, and produced well-defined ridges with smooth surface profiles. A 1.7-cm-long waveguide thus fabricated shows a 1.55-/spl mu/m signal enhancement of 15.4 dB with a 980-nm pump power of 40 mW. This enhancement fully compensates for both Er absorption and waveguide losses, and results in a gain of 7.2 dB.     

Highly Customizable All Solution–Processed Polymer Light Emitting Diodes with Inkjet Printed Ag and Transfer Printed Conductive Polymer Electrodes

Inkjet and transfer printing processes are combined to easily form patterned poly(3,4‐ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) films as top anodes of all solution–processed inverted polymer light emitting diodes (PLEDs) on rigid glass and flexible plastic substrates. An adhesive PEDOT:PSS ink is formulated and fully customizable patterns are obtained using the inkjet printing process. In order to transfer the patterned PEDOT:PSS films, adhesion properties at interfaces during multistep transfer printing processes are carefully adjusted. The transferred PEDOT:PSS film on the plastic substrates shows not only a sheet resistance of 260.6 Ω/□ and a transmittance of 92.1% at 550 nm wavelength but also excellent mechanical flexibility. The PLEDs with spin‐coated functional layers sandwiched between the transferred PEDOT:PSS top anodes and inkjet‐printed Ag bottom cathodes are fabricated. The fabricated PLEDs on the plastic substrates show a high current efficiency of 10.4 cd A^?1 and high mechanical stability. It is noted that because both Ag and PEDOT:PSS electrodes can be patterned with a high degree of freedom via the inkjet printing process, highly customizable PLEDs with various pattern sizes and shapes are demonstrated on the glass and plastic substrates. Finally, with all solution process, a 5 × 7 passive matrix PLED array is demonstrated.     

Spectral characteristics of vertical-cavity surface-emitting lasers with external optical feedback

The measurement of the effects of external optical feedback on the spectra of VCSELs (vertical-cavity surface-emitting lasers) is reported. It is surprising that VCSELs have a sensitivity to optical feedback comparable to that of conventional edge-emitting lasers such as DFBs despite their significantly different structures. This is because the extremely short cavity length of VCSELs negates the effects of their highly reflective output mirrors. As in edge-emitting lasers, VCSELs exhibit well-defined regimes of feedback effects in their spectra. Since optical isolators cannot be easily applied to VCSELs due to their array structure, these lasers may be most useful in applications which are not sensitive to the spectral qualities of the light source.<>     

A new predictive search area approach for fast block motion estimation

According to the observation on the distribution of motion differentials among the motion vector of any block and those of its four neighboring blocks from six real video sequences, this paper presents a new predictive search area approach for fast block motion estimation. Employing our proposed simple predictive search area approach into the full search (FS) algorithm, our improved FS algorithm leads to 93.83% average execution-time improvement ratio, but only has a small estimation accuracy degradation. We also investigate the advantages of computation and estimation accuracy of our improved FS algorithm when compared to the edge-based search algorithm of Chan and Siu (see IEEE Trans. Image Processing, vol.10, p.1223-1238, Aug. 2001); experimental results reveal that our improved FS algorithm has 74.33% average execution-time improvement ratio and has a higher estimation accuracy. Finally, we further compare the performance among our improved FS algorithm, the three-step search algorithm, and the block-based gradient descent search algorithm.     

A low-noise L-band EDFA with a 1500-nm Raman-pumped dispersion-compensating fiber section

This report presents a low-noise L-band erbium-doped fiber amplifier (EDFA) with a dispersion-compensating Raman amplifier. With an optimized prestage and 1500-nm Raman-pump laser diodes, the proposed EDFA achieved an internal noise figure of less than 4.5 dB over a 33-nm flat gain bandwidth within 0.5 dB at -2 dBm of large signal input power.     

Experimental Demonstration of 1.25-Gb/s Radio-Over-Fiber Downlink Using SBS-Based Photonic Upconversion

We experimentally demonstrate a radio-over-fiber downlink system using a stimulated Brillouin scattering (SBS)-based photonic upconversion technique. The Brillouin selective amplification characteristic of SBS is incorporated to generate the 11-GHz band radio-frequency (RF) carrier. The dual-electrode Mach-Zehnder optical modulator, which is used to carry the broadband data in the optical carrier instead of the optical sideband, is adopted along with the SBS-based carrier generation setup. To vindicate the broadband capabilities of the proposed scheme, 1.25-Gb/s pseudorandom bit sequence data is carried in the optical carrier. Error-free operation of the 1.25-Gb/s downlink is achieved without critical power penalties after the 13-km fiber transmission.