Properties and carbonization behavior of asphalt modified with the THF-soluble fraction of a coal liquefaction residue

This study focuses on the effects of the tetrahydrofuran-soluble fraction of direct coal liquefaction residue as a modifier to modify asphalt with formaldehyde. The properties and carbonization behavior of matrix asphalt and the modified asphalts were studied. The results indicate that the ductility properties of modified asphalts have been effectively improved. The morphology of modified asphalts without the addition of formaldehyde is a set of uniform distribution point, and it is converted from linear distribution to clustered distribution observed in fluorescence microscope images with the increase of the adding amount of formaldehyde.     

Efficient Catalyst for Both Suzuki and Heck Cross‐Coupling Reactions: Synthesis and Catalytic Behaviour of Geometry‐ Constrained Iminopyridylpalladium Chlorides

A series of geometry‐constrained iminopyridyl‐palladium chlorides were synthesized and characterized. These phosphine‐free palladium complexes were explored for their catalytic activities in both Suzuki and Heck cross‐coupling reactions, achieving turnover numbers as high as 10⁶ towards various aryl bromides, even those containing various functionalities. In addition, the influence of substituents with steric and electronic factors was reflected by the differences observed in their activities.

     

Decarboxylative (4+1) Oxidative Annulation of Malonate Monoesters with 2‐Vinylpyridine Derivatives

A novel N‐iodosuccinimide‐mediated decarboxylative (4+1) oxidative annulation between 2‐vinylpyridine derivatives and malonate monoesters was developed. It offers a new way to construct indolizine derivatives by utilizing malonate monoesters as a C₁ unit. The alkyl 2,2‐diiodoacetate was found to be the active reaction intermediate during the transformation.

     

基于包容性的城市慢行交通综合导视交互设计研究

针对城市慢行交通系统的导视进行了研究,提出了基于包容性理念的综合导视系统的设计概念,设计过程包括了原型测试、行人动线研究、互动导视系统的设计等内容。     

南京地铁建设项目管理信息系统的建设研究

建设项目管理信息系统是处理工程管理信息的人机系统。它通过收集、存储及分析工程项目实施过程中的有关数据,辅助工程项目的管理人员和决策者规划、决策和检查,其核心是辅助对工程项目目标的控制。     

关于建筑工程深基坑施工应注意的问题

本文就建筑工程深基坑施工过程中应注意的问题进行了浅显地探讨,并提出了有益提高建筑工程深基坑施工技术水平的策略。     

便携式斯特林深冷冰箱研制

研制了一种以斯特林低温制冷机为冷源,有效容积6L,工作温度范围-60℃～-160℃的深冷冰箱.小型斯特林制冷机采用直线电机驱动,电机与压缩机一体化设计,采用氦气制冷工质.斯特林制冷机的冷指置于冰箱内底端直接冷却.圆柱形箱体采用了内环为真空层、外环为硬质聚氨酯发泡层的复合绝热技术,设计了具有3层辐射屏的内盖和真空箱盖.该冰箱具有环境友好、热效率高、制冷温区宽、制冷量易控和体积小等特点,可以满足低温保存和实验等需求.输入功率170W时冰箱内温度低于-150℃,对应-100℃低温时的制冷量为7W.     

基于一种新边缘算法的轴承直径测量

边缘检测是特征提取、图像处理与分析的关键技术,针对现有边缘检测算法检测图像中的单边边缘多数会出现双边响应的问题,提出一种新的非边缘点抑制算法,并将这种算法应用于轴承径向尺寸测量中.实验表明,该算法可以有效地解决上述问题并获得良好的边缘.     

核电厂蒸汽发生器多功能模拟体研制

在压水堆核电厂蒸汽发生器的在役检查和维修中,需要使用蒸汽发生器模拟体,预先对检修工器具进行调试、验证以及人员的培训。基于蒸汽发生器模拟体的功能需求和设计要求,研制了一种可满足多种需求的蒸汽发生器模拟体,模拟体总体结构设计为原型二分之一,选用复合材料,并设置有观察窗。模拟体具有结构紧凑、经济性高、可观测等特点。功能试验验证结果表明,本文所述蒸汽发生器模拟体可有效用于核电厂蒸汽发生器的检修培训。     

次临界反应性测量方法研究

压水堆启动前需要进行物理启动试验,其中调临界是相对耗时的一部分。采用次临界条件下的试验,可以省去调临界的步骤,提高物理启动试验的安全性和适用性,加速物理启动试验的进程,提高压水堆的负荷因子。目前,次临界反应性测量受限于测量信号较弱,背景噪声强,误差较大,难以满足商用压水堆的工程应用要求。本文基于源倍增方法,利用空间重要性修正因子和信号线性修正提高次临界反应性测量的精度,成功地在核电厂首循环上实现了次临界反应性测量的蒙特卡罗方法计算,取得了较好的计算精度与效果。