Effect of cooling rate on the microstructure of electron beam welded joints of two-phase TiAl-based alloy

The analysis of the microstructural characterization and phase composition of electron beam welded joint zones of Ti- 43Al-9V-O. 3Y alloy has been done in this study. The welded seam is mainly composed of B2 phase, the partial γ ＋ α2 twophase lamellar structure and granular γm phase. And the lanthanon Y existed as YAl2 phase and served as grain refined. The impact of different cooling rates on joint microstructure, fracture characteristic and tensile strength were investigated. The high cooling rate restrained the structural transformation and resulted in the ordering structure. The fracture of the joint was brittle cleavage fracture because the ordering structure went against restraining the crack propagation. With the decrease of cooling rate, the transformation amounts of lamellar structure increased, and the fracture presented the layered and crosslayered characteristic.     

On the mechanical performance of closed cell Al alloy foams

The mechanical properties of three different commercially available closed cell Al alloys all made by foam casting are examined. The objective is to assess the roles of cell morphology and of imperfections in governing the basic properties: stiffness, yield strength and fracture resistance. This assessment provides goals for manufacturing strategies that enable attainment of good mechanical performance with affordable process technologies. A prevalent role of curves and wiggles in the cell walls on stiffness and strength (anticipated by models) is affirmed by the present measurements. Systematically larger stiffnesses and yield strengths found in tension than in compression are consistent with a prominent role exerted by such imperfections. Moreover, foam casting is apparently capable of cell morphologies that impart properties approaching the best achievable values for an isotropic closed cell solid, devoid of imperfections. There are associated implications for performance and affordability. Fracture measurements indicate crack growth occurring along the cell walls by a mechanism analogous to the plastic tearing of thin sheets. The crack growth resistances are in the range of 1 kJm⁻². This mechanism infers a toughness that scales with the cell wall thickness and its yield strength.     

铝合金镀镉新工艺

从理论上对硬铝合金的浸锌工艺作了详细的论述。为使直升飞机机轮零件(硬铝材料)适应海洋气候,必须具有足够的抗盐雾性气氛腐蚀能力,锌酸盐浸工艺是提高抗腐蚀能力的较好方法,对硬铝合金的镀镉进行了试验并获得成功,投入了批量生产。     

离子硫氮磷共渗层表层形貌与相结构研究

采用扫描电镜、能谱仪、Ｘ射线衍射仪等分析研究了离子硫氮碳共渗层表面与次表面形貌特征与相结构，探讨了其形成机制．结果表明：硫氮碳共渗表层为以硫化物颗粒组成的多层层状结构，其成分及层数随共渗气氛硫势的变化而变化；次表层为致密的氮碳化物层和氮、碳扩散层，这种渗层结构是其具有良好减摩性、跑合性与耐磨性的原因．     

激光焊接牙科铸造纯钛研究

研究了激光焊接技术对牙科铸造纯钛的机械性能和耐腐蚀性能的影响.用扫描电境观察焊缝区形貌并测试了焊件的抗拉强度.结果表明激光焊接对铸钛的机械性能及耐应力腐蚀性能无明显影响.     

FeMoAl COATING AND ITS HIGHTEMPERATURE SULFIDATION PROPERTIES

ＦｅＭｏＡｌＣＯＡＴＩＮＧＡＮＤＩＴＳＨＩＧＨＴＥＭＰＥＲＡＴＵＲＥＳＵＬＦＩＤＡＴＩＯＮＰＲＯＰＥＲＴＩＥＳ①ＬｉＦａｎｇ，ＨｅＹｅｄｏｎｇ，ＱｉＨｕｉｂｉｎ，ＨｕａｎｇＺｈｅｎｚｈｏｎｇ，ＺｈｕＲｉｚｈａｎｇＢｅｉｊｉｎｇＣｏｒｏｓｉｏｎａｎｄ...     

电脉冲孕育处理Al-22Si合金衰退性的研究

研究了电脉冲孕育处理后不同静置时间对Al-22Si合金凝固组织中初生相形态、大小、分布的影响。结果表明，电脉冲处理后立刻浇注对Al-22Si合金有较明显的变质作用，初生Si相形态由粗大板条状变为块状，其平均尺寸由153．15μm降至77．35μm，分布也较均匀；但电脉冲处理也存在着较明显的衰退性，即随着熔体静置时间的延长孕育效果逐渐消失，当静置时间为80min时，其组织形态与未经电脉冲处理的组织相似，其平均尺寸由77．35μm升至143．67μm。     

ZnO掺杂纳米CeO2的共沸蒸馏法合成

采用化学共沉淀法结合正丁醇共沸蒸馏处理前驱体合成了ZnO掺杂纳米CeO2颗粒,通过XRD,DSC/TG,IR,TEM,原子吸收光谱以及紫外透过率分析等方法对其结构和性能进行了表征;并根据XRD线宽法,由Scherrer公式计算其晶粒尺寸,研究了共沸蒸馏、ZnO掺杂、以及焙烧温度和时间对CeO2纳米晶粒尺寸的影响.结果表明正丁醇共沸蒸馏法能有效脱除前驱体凝胶中的水分,防止干燥和焙烧过程中硬团聚的形成,从而得到粒径更小、分布更均匀、分散性更好的纳米CeO2颗粒;2 mol%～10 mol%掺杂ZnO能与纳米CeO2形成固溶体,且掺入量增加引起纳米CeO2晶粒有所增大;随焙烧温度提高,ZnO掺杂纳米CeO2晶粒显著长大,而高温下随焙烧时间延长,其晶格进一步趋于完整,晶粒尺寸增加;纳米CeO2具有良好的可见光透过和紫外光吸收能力,ZnO掺杂不会影响纳米CeO2的紫外遮蔽效果.     

Nd2Mn17-xAlx(X=1～10)化合物的结构及其稳定性

用电弧炉熔炼制备了Nd2Mn17-xxAlx(x=1-10)样品，对其进行的粉末X－射线衍射研究表明，样品具有菱方相Th2Zn17型结构，随着Ai替代量的增加，Nd2Mn17-xxAlx(x=1-10)化合物样品的晶格常数a,c及单胞体积v都增加，对样品的时效研究表明，Nd2Mn17-xAlx(x=1-10)化合物在自然环境中十分稳定，这表明Al比C更能使富锰的2：17相（Th2Zn17)稳定。     

NiCrMo涂层在750℃硫酸盐中的热腐蚀行为

针对石油及化工设备在苛刻高温腐蚀条件下工作,其零件腐蚀破坏日益严重的现状,采用Q235钢为基体材料,对自行研制的NiCrMo涂层在750℃涂盐腐蚀中的热腐蚀行为进行了研究,并与母材Q235钢的性能进行了比较.采用金相显微镜、配有能谱分析仪的扫描电镜以及X射线衍射仪等检测设备对腐蚀产物的形貌和相组成等进行了分析.结果表明,在母材Q235钢表面涂覆层镍铬含量一定,有适当钼的NiCrMo涂层时,能形成对涂层进行保护的氧化膜,提高母材Q235钢的耐高温热腐蚀性能.这种镍基合金制备成涂层具有优良的抗热腐蚀性能,适于作为石油化工设备的防护材料.