Conductivity enhancement in transparetn ZnO films via Al-dopping produced by CW-CO2 laser-induced evaporation

Highly conductive transparent aluminium-doped ZnO (ZnO:A1) films were successfully deposited by CW-CO₂ laser-induced evaporation. Optimisation of evaporation parameters was based on laser power, substrate temperature, O₂ partial pressure in the vacuum chamber and amount of Al in the ZnO source pellet. ZnO:A1 films with an electrical resistivity as low as 6.6 × 10⁻²Ω·cm and an optical transmission of 80% at 500nm were obtained at laser power of 15 W, substrate temperature of about 200°C, O₂ partial pressure of 6—7 × 10⁻⁴ Torr and 5wt.% Al. Conductivity of ZnO films can be increased one order via Al-doping in ZnO films. The films obtained by laser-induced evaporation have compared quite favorably with the high quality films obtained by sputtering.     

稀土含量对喷熔层组织及耐蚀性的影响

本文通过在镍基自熔合金粉末中加入不同含量的稀土，研究了稀土含量对喷熔层组织及耐蚀性的影响规律及其作用机制。结果表明，在喷熔材料中加入适量稀土，可使喷熔层组织细化、晶界净化，从而使腐蚀过程中的表面活性点减少，耐蚀性提高。     

锻压机械打击力测量误差的加速度补偿

提出了锻压机械打击力测量中存在的问题，介绍了常用的补偿法，并通过实验验证了加速度补偿法是消除锻压机械打击力测量误差的有效途径。     

实施国库集中支付制度存在问题与建议

按照财政部国库管理制度改革统一要求，鄂尔多斯市开展了国库集中支付试点工作。运行过程中，一些阻碍改革运行的问题引起笔者的思考。文中介绍了笔者当地实施改革试点存在的突出问题，如电脑网络不完善情况下国库集中支付操作难以运行、预算编制不能满足国库支付的基本要求、国库支付系统与银行业务收支不兼容、财政收支进度不一致、财政财力供给不足给集中支付造成瓶颈制约、政策法规出台滞后、改革现行的财政支出管理体系阻力很大、政府采购项目及资金审批程序不规范等。笔者并结合问题大胆提出了自己对推进的改革的措施和建议，即加强组织领导、强化理论学习借鉴、彻底清理银行账户、加强网络建设、制定切实可行的改革方案及配套办法、加快行政审批服务制度的改革、改革传统发放工资制度、进一步规范政府采购制度。     

新型节能玻璃钢门窗的研究

本文主要围绕节能主题，从能耗方式、性能指标、结构形式、制作安装等方面论述了玻璃钢门窗在不同气候地区、不同环境和不同领域中的开发和应用。     

Synthesis and Morphology of TiO2 Nanotube Arrays by Anodic Oxidation Using Modified Glycerol-Based Electrolytes

Titanium dioxide (TiO₂) nanotube arrays were prepared by electrochemical anodization of titanium sheets in the glycerol 176 mL/H₂O 44 mL/NH₄F 0.5 wt% electrolytes modified with H₂SO₄ and NaAc addition. The surface morphologies, average inner diameter, and the length of the nanotube arrays changed with the solution pH in the range from 5.6 to 4.0 by adding H₂SO₄. A uniform surface morphology of the nanotubes with average inner diameter of ∼80 nm and a length of ∼1000 nm was obtained when the solution pH was 5.0. The growth rates of the nanotubes were remarkably enhanced by NaAc addition in the range of 0.04–0.14 M . With NaAc addition of 0.10 M , the length of the nanotube arrays reached 4.16 μm after an 8-h anodization, increasing 3.23 μm compared with no NaAc addition. The relationship between solution pH and growth of TiO₂ nanotubes was analyzed by current–time curves, solution electrical conductivities, and scanning electron microscopy (SEM), and the role of NaAc was also discussed based on SEM and solution electrical conductivities.     

Carbon molecular sieve films produced by dc sputtering

This paper reports adsorption measurements that show molecular sieve effects in amorphous hydrogenated carbon (a-C : H) films deposited by d.c. magnetron discharge decomposition of acetylene. Adsorption of organic gases on the films is studied by using a quartz crystal microbalance technique. The sieve effect in this material depends on both deposition and annealing conditions. Films having significant molecular sieve effects are found to be typically microporous and to have a very small characteristic micropore dimension. It is suggested that the d.c. sputtered a-C : H film may be useful as a molecular sieve material in selective adsorption and gas permeation studies.     

策应鄱阳湖生态经济区建设 推动吉安进位赶超绿色崛起

建设鄱阳湖生态经济区是国家从战略全局和长远发展出发作出的一项重大决策。如何主动策应鄱阳湖生态经济区建设,推动吉安进位赶超、跨越发展,是摆在我们各级政府和科技部门面前一项亟待解决的问题。为此,一是要提高认识,统一思想,切实增强策应规划的使命感和责任感;二是要结合实际,突出重点,全面对接鄱阳湖生态经济区规划;三是要加强领导,落实措施,确保吉安进位赶超、绿色崛起取得明显成效。     

新自由主义中的政府与市场理论述评

作为凯恩斯主义的反对者,新自由主义以抵制政府干涉,提倡自由市场竞争的面目出现,在一定程度上被看做是对古典自由主义的复辟,但它绝不仅仅是对古典"放任自由"的一种简单继承。对新自由主义主流学派关于政府与市场理论进行考察,理清新自由主义理论思想,从而对其有一个更客观的认识和评价。     

Preparation and characterization of polyelectrolyte copolymers containing methyl methacrylate and 2-hydroxyethyl methacrylate. I. Polymers based on methacrylic acid

Acidic polyelectrolyte copolymers containing 2-hydroxyethyl methacrylate (HEMA), methyl methacrylate (MMA), and methacrylic acid (MAA) were prepared by free radical polymerization to high conversion in solution. Copolymer yields were obtained by gravimetry (all in the 30–50% range), relative molecular weights estimated by intrinsic viscosity measurements (all in the 50–70 cc/g range), tacticity by ¹³C nuclear magnetic resonance (NMR) spectroscopy (all polymers predominantly syndiotactic with some atactic content), and composition by acid/base titrations in conjunction with ¹H-NMR spectroscopy (all close to the monomer charge ratios). Acid strengths or apparent pKa's were examined as a function of extent of ionization. Measurements performed in water indicated that the compact/extended coil transformation in predominantly syndiotactic polymethacrylic acid occurs also in copolymers of similar tacticity containing moderate to high concentrations of MAA. The apparent pKa of such polymers containing only small amounts of MAA did not vary with extent of ionization, indicating a low degree of interaction between the acid groups. In copolymer pairs containing similar amounts of MAA but differing HEMA and MMA contents, the polymer containing more HEMA appeared the stronger acid, presumably due to a better solvation of that polymer which would increase the net spatial charge–charge separation and decrease cooperative effects that lead to suppressed ionization.