Charge ordering state of mixed-valence (TP-EDTT)3(PF6)2

4,5-Ethylenedithio-2-(thiopyran-4-ylidene)-1,3-dithiole (TP-EDTT) and its radical cation salts were prepared. Conventional galvanostatic electrocrystallization gave (TP-EDTT)₂SbF₆, (TP-EDTT)GaCl₄, (TP-EDTT)ReO₄, and (TP-EDTT)₃(PF₆)₂. The variation of bond lengths upon the charge of each molecule was examined based on 0, +0.5, and +1.0-charged TP-EDTT molecules. Applying the relationship between the charge and the bond lengths to the donor molecules, (TP-EDTT)₃(PF₆)₂ was proved to be a charge ordering system.     

Vinyl polymerization by metal complexes, 26. Vinyl polymerization initiated by polyvinylamine-copper(II) chelate in dimethylsulfoxide solution

The polymerization of acrylonitrile and methyl methacrylate initiated by polyvinylamine-copper(II) chelate was studied in dimethylsulfoxide solution, in the presence and absence of carbon tetrachloride. For comparison, the dimeric chelate(1,3-diaminopropane-copper(II) chelate) was also chosen as an initiator. The initiation activity of the dimeric chelate was found to be higher than that of the polymeric chelate in dimethylsulfoxide solution, different from the cases in aqueous media. The dimeric chelate could initiate the polymerization of acrylonitrile effectively, even in the absence of carbon tetrachloride.     

The spinnability of polymer fluid filaments

A theoretical study of the stability of extending liquid filaments has been carried out. The interaction of surface tension and different fluid rheological properties is investigated. It is also hypothesized that cohesive failure or fracture will occur if a critical stress level is reached. It is predicted that viscosity and viscoelasticity tend to stabilize the filaments. However, even extremely high viscosity filaments will neck and exhibit ductile failure. In highly viscoelastic fluids, defects tend to heal during stretch. Highly viscoelastic fluid filaments fail by fracture. The theory is used to predict the failure of molten polymer filaments as a function of molecular weight. The extensibility or spinnability of filaments is predicted to exhibit a maximum at intermediate molecular weights with capillarity-ductile failure occurring at low molecular weights and cohesive fracture, at high molecular weights. The results are compared to experiments on polyethylenes. There is general qualitative agreement especially with the behavior of low and high molecular weights where capillarity and fracture occur. The tendency to necking and ductile failure differs considerably among melts and is more pronounced in high-density than in low-density polyethylenes. The application to continuous spinline behavior is discussed, and draw resonance is suggested to be the continuous process analogue of ductile failure.     

Additive effect of CF3Cl on OH, CH, and C2 emissions: Shock tube study with C2H4---O2---CF3Cl and CH4---O2---CF3Cl mixtures

Mixtures of C₂H₄---O₂---CF₃Cl and CH₄---O₂---CF₃Cl, highly diluted with argon, were heated to the temperature range 1350–2200K behind reflected shock waves, and the additive effects of CF₃Cl on OH^*, CH^*, and C₂^* emissions in the ethylene and methane combustion processes were examined by observing the delay time, and the intensities of OH^*, CH^*, and C₂^* emissions. It was found that, in ethylene combustion, the addition of CF₃Cl prolonged the delay times to the maximum intensities, decreased the intensities of OH^* and CH^* emissions, and had little influence on that of C₂^* emission. However, in methane combustion, it was found that the addition of CF₃Cl shortened the delay times to the maximum intensities and to the onset of ignition, increased the intensities of CH^* and C₂^* emissions, and had little influence on that of OH^* emission.     

Contact-based stiffness sensing of human eye.

Goldmann applanation tonometry is commonly used for measuring intraocular pressure (IOP) to diagnose glaucoma. However, the measured IOP by conventional applanation tonometry is valid only under the assumption that all subjects have the same structural eye stiffness. This paper challenges in vivo measurement of eye stiffness with a noninvasive approach and investigates individual differences of eye stiffness. Eye stiffness is defined by the applied force and displacement of the cornea. The displacement is detected based on captured images by a high resolution camera. The experimental results show that the measured stiffness nicely matches the analytical result that is derived from a simple spherical deformation model with an internal pressure. However, some subjects have different eye stiffness even with the same IOP. IOP with abnormal stiffness may be over/underestimated by conventional applanation tonometry. The proposed eye stiffness measurement can help detect the misestimated eye and it contributes to the early detection of glaucoma.     

Fabrication of a PTFE-filled waveguide for millimeter-wave components using SR direct etching

PTFE is widely used as a microwave and millimeter-wave material. However, it is known that PTFE is a difficult material to cut at high precision by conventional machining, or even by laser cutting or electrical discharge machining. It has been reported that PTFE microstructures can be fabricated by direct exposure to synchrotron radiation. A metallic waveguide is one of effective media guiding a millimeter- and submillimeter-wave because of the advantage of low loss. In this paper, the SR direct etching of PTFE is introduced and a trial fabrication of millimeter-wave PTFE waveguide is attempted.     

Experimental Investigation of Multihazard Resistant Bridge Piers Having Concrete-Filled Steel Tube under Blast Loading

This paper presents the development and experimental validation of a multizard bridge pier concept, i.e., a bridge pier system capable of providing an adequate level of protection against collapse under seismic and blast loading (but not acting simultaneously). A multicolumn pier-bent with concrete-filled steel tube (CFST) columns is the proposed concept, and the adequacy of this system is experimentally investigated under blast loading. This paper describes simplified blast analysis, multihazard design of bridge piers, and blast experimental program and results. Additionally, the results from the blast experiments are compared with the results from the simplified method of analysis considering an equivalent single degree of freedom system having an elastic-perfectly plastic behavior. It is found that prototype bridge CFST columns can be designed to provide both satisfactory seismic performance and adequate blast resistance. It is also shown that the CFST columns exhibited a ductile behavior under blast load in a series of tests at 1/4 scale. Maximum deformation of the columns could be calculated using simplified analysis considering a factor to account for the reduction of pressures on the circular column and determined from this experimental program.     

Ligand‐Free and Heterogeneous Palladium on Carbon‐Catalyzed Hetero‐Suzuki–Miyaura Cross‐Coupling

A ligand‐free and heterogeneous palladium on carbon (Pd/C)‐catalyzed hetero‐Suzuki–Miyaura coupling reaction has been developed. The protocol enables the construction of both heterocyclic‐alicyclic and heterocyclic‐heterocyclic biaryl derivatives in good to excellent yields. Furthermore, Pd/C could be reused. The time‐course study clarified that palladium was leached into the reaction media as the reaction proceeded and then completely deposited on the carbon support.     

GaAs solar cells grown on Si substrates for space use

GaAs single‐junction and InGaP/GaAs multi‐junction thin‐film solar cells fabricated on Si substrates have great potential for high‐efficiency, low‐cost, lightweight and large‐area space solar cells. Heteroepitaxy of GaAs thin films on Si substrates has been examined and high‐efficiency GaAs thin‐film solar cells with total‐area efficiencies of 18·3% at AM0 and 20·0% at AM 1·5 on Si substrates (GaAs‐on‐Si solar cells) have been fabricated. In addition, 1‐MeV electron irradiation damage to GaAs‐on‐Si cells has been studied. The GaAs‐on‐Si cells are found to show higher end‐of‐life efficiency than the conventional GaAs cells fabricated on GaAs substrates (GaAs‐ on‐GaAs cells) under high‐fluence 1‐MeV electron irradiation of more than 1 × 10¹⁵ cm⁻². The first space flight to make use of them has been carried out. Forty‐eight 2 × 2 cm GaAs‐on‐Si cells with an average AM0 total‐area efficiency of 16·9% have been evaluated in the Engineering Test Satellite No.6 (ETS‐VI). The GaAs‐on‐Si cells have been demonstrated to be more radiation‐resistant in space than GaAs‐on‐GaAs cells and 50, 100 and 200‐μm‐thick Si cells. These results show that the GaAs‐on‐Si single‐junction and InGaP/GaAs‐on‐Si multi‐junction cells have great potential for space applications. Copyright © 2001 John Wiley & Sons, Ltd.