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排序方式: 共有1207条查询结果,搜索用时 15 毫秒
31.
Amakura Y Tsutsumi T Sasaki K Maitani T 《Shokuhin eiseigaku zasshi. Journal of the Food Hygienic Society of Japan》2003,44(6):321-327
To determine polychlorinated dibenzo-p-dioxins (PCDDs), polychlorinated dibenzofurans (PCDFs) and coplanar polychlorinated biphenyls (Co-PCBs) in green leafy vegetables, the cleanup method was modified, and packing methods for a multi-layer silica gel column were compared in food samples. First, the additional cleanup was examined for a mono-ortho PCBs fraction obtained by alumina column chromatography from spinach extract. Small solids such as rough crystals that remained after concentration of the mono-ortho PCBs fraction were identified as long-chain hydrocarbons from leaf epicuticular wax by GC/MS. Cleanup using an activated carbon silica gel column with n-hexane as the washing solvent was effective. Next, multi-layer silica gel columns packed by wet packing and dry packing were compared using komatsuna, salmon and butter as samples. The columns prepared by both methods gave similar values at each isomeric concentration level and showed similar efficiency with favorable recoveries. 相似文献
32.
The role of ergosterol in yeast stress tolerance, together with heat shock proteins (hsps) and trehalose, was examined in a sterol auxotrophic mutant of Saccharomyces cerevisiae. Ergosterol levels paralleled viability data, with cells containing higher levels of the sterol exhibiting greater tolerances to heat and ethanol. Although the mutant synthesised hsps and accumulated trehalose upon heat shock to the same levels as the wild-type cells, these parameters did not relate to stress tolerance. These results indicate that the role of ergosterol in stress tolerance is independent of hsps or trehalose. 相似文献
33.
Xiaohan Zhang Crystal Young Yoshiaki Morishita Kookjoo Kim Omer O. Kabil Oliver B. Clarke Bruno Di Jeso Peter Arvan 《International journal of molecular sciences》2022,23(21)
The primary functional units of the thyroid gland are follicles of various sizes comprised of a monolayer of epithelial cells (thyrocytes) surrounding an apical extracellular cavity known as the follicle lumen. In the normal thyroid gland, the follicle lumen is filled with secreted protein (referred to as colloid), comprised nearly exclusively of thyroglobulin with a half-life ranging from days to weeks. At the cellular boundary of the follicle lumen, secreted thyroglobulin becomes iodinated, resulting from the coordinated activities of enzymes localized to the thyrocyte apical plasma membrane. Thyroglobulin appearance in evolution is essentially synchronous with the appearance of the follicular architecture of the vertebrate thyroid gland. Thyroglobulin is the most highly expressed thyroid gene and represents the most abundantly expressed thyroid protein. Wildtype thyroglobulin protein is a large and complex glycoprotein that folds in the endoplasmic reticulum, leading to homodimerization and export via the classical secretory pathway to the follicle lumen. However, of the hundreds of human thyroglobulin genetic variants, most exhibit increased susceptibility to misfolding with defective export from the endoplasmic reticulum, triggering hypothyroidism as well as thyroidal endoplasmic reticulum stress. The human disease of hypothyroidism with defective thyroglobulin (either homozygous, or compound heterozygous) can be experimentally modeled in thyrocyte cell culture, or in whole animals, such as mice that are readily amenable to genetic manipulation. From a combination of approaches, it can be demonstrated that in the setting of thyroglobulin misfolding, thyrocytes under chronic continuous ER stress exhibit increased susceptibility to cell death, with interesting cell biological and pathophysiological consequences. 相似文献
34.
A study on the kinetics and mechanism of the polymerization of acrylonitrile initiated by imidazole and 2-substituted imidazole-copper-(II) complexes was made in dimethyl sulfoxide solution at 40–70°C. The rate of polymerization, Rp, could be expressed as follows: The overall activation energies of these polymerization processes are in a range from 14.2 to 69.1 KJ mole-1. From the data of electronic spectra and electron paramagnetic resonance, it was confirmed that the polymerization in question could be initiated by free radicals which were formed by the reduction of copper-(II) complex to copper-(I) complex, and the latter formed a new complex with polyacrylonitrile resulted. 相似文献
35.
We report here the fabrication of freestanding HfO2 grating by combining fast atom beam etching (FAB) of HfO2 film with dry etching of silicon substrate. HfO2 film is deposited onto silicon substrate by electron beam evaporator. The grating patterns are then defined by electron beam lithography and transferred to HfO2 film by FAB etching. The silicon substrate beneath the HfO2 grating region is removed to make the HfO2 grating suspend in space. Period- and polarization-dependent optical responses of fabricated HfO2 gratings are experimentally characterized in the reflectance measurements. The simple process is feasible for fabricating freestanding HfO2 grating that is a potential candidate for single layer dielectric reflector.PACS: 73.40.Ty; 42.70.Qs; 81.65.Cf. 相似文献
36.
37.
Kazumasa Ide Masatoshi Watanabe Masaki Sato Miyoshi Takahashi Noriyoshi Takahash 《Electrical Engineering in Japan》1995,115(3):108-119
This paper describes relationships between characteristics of a magnetically anisotropic slot wedge and voltage higher harmonics in an ac exciting synchronous generator terminal due to permeance ripple caused by an open-slot-type rotor. From the relationships obtained, practical guidelines were formulated for machine designs applying the magnetically anisotropic slot wedge. The results are as follows.
- 1 (1) Equivalent permeability of the magnetically anisotropic slot wedge became isotropic wedge permeability for air-gap flux ripple.
- 2 (2) Two ways were identified to reduce voltage-higher harmonics by using the slot wedges.
- 3 (3) The level of leakage flux passing through the anisotropic slot wedge was determined only by its permeability in the width direction.
- 4 (4) Effectiveness of the magnetic anisotropic slot wedges inserted into the stator slots was verified from experimental results using a model machine of the open- slot-type rotor.
38.
Thermal desorption aerosol mass spectrometers (TDAMSs) with electron ionization are widely used for quantitative analysis of aerosol chemical composition, and the ionization efficiency of evolved gas molecules from aerosol particles is an important parameter for such analysis. We performed laboratory experiments using a custom-made TDAMS to investigate the key factors affecting ionization efficiency. Ammonium chloride (NH4Cl) and ammonium iodide (NH4I) were used as test compounds because their thermal decomposition products are expected to be simple (dominated by ammonia (NH3) and hydrogen halide (HX)). The ion signals originating from NH3 and HX were measured by altering the position of the ionizer relative to the vaporization point. The ratio of ion signal from NH3 to that from HX increased with increasing divergence angle of evolved gas plumes, which suggests that the angular distribution of gas molecules could be an important factor affecting the ionization efficiency.
Copyright © 2018 American Association for Aerosol Research 相似文献
39.
Masaki Honda Hakuto Kageyama Takashi Hibino Rungaroon Waditee‐Sirisattha Tetsuya Fukaya Yoshiaki Hayashi Motonobu Goto 《European Journal of Lipid Science and Technology》2020,122(3)
Z‐isomers of lycopene exhibit higher bioavailability and antioxidant capacity than those of the all‐E‐isomer. Therefore, it is important to develop an efficient and environmentally friendly procedure for Z‐isomerization. The current methods for Z‐isomerization of (all‐E)‐lycopene use toxic chemicals such as organic solvents and catalysts. This study is aimed to develop a chemical‐free method for Z‐isomerization of (all‐E)‐lycopene in tomato powder by hot air and superheated steam heating. The Z‐isomerization reaction is promoted by heating above the melting point of lycopene. When heated with superheated steam, the thermal decomposition of lycopene is suppressed compared to that when heated with hot air. When tomato powder is heated at 240 °C for 5 min by superheated steam, the total Z‐isomer content and remaining lycopene are 69.0% and 90.7%, respectively, while with hot air heating, the total Z‐isomer content and remaining lycopene are 69.9% and 68.0%, respectively. These results indicate that the thermal Z‐isomerization of lycopene occurs in the molten state and heating in a low oxygen atmosphere suppresses the thermal decomposition of lycopene. Practical Applications: Tomato powder rich in lycopene Z‐isomers is an important ingredient for the food and animal feed industries. Since Z‐isomers of lycopene are more soluble in solvents including ethanol which is a low‐toxicity and environmentally friendly solvent, the efficiency of lycopene extraction with ethanol can be improved by using the Z‐isomer‐rich tomato powder as a raw material. The obtained Z‐isomer‐rich extract has a high added value because the Z‐isomers have higher bioavailability and antioxidant capacity than those of the all‐E‐isomer. In addition, since lycopene Z‐isomers exhibit higher accumulation efficiency and better color improvement in hen egg yolks than those of the all‐E‐isomer, Z‐isomer‐rich tomato powder is an effective animal feed. 相似文献
40.
Several hexaaluminate-related materials were prepared via hydrolysis of alkoxide and powder mixing method for high temperature combustion of CH4 and C3H8, in order to investigate the effect of the concentration of the fuels, O2 and H2O on NOx emission and combustion characteristics. Among the hexaaluminate catalysts, Sr0.8La0.2MnAl11O19− prepared by the alkoxide method exhibited the highest activity for methane combustion and low NOx emission capability. NOx emission at 1500 °C was increased linearly with O2 concentration, whereas water vapor addition decreased NOx emission in CH4 combustion over the Sr0.8La0.2MnAl11O19− catalyst. In the catalytic combustion of C3H8 over the Sr0.8La0.2MnAl11O19− catalyst, the amount of NOx emitted was raised in the temperature range between 1000 and 1500 °C when the C3H8 concentration increased from 1 to 2 vol.%. It was found that NOx emission in this temperature range was reduced effectively by adding water vapor. 相似文献