The Effect of Air Foam Inclusion on the Permeability and Absorption Properties of Light Weight Soil

Cement-treated clay with air foam, which is called Super Geo-Material (SGM), was developed to utilize dredged clay in an effective way. As SGM is mainly used at levels below the ground water table, water permeability and absorption properties of SGM will affect the durability of the material. In this research, the changes in SGM permeability and absorption as functions of the air foam fraction were investigated. First, permeability tests with triaxial apparatus and constant rate of consolidation tests were conducted on samples containing less than 10% of air foam by volume. From the results, air foam was found to be an impermeable medium in SGM. Secondly, a series of permeability tests and absorption tests were conducted for the SGM with different fractions of air foam while observing the specimen with a micro focus X-ray Computed Tomography (CT) scanner. The results showed that the permeability of SGM increased dramatically due to the appearance of interior water channels when the air foam fraction exceeded 30% by volume. The density distribution change and water absorbed zones of the specimens during absorption tests were estimated using the X-ray CT data. From these results, the air in the SGM was found to be progressively substituted with water from the surface to the inside of the specimen and the substituted zone expanded as it made its way to the specimen interior. The expansion velocity of the substituted zone was not affected by the coefficient of permeability but by the fraction of the air in the specimen.     

Kinetic analysis of NaF vaporization in SiF4-Ar mixture

Slags used in steelmaking and continuous casting that contain SiO₂, Na₂O, and CaF₂ tend to be unstable and gaseous. Species, such as NaF and SiF₄, evolve simultaneously from these slags at steelmaking temperatures. In addition, the reaction between NaF and SiF₄ can occur to produce Na₂SiF₆ (sodium hexafluorosilicate). In a previous study on the vaporization of NaF into an inert gas stream, the diffusivity of NaF in argon, nitrogen, and helium was measured. In this study, the rate of NaF vaporization in a SiF₄ atmosphere was measured. Ternary diffusion coefficients were then evaluated from the binary diffusion coefficients obtained in a previous study, and a kinetic analysis was carried out. The rate calculations were found to be in accord with the measured results, indicating that the experiments were carried out in a regime where diffusion of NaF from the surface of the sample was rate controlling.     

Molecular recognition by wall-assembling-type nanocavity in aqueous media

Steroid cyclophanes, each having a macrocyclic ring attached to four bile acid moieties via chiral lysine connectors, were synthesized, and the binding of the 2-naphthylphenylketone (guest) to the steroid cyclophanes in water was investigated. The circular dichroism spectra of the steroid cyclophane with cholic acid and L-lysine were significantly affected by the binding of the guest, and the induced circular dichroism based on the absorption of the achiral guest was also observed. The binding of the guest to the steroid cyclophane with cholic acids and D-lysines induced changes in the circular dichroism spectra with the opposite sign of the molecular ellipticities. An induced circular dichroism spectral change was not observed upon binding of the guest to the analogous host without OH sites. These results strongly suggest that the guest is conformationally fixed through hydrogen bonding between the carbonyl group of the guest and the steroidal hydroxyl group of the host. The assembly of only four steroid residues on the macrocyclic ring probably provided a hydrophobic nanocavity for hydrogen bonding.     

Kinetics of formation and dissociation of Na2SiF6

Spontaneous fluoride emissions from high-temperature processes can result in an increased atmospheric fluorine content and environmental contamination. Slags containing SiO₂, Na₂O, and CaF₂ tend to be unstable at high temperatures, and gaseous species such as NaF and SiF₄ evolve simultaneously. Furthermore, a reaction between NaF and SiF₄ can occur to produce Na₂SiF₆ (sodium hexafluorosilicate), the behavior and properties of which are not well established. In a previous study, the diffusivity of NaF in argon, nitrogen, and helium was measured. In this study, the rate of NaF vaporization in a SiF₄-Ar atmosphere was investigated and the rates of formation and dissociation of Na₂SiF₆ were measured. Kinetic analyses were carried out and the rate constants of the formation and dissociation of Na₂SiF₆ were obtained. The rate equation for Na₂SiF₆ formation was expressed as follows:

Dependence of ion selectivity on ordered orientation of neutral carriers in ion-sensing membranes based on thermotropic liquid crystals

Thermotropic liquid-crystalline compounds were applied as membrane materials (membrane solvent and neutral carrier) for neutral carrier-type ion sensors to investigate how the ordered arrangement of neutral carriers affects the property of the resulting ion sensors. Nematic, smectic, and cholesteric liquid-crystalline compounds were used as the membrane solvents and crown ether derivatives with a molecular structure similar to the liquid-crystalline solvent as the K+ neutral carriers. Polarized IR spectroscopy and X-ray diffraction experiments confirmed that the highly ordered arrangement of membrane components was retained in the liquid-crystal-based ion-sensing membranes containing a neutral carrier and a lipophilic salt. The ordered arrangement of neutral carriers in the liquid-crystalline membranes enhanced the ion selectivity significantly, probably due to the efficient cooperation of two adjacent crown ether moieties in the highly ordered and aggregated state.     

An algorithm for similar utterance section extraction for managing spoken documents

This paper proposes a new, efficient algorithm for extracting similar sections between two time sequence data sets. The algorithm, called Relay Continuous Dynamic Programming (Relay CDP), realizes fast matching between arbitrary sections in the reference pattern and the input pattern and enables the extraction of similar sections in a frame synchronous manner. In addition, Relay CDP is extended to two types of applications that handle spoken documents. The first application is the extraction of repeated utterances in a presentation or a news speech because repeated utterances are assumed to be important parts of the speech. These repeated utterances can be regarded as labels for information retrieval. The second application is flexible spoken document retrieval. A phonetic model is introduced to cope with the speech of different speakers. The new algorithm allows a user to query by natural utterance and searches spoken documents for any partial matches to the query utterance. We present herein a detailed explanation of Relay CDP and the experimental results for the extraction of similar sections and report results for two applications using Relay CDP. Yoshiaki Itoh has been an associate professor in the Faculty of Software and Information Science at Iwate Prefectural University, Iwate, Japan, since 2001. He received the B.E. degree, M.E. degree, and Dr. Eng. from Tokyo University, Tokyo, in 1987, 1989, and 1999, respectively. From 1989 to 2001 he was a researcher and a staff member of Kawasaki Steel Corporation, Tokyo and Okayama. From 1992 to 1994 he transferred as a researcher to Real World Computing Partnership, Tsukuba, Japan. Dr. Itoh's research interests include spoken document processing without recognition, audio and video retrieval, and real-time human communication systems. He is a member of ISCA, Acoustical Society of Japan, Institute of Electronics, Information and Communication Engineers, Information Processing Society of Japan, and Japan Society of Artificial Intelligence. Kazuyo Tanaka has been a professor at the University of Tsukuba, Tsukuba, Japan, since 2002. He received the B.E. degree from Yokohama National University, Yokohama, Japan, in 1970, and the Dr. Eng. degree from Tohoku University, Sendai, Japan, in 1984. From 1971 to 2002 he was research officer of Electrotechnical Laboratory (ETL), Tsukuba, Japan, and the National Institute of Advanced Science and Technology (AIST), Tsukuba, Japan, where he was working on speech analysis, synthesis, recognition, and understanding, and also served as chief of the speech processing section. His current interests include digital signal processing, spoken document processing, and human information processing. He is a member of IEEE, ISCA, Acoustical Society of Japan, Institute of Electronics, Information and Communication Engineers, and Japan Society of Artificial Intelligence. Shi-Wook Lee received the B.E. degree and M.E. degree from Yeungnam University, Korea and Ph.D. degree from the University of Tokyo in 1995, 1997, and 2001, respectively. Since 2001 he has been working in the Research Group of Speech and Auditory Signal Processing, the National Institute of Advanced Science and Technology (AIST), Tsukuba, Japan, as a postdoctoral fellow. His research interests include spoken document processing, speech recognition, and understanding.     

Magnetic Interaction in Insulating Cuprates

We examine two-spin (2S) and cyclic four-spin (4S) magnetic interactions in insulating ladder and two-dimensional (2D) cuprates. By a comparison of eigenstates between d-p and Heisenberg models, we evaluate magnitudes of these interactions. We find that the 4S interaction is 10 % of nearest neighboring 2S interaction, and a diagonal 2S interaction is considerably small. The 4S interaction for a ladder cuprate is larger than that for 2D one, and plays an important role in the low-energy excitation. The Heisenberg ladder with the obtained 2S and 4S interactions reproduces very well the experimental result of the temperature dependence of the magnetic susceptibility.     

A new blood compatible and permselective hollow fiber membrane for hemodialysis

The authors have prepared a blood compatible and highly permselective hemodialysis membrane composed of polyether segmented nylon. This block copolymer was synthesized by polycondensation of bis-3-aminopropyl-poly(tetramethylene oxide) (PTMO) and poly(imino-1,3-bismethyl-cyclohexyl-iminoisophtharoyl) (NyBl) prepolymer obtained by polycondensation of 1,3-bis(aminomethyl)cyclohexane (B) and isophthalic acid (I). The molecular weight (MW) calculated from the number of end-groups was 16,000-21,000. In vitro blood compatibility was evaluated in terms of platelet adhesion onto the surface. PTMO-NyBl surfaces showed excellent platelet adhesion preventing properties. The PTMO-NyBl hollow fiber membrane was obtained by a dry-wet spinning process. The membranes had higher permeability coefficients for macromolecules ranging from MW 10,000 to 20,000 than polysulfone hollow fiber membrane (PS membrane), and had acceptably low albumin permeability for use as a dialysis membrane. The ex vivo blood compatibilities of PTMO-NyBl membrane and PS membrane were investigated by extracorporeal circulation in a pig model. The PTMO-NyBl membrane gave excellent results when assessing hemodialysis leukopenia, oxidative burst, and free platelet count decrease.