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11.
Silica-supported cobalt catalysts for the selective reduction of nitrogen monoxide with propene 总被引:1,自引:0,他引:1
Megumu Inaba Yoshiaki Kintaichi Masaaki Haneda Hideaki Hamada 《Catalysis Letters》1996,39(3-4):269-274
Catalytic behavior of silica-supported transition metals for NO reduction with propene in the presence of oxygen was investigated. While both silica and cobalt oxides did not show any activity for the selective NO reduction, impregnated CoO/SiO2 prepared from cobalt acetate showed good activity although the preparation conditions had significant effect on the activity. It was suggested that highly dispersed surface Co2+ ions on silica are responsible for the catalytic activity. 相似文献
12.
The synthesis of super-microporous aluminosilicate with a pore diameter of 14.6 Å has been achieved, by means of synthesis under specified conditions with a skeletal material comprising TMOS and a small quantity of sodium aluminate, and a conventional alkyl-trimethylammonium halide (C10TMABr) as a template. This super-microporous aluminosilicate has an adsorption capacity of 0.2 ml/g at a relative water vapor pressure of 0.2, and thus is promising as an adsorbent for an adsorption heat-pump. 相似文献
13.
Viscoelastic properties of poly(isoprene-b-styrene) in dioctylphthalate under steady shear flow were measured near the order—disorder transition temperature. In ordered states, first normal stress difference N1 is proportional to shear rate
at low
region, but becomes proportional to
at the high
region, similar to the N1 behaviour of polymer blends undergoing shear-induced homogenization. Because the existence of microdomains was confirmed at the high
region by the flow birefringence method, it is concluded that the above N1 behaviour is not caused by shear-induced homogenization, but is probably caused by the shear-induced alignment of the microdomain structure. 相似文献
14.
15.
Yoshiaki Katada Akihiro Nishiguchi Kazuya Moriwaki Ryosuke Watakabe 《Artificial Life and Robotics》2016,21(3):295-301
One approach in swarm robotics is homogeneous system which is embedded with sensing, computing, mobile and communication components. In this study, a target detection problem, which is one of navigation problems, was employed. Once a robot detects a target, robots immediately communicate with a base station via intermediate relay robots due to the multi-hop transmission of wireless communication. Therefore, this control task is completed with connectivity of the network. In a target detection problem, we must improve the performance of exploration as well as connectivity of the network. This study investigates the performances of the two types of random walk algorithm in navigation while loosely ensuring connectivity of the robotic network based on our previous study. 相似文献
16.
This paper reports a fundamental study of the stripe laminar flow pattern on a centrifugal microfluidic device with the goal of realizing a sedimentation-based, continuous mode particle separation technique. Microfluidic channels were designed with a concentrically integrated microchannel, and the patterning of the flow in the channel was investigated. A significant secondary flow was observed as a preliminary result. We conclude that the origin of this secondary flow was not the Dean force, because it was observed in a straight microchannel, but was not observed in curved channel during the spinning of the system at rest. The transition of the pattern was investigated using a simulation and experiment, and the flow pattern’s dependence on the rotational speed was determined, which suggested that the origin of the secondary flow was the Coriolis force. The significance of the secondary flow was controlled by adjusting the rotational speed of the disk, and the flow rate and laminar flow patterns were controlled by the stripe flow pattern. 相似文献
17.
Yoshiaki Ukita Kazuhiro Kanda Shinji Matsui Mitsuyoshi Kishihara Yuichi Utsumi 《Microsystem Technologies》2008,14(9-11):1567-1572
Polytetrafluoroethylene (PTFE) microstructures’ processing characteristics using X-ray photo dcomposition and desorption are studied in the highest energy region (2 keV to >12 keV). While the exposed surface states are seen melting and boiling from the remaining bubble structure of the irradiated surface, basic photochemistry of PTFE is also same as previous reports and high-aspect ratio structures are successfully formed. We developed new Ni stencil electroformed stencil masks and successfully fabricated first and practical example of PTFE micro fluidic parts. The characteristics of fabricated micro fluidic parts, a PTFE fluid filter for vertical fluid flow operation which works as passive valve, agreed with the calculated results. This suggests that the accuracy of patterning is adequate to apply this technique to fabricate microfluidic parts and other various microparts. 相似文献
18.
Yoshiaki Ukita Toshifumi Asano Kuniyo Fujiwara Katsuhiro Matsui Masahiro Takeo Seiji Negoro Yuichi Utsumi 《Microsystem Technologies》2008,14(9-11):1573-1579
The advantages of vertical microreactor stack with three-dimensional (3D) structure for immunoassay are discussed. The vertical microreactor stack uses vertical fluid flow operation with multifunctional fluid filters. The multi function of fluid filter is very effective for micromixing and passive valve operation. The mechanism of micromixing is discussed by using computational fluid dynamics (CFD), and we know that the mixing mechanism based on Coanda effect. To evaluate the micromixing performance of fluid filter, we demonstrated enzyme reaction with unique repeat mixing operation. As the results, we proved that the fluid filter has very effective mixing performance. The detection limit, which demonstrated by competition enzyme-linked immunosorvent assay (ELISA), is comparable with recommended detection limit, which suggested by Japanese ministry for the environment. 相似文献
19.
Summary 2,2-Dimethylazobenzenes having metal chelating ligands at meta-positions were synthesized, and the interaction with metal ions were estimated for syn- and anti-ligands on thermal isomerization. The azobenzenes with the metal-interaction were transformed to vinyl azobenzenes and copolymerized with styrene. The metal extracting ability was found in photo-isomerized polymer having syn-bis(iminodiacetic acid) groups; the selectivity was high for Cu(II) ion. 相似文献
20.
Yuichiro Ezoe Ikuyuki Mitsuishi Utako Takagi Masaki Koshiishi Kazuhisa Mitsuda Noriko Y. Yamasaki Takaya Ohashi Fumiki Kato Susumu Sugiyama Raul E. Riveros Hitomi Yamaguchi Shinya Fujihira Yoshiaki Kanamori Kohei Morishita Kazuo Nakajima Ryutaro Maeda 《Microsystem Technologies》2010,16(8-9):1633-1641
We are developing novel ultra light-weight and high-resolution X-ray micro pore optics for space X-ray telescopes. In our method, curvilinear micro pore structures are firstly fabricated by silicon deep reactive ion etching (DRIE) or X-ray LIGA processes. Secondly, side walls of the micro structures are smoothed by magnetic field assisted finishing and/or hydrogen annealing techniques for high reflectivity mirrors. Thirdly, to focus parallel X-ray lights from astronomical objects, these structures are elastically or plastically bent into a spherical shape. Fourthly, the bent structures are stacked to form a multi-stage X-ray telescope. In this paper, we report on fabrication and X-ray reflection tests of silicon and nickel X-ray mirrors using the DRIE and LIGA processes, respectively. For the first time, X-ray reflections were confirmed on both of the mirrors. Estimated rms roughnesses were 5 nm and 3 nm for the silicon and nickel mirrors, respectively. 相似文献