Microstructure of External Stress Whiskers and Mechanical Indentation Test Method

Lead-free commercial products have been dramatically increasing in the world markets as the restriction of certain hazardous substances (RoHS) directive in the European Union has been enacted. At the same time, the problem of “tin whiskers” has become one of the most serious problems in the industry. Growth of tin whiskers is believed to be related to residual stress inside the tin plating film and external compressive stress. Whiskers in fine-pitch connectors have affected the practical production of advanced digital equipment. The Japan Electronics and Information Technology Industries Association (JEITA) has proposed a new testing method to evaluate tin whiskers, especially for the fine-pitch connectors. This paper describes the microstructures of external stress whiskers and the mechanical indentation test method.     

Growth of β-Alumina (Na2O · 11Al2O3) Single Crystals by the Flux Method

The crystal-growth process and growth conditions of β-alumina (Na₂O · Al₂O₃) were investigated using the Na₂B₄O₇-Na₃AlF₆ flux method. β-Alumina (electric fusion brick) was used as both nutrient and seed. Weight loss of the flux varied widely for various runs: ≅ 10 wt% of flux evaporated at 100 h, ≅ 17 wt% at 150 h, and 43 wt% at 600 h. When β-alumina crystal was grown, only 20 wt% Na₂B₄O₇ was added to the Na₃AlF₆ flux. The linear growth rates of the β-alumina single crystal grown by an Na₃AlF₆-20 wt% Na₂B₄O₇ flux method at 1040°C and Δ t = 18°C were ≅ 1.0 × 10⁻³ mm/h ( a face) and ≅0.3 × 10⁻³ mm/h ( c face). The β-alumina single crystals grown were bounded by only c [001] and a [100] and were colorless and transparent.     

Round‐robin measurement intercomparison of c‐Si PV modules among Asian testing laboratories

Because of recent advances in the production and installation of photovoltaic (PV) systems, the international conformity of PV module performance measurement has become increasingly important. The increase in PV production sites is particularly significant in the Asian region. The present paper summarizes and discusses the results of a round‐robin intercomparison of crystalline silicon modules among national laboratories and certified testing laboratories in the Asian region conducted from 2009 to 2011. Most of the values of P_max measured at the different laboratories were within a ±2% range, although some P_max results showed differences of up to about 3%. This result is comparable to that obtained in the recent intercomparison among international laboratories. Possible sources of difference in the measured values of I_sc, V_oc, FF, and P_max are discussed, for further improvement of international conformity in PV measurement technologies. Copyright © 2012 John Wiley & Sons, Ltd.     

Random-coiled conformation of polypeptide chains

Summary Random-coiled conformation of poly(L-leucine), which has -branched side-chain, was theoretically analyzed by a conformational energy calculation based on intra-residue interactions. Calculated characteristic ratio 7.62 was obtained by using the transformation matrix statistically averaged over the entire side-chain conformational space of L-Leu residue. This value is smaller than those of poly(L-phenylalanine) (11.24) and poly(L-tyrosine) (12.33) which have -branched side-chain.     

Microporous activated carbons from used coffee grounds for application to electric double‐layer capacitors

Electrochemical double‐layer capacitors (EDLCs) are devices that store enormous amounts of charge electrostatically when a potential is applied between electrodes of very high surface area (typically made of porous carbon) and an electrolyte. Wider commercialization of this technology has been held back by the lack of ultralow‐cost electrode materials. We demonstrate that used coffee grounds can be processed to form low‐cost electrodes. The surface and electrochemical characteristics of microporous activated carbons from used coffee grounds (CGCs) were measured. First, optimal times and temperatures for carbonization and activation were identified on the basis of Brunauer–Emmett–Teller (BET) surface area, pore volume, and pore size distribution. Second, CGCs were used as polarized electrodes in EDLCs, whose capacitances were evaluated using cyclic voltammetry. The results show that carbonization for 1 h at 600 °C with a heating rate of 300 °C/h, followed by CO₂ activation for 2 h at 1000 °C, affords the highest BET surface area (1867 m²/g) compared to other works. The produced CGCs have many micropores of less than 2 nm across, which contribute to the formation of an electric double layer. Capacitors made using these CGCs show the highest capacitance (103 F/g) in 0.8 M (C₂H₅)₄NBF₄/PC as an organic electrolyte, which is much higher than the ∼80 F/g typically used in organic‐electrolyte‐based commercial EDLCs, suggesting that coffee grounds are a useful electrode material. © 2014 Institute of Electrical Engineers of Japan. Published by John Wiley & Sons, Inc.     

A method to determine direct‐ and quadrature‐axis inductances of permanent magnet synchronous motors

The equivalent circuit constants of permanent magnet synchronous motors are needed in the calculation of operation characteristics, construction of a control system, etc. These constants can be computed from the data on structural form and materials. However, measurements are necessary to obtain highly precise values. Methods for measurement of the d‐ and q‐axis inductances can be roughly divided into rotational and standstill methods. The standstill methods have the advantage that they are easy to carry out. However, it is difficult to consider magnetic saturation and distortion of the change in the armature winding inductance. The accuracy of the standstill method can be improved if these effects can be readily taken into account. This paper describes a standstill method for measuring accurate d‐ and q‐axis synchronous inductances of permanent magnet synchronous motors. By utilizing the fact that the EMF interference terms in the motor voltage equation considering the distortion of the inductance change are equal to zero when the rotor is in a specific position, the proposed method determines the inductances considering both magnetic saturation and inductance distortion effects from simple off‐line standstill testing. In addition, this method is capable of taking cross‐magnetic saturation into account when used with the necessary testing equipment. The proposed method was implemented on a 0.4‐kW interior permanent magnet synchronous motor with concentrated stator winding. The validity of the proposed method was demonstrated by comparing the measured and calculated results of the no‐load and on‐load characteristics. © 2010 Wiley Periodicals, Inc. Electr Eng Jpn, 171(3): 41–50, 2010; Published online in Wiley InterScience ( www.interscience.wiley.com ). DOI 10.1002/eej.20969     

Measurement and numerical prediction of fiber‐reinforced thermoplastics' thermal conductivity in injection molded parts

Recent improvements in injection molding numerical simulation software have led to the possibility of computing fiber orientation in fiber reinforced materials during and at the end of the injection molding process. However, mechanical, thermal, and electrical properties of fiber reinforced materials are still largely measured experimentally. While theoretical models that consider fiber orientation for the prediction of those properties exist, estimating them numerically has not yet been practical. In the present study, two different models are used to estimate the thermal conductivity of fiber reinforced thermoplastics (FRT) using fiber orientation obtained by injection molding numerical simulation software. Experimental data were obtained by measuring fiber orientation in injection molded samples' micrographs by image processing methods. The results were then compared with the numerically obtained prediction and good agreement between numerical and experimental fiber orientation was found. Thermal conductivity for the same samples was computed by applying two different FRT thermal conductivity models using numerically obtained fiber orientation. In the case of thermal conductivity, predicted results were consistent with experimental data measurements, showing the validity of the models. © 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014 , 131, 39811.     

Electroelastic Response of Cylindrical Fiber with D∞ Symmetry Exposed to Local Electric Field Through Opposed Electrode Pair

To obtain practical information on the electroelastic behavior of poly-l-lactic acid microtweezers or catheters, a previously constructed analytical technique is used to obtain the electroelastic field solution of a poly-l-lactic acid cylindrical fiber exposed to a local electric field, which is applied through an opposed pair of square-sectioned electrodes. The numerical representation of the solution reveals the detailed field quantity distributions, their importance in the design of microtweezers and catheters, the overall deformation of such devices, and the effects of the electrode dimensions on the deformation.