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11.
The light scattering from the spherulites of polyethylene terephthalate grown near the glass transition temperature has been investigated. The Hv scattering profiles can be reproduced by the sum of the ideal spherulite scattering with the distribution of spherulite radius and the isotropic scattering from randomly oriented crystallites. The ratio of optical anisotropies in the isotropic scattering to the ideal spherulite scattering is obtained by the method established to eliminate the effects of the number density of spherulites and the coefficient depending on the experimental conditions. It is found that the anisotropy ratio is almost independent of the crystallization time and of temperature above 106 °C, while it is larger at a crystallization temperature of 103 °C. The spherulitic structure is discussed in terms of the anisotropy ratio. 相似文献
12.
Zhen-Yan Deng Jian-Feng Yang Yoshihisa Beppu Motohide Ando Tatsuki Ohji 《Journal of the American Ceramic Society》2002,85(8):1961-1965
Porous ZrO2 ceramics were fabricated by compacting a fine ZrO2 powder, followed by pressureless sintering. Two unidirectional pressures of 30 and 75 MPa were used to prepare the green compacts. The strength and the fracture toughness of porous ZrO2 specimens sintered from the compacts prepared by 75 MPa were substantially higher than those by 30 MPa, especially for the specimens with low porosity. However, the corresponding Young's moduli were identical. This caused the strain to failure of these porous bodies to increase significantly with increasing compaction pressure. Microstructural analyses showed that a number of voids and small flaws existed in the green compacts prepared by the lower pressure, due to the agglomeration of fine ZrO2 grains. It was revealed that the ZrO2 agglomeration resulted in a localized nonuniform shrinkage and degraded the mechanical properties of porous ZrO2 ceramics. 相似文献
13.
Dalia Heggo Shinichi Ookawara Teruhisa Ohno Toru Nakai Yoshihisa Matsushita Mona Gamal Eldin Masahiro Ohshima 《加拿大化工杂志》2020,98(1):119-126
Dense photocatalyst slurry was employed for the synthesis of p-anisaldehyde under solar light irradiation. An Fe-modified rutile TiO 2 (Fe-TiO 2, 34.5 m 2/g) photocatalyst was used as a visible-light-responsive photocatalyst. A conventional TiO 2 (P25, 35 m 2/g) photocatalyst was also examined as a reference catalyst. XRD patterns and diffuse reflectance spectra showed that Fe-TiO 2 consists of 100 % rutile phase and absorbs more visible light compared to P25, respectively. The catalyst powder was suspended in an ethyl acetate solution of p-methoxytoluene in the mini-reactor, with oxygen bubbling, under a solar simulator, visible light, and UV LEDs. p-anisaldehyde, as a reaction product, was analyzed by sampling using gas-chromatograph. Regardless of the light source, Fe-TiO 2 always outperformed P25 in terms of both generation rates (GR) of p-anisaldehyde and energy requirements (ER). It was demonstrated that the highly dense Fe-TiO 2 slurry was efficient for the synthesis under solar light owing to the small size of the reactor. The small amount of Pt and ZrO 2 cocatalysts significantly enhanced the GR under solar light. By adopting a visible light responsive Fe-TiO 2 photocatalyst, the mini slurry-bubble reactor under solar light achieved a high GR per catalyst mass (CM), which is one to two orders higher than that reported by most previous studies with high-power lamps. 相似文献
14.
To improve the versatility of light cycle oil (LCO), separation of aromatic compounds from LCO by solvent extraction was investigated. LCO was analyzed to identify 35 components: 19 aromatics and 16 alkanes. The batch liquid–liquid equilibrium extraction of LCO was performed using furfural, sulfolane, and methanol as extraction solvents. In each solvent, the aromatics present in LCO were selectively extracted relative to the alkanes. The separation selectivities of aromatics relative to alkanes were larger in sulfolane than in the other solvents. Among the aromatic components, di- and tricyclic compounds were selectively extracted relative to the monocyclic ones. 相似文献
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17.
Yoshihisa Matsushita Nobuko Ohba Tadashi Suzuki Teijiro Ichimura 《Catalysis Today》2008,132(1-4):153-158
A photocatalytic microreaction system was developed and photocatalytic N-alkylation process of benzylamine, aniline, and piperidine was examined. The reaction proceeded quite rapidly in the microreactors with immobilized Pt-free TiO2 as well as Pt-loaded TiO2, while it has been reported that the N-alkylation did not occur by the irradiation of Pt-free TiO2 in conventional batch reactors. It was revealed that by using the unique features of the continuous-flow microreactor, for instance spatial illumination homogeneity and precise control of flow and irradiation conditions, one can control the selectivity of N-alkylation and N,N-dialkylation processes. These results suggest the possibilities of a photocatalytic microreaction system on organic synthetic reactions. 相似文献
18.
Masao Shimizu Naoto Kudo Yoshinobu Nakajima Noboru Matsuo Yoshihisa Katsuragi Ichiro Tokimitsu Francisca Barceló 《Journal of the American Oil Chemists' Society》2008,85(7):629-633
Olive oils have a higher relative diacylglycerol (DAG) content than other plant oils. The lipase in olive fruits is involved
in DAG production and is directly related to the acidity of the olive oil. However, the lipase activity and positional selectivity
have not been clarified. To investigate the properties of olive fruit lipase, olive fruits of the Mission variety harvested
during mid-December of 2005 on Shodoshima Island (Japan) were stored at 20, 30 or 40 °C for 4 weeks. Changes in the acidity
and acylglycerol content of the oils extracted from the stored fruits were analyzed. The acidity and DAG content of the olive
oils increased due to triacylglycerol (TAG) hydrolysis during storage. sn-1,2-DAGs preferentially increased during the early stages of storage, indicating that the olive fruit lipase is enantioselective
for the sn-3 position, while non-enzymatic isomerization of sn-1,2-DAGs was observed throughout the entire duration of storage. Kinetic analysis revealed that the enantioselectivity of
olive fruit lipase for the sn-3 position was approximately four times greater than for the sn-1 position. The lipase was gradually inactivated at temperatures of 30 °C or higher, and the ratios of the rate constant
for inactivation to TAG hydrolysis at the sn-3 position was 0.2, 13, and 23 at 20, 30, and 40 °C, respectively. 相似文献
19.
The tensile properties and fracture behavior of ultrahigh tensile strength PAN-based (T1000GB), ultrahigh modulus pitch-based (K13D) and high ductility pitch-based (XN-05) carbon fibers have been investigated. The statistical distributions of the tensile strength were characterized. The Weibull modulus for the T1000GB, K13D and XN-05 fibers were calculated to be 5.9, 4.2 and 7.9, respectively. The results clearly show that for PAN- and pitch-based carbon fibers, the Weibull modulus decreases with an increase in the tensile modulus and the mean tensile strength. 相似文献
20.
An anti-fatigue smart paste, which consists of fine alumina particles and silicone grease with low viscosity, was applied to a bolt hole (and its periphery in some cases) in a steel plate specimen, and the effects of the smart paste on automatic restraint and visual detection of fatigue crack growth were experimentally investigated through fatigue tests. Fractographic observations using a scanning electron microscope were also carried out. As a result, approximately 20~410% increase in failure life was produced by the wedge effect of the alumina particles in the smart paste. When the smart paste was applied, remarkable black colour developed in the white paste along the paths of crack growth, exceedingly facilitating the visual detection of the crack growth. 相似文献