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101.
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ABSTRACT

Parametric analyses of the strain-stress in the drying process are performed to study the influence of the intermittent drying on the behaviors of drying-induced strain-stress and deformation as well as the drying characteristic. The transient three-dimensional problem of strain-stress and heat and moisture transfer in a slab is solved simultaneously by the finite element method. The dimensionless parameters are introduced to generalize the problem in the conservation equations of heat and moisture transfer. The intermittent drying is modeled by applying periodically smaller and larger Biot numbers to the boundary conditions. The maximum tensile and compressive stresses fluctuate, and fall remarkably during the smaller Biot number period when a slab is heated intermittently. The peak stress of the fluctuation exceeds beyond the case in the continuous healing where the overall drying rate is almost equivalent to that in the intermittent beating, but the reduction of the stresses takes place rapidly in the low heating period.  相似文献   
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We have developed an efficient method for the esterification or thioesterification of equimolar amounts of carboxylic acids and alcohols or thiols using a novel reagent, p‐toluenesulfonyl chloride (TsCl) together with N‐methylimidazole. The present method is simple, mild, and reactive, uses readily available and economical reagents. The choice of amine is critical for the present method. The amine, N‐methylimidazole, has two roles: (i) as an HCl scavenger for the initial smooth generation of mixed anhydrides between carboxylic acids and TsCl and (ii) successive formation of highly reactive ammonium intermediates from mixed anhydrides. This method could be applied to various types of carboxylic acids, alcohols, and thiols: a) several functionalities were tolerated; b) two N‐Cbz amino acids were smoothly esterified without racemization; and c) the labile 1β‐methylcarbapenem key intermediate and a pyrethroid insecticide, prallethrin, were successfully prepared. The related amide formation between carboxylic acids and primary or secondary amines was also performed. The proposed reaction mechanism involves a novel method for producing the reactive acylammonium intermediates. The production of these intermediates was rationally supported by a careful 1H NMR monitoring study.  相似文献   
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The triacylglycerols (TAGs) containing saturated (Sat)-unsaturated (U) fatty acid moieties (Sat-U mixed acid TAGs) are widely present in most natural fats and employed in many industrial applications. The mixing behavior of different Sat-U mixed acid TAGs acts important roles in the physicochemical properties TAG-based materials. Among the three main mixing states of miscible, eutectic and molecular compound (MC) forming mixtures, fundamental research has been conducted on the MC crystals formed by different Sat-U mixed acid TAGs to understand the structures, phase behavior and crystallization properties. This article reviews studies to date on the complex thermodynamic, kinetic and structural factors that affect the formation of MC crystals in binary and ternary mixtures of Sat-U mixed acid TAGs (SatUSat, SatSatU, USatU and UUSat) through specific molecular interactions among the component TAGs. Furthermore, the application of the MC-forming mixtures containing cacao butter to new types of cocoa butter alternative is reviewed.  相似文献   
106.
In this paper, a new efficient feature extraction method is proposed to handle the one‐step‐ahead daily maximum load forecasting. In recent years, power systems become more complicated under the deregulated and competitive environment. As a result, it is not easy to understand the cause and effect of short‐term load forecasting with a bunch of data. This paper analyzes load data from the standpoint of data mining. By it we mean a technique that finds out rules or knowledge through large database. As a data mining method for load forecasting, this paper focuses on the regression tree that handles continuous variables and expresses a knowledge rule as if‐then rules. Investigating the variable importance of the regression tree gives information on the transition of the load forecasting models. This paper proposes a feature extraction method for examining the variable importance. The proposed method allows to classify the transition of the variable importance through actual data. © 2006 Wiley Periodicals, Inc. Electr Eng Jpn, 156(2): 43–51, 2006; Published online in Wiley InterScience ( www.interscience.wiley.com ). DOI 10.1002/eej.20104  相似文献   
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The spanning tree model' (utilising Gaussian-flight statistics) for the kinetics of simultaneous ring-chain competition in linear and branched polycondensation reactions has been extended by the use of the path weighting method of cascade statistics to the system glycerol/adipic acid. In this system there is no single fixed increment in ring sizes as more units are added to the ring-closing path, since a glycerol unit incorporated through the reaction of its two primary hydroxyls contributes a longer increment to the path length than when one primary and one secondary hydroxyl are involved. A computational method has been developed to count, as the reaction proceeds, the mean number of paths of all lengths available for forming a cycle back to a given root functionality, with each path receiving the correct Gaussian weight according to its length.  相似文献   
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The mixing and mass transfer characteristics in concentric-tube airlift gas-liquid contactors intended for possible use as fermenters are discussed. Liquid velocities, circulation times, gas hold-ups, and volumetric mass transfer coefficients were measured in water and aqueous carboxy methyl cellulose solutions. Measurements were made in an inverted conical-bottom device with draft tubes of three different diameters. An increase of liquid velocities at the column axis and a corresponding decrease of volumetric mass transfer coefficients due to the introduction of draft tubes were found for water as the liquid medium. For the non-Newtonian fluids, a complicating influence of the draft tubes on liquid velocity and mass transfer, which is attributed to a combination of factors related to improvement of liquid circulation and reduction of apparent viscosity, was observed.  相似文献   
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