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121.
Tomomichi Okano Naoyuki Egawa Masami Fujiwara Masahiro Fukuda 《Journal of the American Oil Chemists' Society》1996,73(1):31-37
Sodium α-sulfonated, fatty acid polyethylene glycol monoesters [C
m
H2m+1CH(SO3Na)COO(C2H4O)
n
H] and diesters [C
m
H2m+1CH(SO3Na)COO(C2H4O)
n
COCH(SO3Na)C
m
H2m+1], wherem=10–16 andn=1–35, were prepared by esterification of α-sulfonated, fatty acids with polyethylene glycols, followed by neutralization
with NaOH. Crude products were purified by reversed-phase column chromatography on an octadecyl-modified silica gel. Characteristic
solution behavior of these α-sulfonated fatty acid esters was, examined, and the following features were observed. All monoesters
prepared in this work had Krafft points below 0°C and also possessed good calcium stabilities. Critical micelle concentrations
of the monoesters increased monotonously, as a rule, with an increase in the number of oxyethylene units. These results suggest
that the polyethylene glycol residue of the monoester behaves as a hydrophile. On the other hand, diesters possessed high
water solubility, low foamability, and critical micelle concentrations that were lower by a factor of ten compared to those
of the monoesters. 相似文献
122.
The State of the Art of Sludge Drying in Japan 总被引:1,自引:0,他引:1
123.
124.
Measures preventing an earthquake-induced soil liquefaction are of significant importance to mitigate the liquefaction hazards. An air-injection technique may be a simple, inexpensive method - this leads the saturated soils to the desaturated by injecting pressurized air, resulting in a higher liquefaction strength and lower susceptibility. The objective of this study is to investigate the evolution of desaturation process during air injection into saturated soil deposits and verify the validity of a multiphase flow simulator if it is capable of being applied for predicting the process as well as the distribution of degree of saturation after the air injection ceased. In this study simplified model tests that simulate the air injection into saturated soils using air-injection probes, are conducted using two different sizes of soil containers. The experiments using the small container are aimed to examine the nominal rates and magnitudes of the soil desaturation driven by air injection, whilst those with the large container are performed to obtain not only the rates and magnitudes but also the distributions of the desaturated zones within the soil. The results obtained indicate, although clearly depending on the physical properties of targeted soils, that the evolution of desaturation is strongly controlled by the air pressures injected and the soil permeabilities. Numerical analyses are also conducted using a multiphase flow simulator to describe the evolution of the soil desaturation, and to examine the applicability of the model as a prediction tool enabling an evolution of desaturation in situ to be followed with time and space. Predictions show a relatively good agreement with the experimental measurements regarding the rates, magnitudes, and distribution of desaturation specifically for the small-container experiments although predictions of desaturated domain slightly overestimate the measurements for the large-container experiments. Thus, this study indicates that the numerical model described is applicable to field problems when the soil properties in terms of flow transport are well-constrained. 相似文献
125.
Taher Sharshar Kotoyuki Okano Yoichi Kawase 《Nuclear instruments & methods in physics research. Section B, Beam interactions with materials and atoms》1992,70(1-4):259-264
The basic characteristics of a N2-jet system coupled with a surface-ionization type ion source have been investigated at KUR-ISOL. The yields of transported activities and ionized ions have been measured under various conditions for both the He- and N2-jets. The effects of N2 gas upon the ionization and skimmer efficiency have been investigated. It was found that N2 gas has almost no effect upon the ionization efficiency, but causes poorer skimmer efficiency than He gas owing to the large opening angle of aerosol particles at the outlet of a capillary. A mixture of He and N2 gases was also tested. 相似文献
126.
127.
Araki Masuyama Tomomichi Okano Mitsuo Okahara 《Journal of the American Oil Chemists' Society》1988,65(11):1830-1833
Amide oxime compounds have become of major interest because they can complex with uranium, gallium and various transition
metal ions. In this work surface active amide oximes were prepared to make some functions of the amide oxime group exhibit
as molecular aggregates in aqueous media. Amide oximes were obtained from nitriles which were prepared by the cyanoethylation
of alcohol ethoxylates with a monodispersed oligo(oxyethylene) group. Surface active properties of these compounds were measured
under various conditions and were compared with nonionics of the alcohol ethoxylate type. The pKa1 values of these amide oximes were about five, and they acted as cationic surfactants under acidic conditions and nonionic
ones under neutral and basic conditions. When they served as nonionics, the cloud point, CMC, γCMC and foaming properties of surface active amide oximes were similar to other alcohol ethoxylate nonionics. 相似文献
128.
Hepatocyte growth factor (HGF) stimulates inositol 1,4,5-trisphosphate (InsP3) formation in rat primary cultured hepatocytes, which is inhibited by the pretreatment with a tyrosine kinase inhibitor, genistein. This InsP3 production was coincident with tyrosine phosphorylation of phospholipase C gamma (PLC gamma), detected in immunoprecipitates with anti-PLC gamma, suggesting activation mechanism of PLC gamma by tyrosine phosphorylation. However, in human hepatocarcinoma HepG2 cells, HGF, which suppresses cell growth, causes neither phosphorylation of PLC gamma nor InsP3 formation. The results suggests that PLC gamma in normal hepatocytes was activated by HGF through tyrosine kinase of HGF receptor. 相似文献
129.
LIM-kinase 1 (LIMK1) and 2 (LIMK2) are members of a novel class of protein kinases containing two LIM motifs at the N-terminus. The LIM motif is thought to be involved in protein-protein interactions. We report here evidence that LIMK1 self-associates and also associates with LIMK2. In vivo and in vitro binding analyses using variously deleted mutants of LIMKI revealed that the self-association of LIMK1 was caused by interaction between the N-terminal LIM domain and the C-terminal kinase domain. The association of LIMK1 with itself and with LIMK2 is important for understanding how activities and functions of LIMK family kinases are regulated. 相似文献
130.
Yoshinori Iwahashi Zenji Horita Minoru Nemoto Terence G. Langdon 《Metallurgical and Materials Transactions A》1998,29(10):2503-2510
Experiments were undertaken to compare the equal-channel angular (ECA) pressing of Al-1 pct Mg and Al-3 pct Mg solid-solution
alloys with pure Al. The results reveal both similarities and differences between these three materials. Bands of subgrains
are formed in all three materials in a single passage through the die, and these subgrains subsequently evolve, on further
pressings through the die, into an array of grains with high-angle boundaries. However, the addition of magnesium to an aluminum
matrix decreases the rate of recovery and this leads, with an increasing Mg content, both to an increase in the number of
pressings required to establish a homogeneous microstructure and to a decrease in the ultimate equiaxed equilibrium grain
size. It is concluded that alloys exhibiting low rates of recovery should be especially attractive candidate materials for
establishing ultrafine structures through grain refinement using the ECA pressing technique. 相似文献