Surface modification of biodegradable plastics by ion beams

Biodegradable plastics can be used as conventional plastics, while on disposal they decompose to water and carbon dioxide by microorganisms existing in natural environment. Products using biodegradable plastics have recently been developed in many companies pursuing ecology. In this study, surface modification of biodegradable plastics was carried out by inert ion beams for improvement of photo deterioration under an ultraviolet ray. The hardness of biodegradable plastics tended generally to decrease with irradiation of an ultraviolet ray. In this method, the hardness of ion-bombarded biodegradable plastics was kept at an initial value under an ultraviolet ray, because the modified layer by ion bombardment intercepted an ultraviolet ray. The hardness of He⁺ ion-bombarded biodegradable plastics showed larger value than that of Ar⁺ ion bombardment. He⁺ ion bombardment at ion energy of 10 keV produced the suitable property with both of high transmittance of a visible ray and high interception of an ultraviolet ray in a surface layer of biodegradable plastics.     

Photocatalytic TiO2 films deposited by reactive magnetron sputtering with unipolar pulsing and plasma emission control systems

TiO₂ films with thickness of about 500 nm were deposited on unheated non-alkali glass substrates by reactive magnetron sputtering using one Ti metal target with unipolar pulsed powering of 50 kHz and the plasma emission feedback system (PCU). In order to keep the very high deposition rate, the depositions were carried out in the “transition region” between the metallic and the reactive (oxide) sputter mode where the target surface was metallic and oxidized, respectively. Stable deposition was successfully carried out in the whole “transition region” with PCU at total gas pressure of 3.0 Pa. All the as-deposited films deposited in the “transition region” showed amorphous structure, which performed very low photocatalytic activity. After the post-annealing in air at higher than 300 °C, all the films crystallized to anatase polycrystalline structure. They performed both photoinduced decomposition of acetaldehyde and photoinduced hydrophilicity under UV light illumination. The highest deposition rate in this study to deposit the photocatalytic TiO₂ films in the “transition region” was 90 nm/min, which was over twenty times higher than that for conventional sputter deposition processes.     

Czochralski growth of Yb doped oxyapatite for high power laser application

Ca₈(La,Yb)₂(PO₄)₆O₂ (Yb:CLPA) single crystals with the apatite-type structure could be grown from the melt using the Czochralski method. Grown crystal was 18 mm in diameter and 110 mm in length. It is transparent with slightly blue color. Neither visible inclusion nor crack was observed. Thermal conductivity of Yb:CLPA was calculated from the values of thermal diffusivity, heat capacity measurement and density. Luminescent characterization was carried out from the results of emission, absorption and Raman spectrum.     

Remote sensing of vegetation and land-cover change in Arctic Tundra Ecosystems

The objective of this paper is to review research conducted over the past decade on the application of multi-temporal remote sensing for monitoring changes of Arctic tundra lands. Emphasis is placed on results from the National Science Foundation Land-Air-Ice Interactions (LAII) program and on optical remote sensing techniques. Case studies demonstrate that ground-level sensors on stationary or moving track platforms and wide-swath imaging sensors on polar orbiting satellites are particularly useful for capturing optical remote sensing data at sufficient frequency to study tundra vegetation dynamics and changes for the cloud prone Arctic. Less frequent imaging with high spatial resolution instruments on aircraft and lower orbiting satellites enable more detailed analyses of land cover change and calibration/validation of coarser resolution observations.The strongest signals of ecosystem change detected thus far appear to correspond to expansion of tundra shrubs and changes in the amount and extent of thaw lakes and ponds. Changes in shrub cover and extent have been documented by modern repeat imaging that matches archived historical aerial photography. NOAA Advanced Very High Resolution Radiometer (AVHRR) time series provide a 20-year record for determining changes in greenness that relates to photosynthetic activity, net primary production, and growing season length. The strong contrast between land materials and surface waters enables changes in lake and pond extent to be readily measured and monitored.     

Chemical doping and improved flux pinning in Hg-based superconductors

Chemical doping of a small amount (0.020.3) of rhenium (Re) ion into HgBa₂Ca_n–1Cu_nO_y(n=14) has been studied. The flux pinning strength in these Hg-based superconductors is significantly enhanced compared to the undoped parent materials. Neutron diffraction analysis of representative samples (n=3) revealed that Re partially substitutes the Hg-site with octahedrally fully coordinated oxygen atoms, giving rise to the stabilization of Hg(Re)O layer and reduction of this blocking layer thickness. Associated with the expected hybridization of Re-5d and O-2p orbitals and possible metallization of the Hg(Re)O layer, the improved flux pinning behavior is considered to be caused by the decrease of the electromagnetic anisotropy and the enhanced interlayer superconducting coupling strength.     

Superior electrocatalytic activity of mesoporous Au film templated from diblock copolymer micelles

Mesoporous Au films consisting of a network of interconnected Au ligaments around ultra-large pores were found to exhibit a promising electrocatalytic activity towards sluggish reactions. Mesoporous Au films with pore sizes up to 25 nm were successfully fabricated using a polymeric micelle approach. A superior catalytic activity of the mesoporous Au films towards methanol oxidation was confirmed, which was thoroughly analyzed and compared with that of other Au materials. An intrinsic investigation on the high catalytic activity revealed that the superior performance of the as-prepared mesoporous Au film was related to its unique atomic structures around the mesopores with well-crystallized facets and several step/kink sites on the Au surfaces. These findings showcase a strategic and feasible design for preparing highly active Au-based catalysts that could be used as promising candidates in electrocatalytic applications.

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A versatile planar QCM-based sensor design for nonlabeling biomolecule detection

Despite high theoretical sensitivity, low-cost manufacture, and compactness potentially amenable to lab-on-a-chip use, practical hurdles have stymied the application of the quartz crystal microbalance (QCM) for aqueous applications such as detection of biomolecular interactions. The chief difficulty lies in achieving a sufficiently stable resonance signal in the presence of even minute fluctuations in hydrostatic pressure. In this work, we present a novel versatile planar sensor chip design (QCM chip) for a microliter-scale on-line biosensor. By sealing the quartz resonator along its edges to a flat, solid support, we provide uniform support for the crystal face not exposed to solvent, greatly decreasing deformation of the crystal resonator under hydrostatic pressure. Furthermore, this cassette design obviates the need for direct handling when exchanging the delicate quartz crystal in the flow cell. A prototype 27-MHz sensor signal exhibited very low noise over a range of flow rates up to 100 microL/min. In contrast, signals obtained from a conventional QCM sensor employing an O-ring-based holder were less stable and deteriorated even further with increasing flow rate. Additional control designs with intermediate amounts of unsupported undersurface yielded intermediate levels of stability, consistent with the interpretation that deformation of the crystal resonator under fluctuating hydraulic pressure is the chief source of noise. As a practical demonstration of the design's high effective sensitivity, we readily detected interaction between myoglobin and surface-bound antibody.     

Evaluation of thermal spike due to exothermic reaction in curing process of carbon fiber-reinforced plastic pressure accumulators for hydrogen stations

In the curing process of fiber-reinforced plastic accumulators, a thermal spike appears due to the exothermic reaction of the resin. It is necessary to accurately evaluate this thermal spike to guarantee quality and avoid using a trial and error approach to control the temperature. Thus, we developed a curing process simulator that is able to accurately evaluate the thermal spike of the thermosetting resin. A simplified mesoscale finite element model with the definite separation of fiber and resin is used in the simulation. In this study, the newly developed simulation system was examined by comparing its results with the experimental results from the curing process of fiber-reinforced plastic accumulators.     

Readout characteristics of flexible monolithic optical head slider combined with visible laser light guide

Optical near-field recording is a candidate technology for overcoming the diffraction limit of conventional optical recording. In our previous work, we proposed a novel optical head slider for near-field recording that we call a flexible optical head slider. An air-bearing pad pattern is formed on the apex of a cantilever-like polymeric waveguide so that, by using the cantilever itself as the slider suspension, a single body structure incorporates the functions of the flying slider, suspension, and waveguide. This structure can be expected to provide several important advantages by miniaturizing head assemblies; simplifying the assembly and optical trimming processes; and producing a lighter head, thus allowing a wider tracking bandwidth. In this paper, we report the read-out signal evaluation of the flexible optical head slider. Using a slider with a sub-micron sized aperture, read-out of a test metal-patterned ROM (Read Only Memory) disk was successfully demonstrated down to a 0.2 μm linewidth line and space pattern.     

Photoluminescence Analysis of Iron Contamination Effect in Multicrystalline Silicon Wafers for Solar Cells

We investigated the effect of Fe contamination on the electronic properties of dislocation clusters in relation to oxygen precipitation in multicrystalline silicon (mc-Si). Photoluminescence (PL) spectroscopy and mapping were performed at room and liquid-He temperatures on mc-Si wafers before and after Fe contamination. PL spectra consisted of the band-edge emission, the 0.78-eV emission associated with oxygen precipitates, and the dislocation-related D-lines. The Fe contamination increased the electrically active dislocation clusters. Part of these clusters acted as preferential oxygen precipitation sites, and their electronic properties were not further influenced by the Fe contamination.