Synthesis and characterization of La2Ti2O7 employed for photocatalytic degradation of reactive red 22 dyestuff in aqueous solution

Perovskite structured La₂Ti₂O₇ catalyst prepared by polymerized complex method was characterized and examined the photocatalytic activity by decomposing an azo dyestuff, Reactive Red 22, in aqueous solutions under UV irradiation. La₂Ti₂O₇ powders prepared by polymerized complex method exhibit higher surface areas, better homogeneity and are more sensitive to solution than those prepared by solid-state method. The first derivatives of UV–vis DRS patterns confirmed the complete crystallization of La₂Ti₂O₇ sintered at temperatures higher than 900 °C. The effects of sintering temperature of catalyst and solution pH of photocatalytic reaction were studied. The photocatalytic decomposition of Reactive Red 22 per unit surface area was found to be higher for experiments using La₂Ti₂O₇ than using TiO₂. However, the electron–hole recombination was found to be more obvious for La₂Ti₂O₇ than for TiO₂ because the network of metal cations constructed within La₂Ti₂O₇ enhances the mobility of photogenerated electrons and holes.     

Multifinality in implicit choice.

This research examines the possibility that people's choices in the service of an explicit focal goal may also reflect their tendency to fulfill implicit background goals and in that sense are multifinal. We carried out 5 experimental studies to investigate this notion. In Experiment 1, a primed implicit goal affected individuals' choices even when those avowedly served an explicit “focal” goal. Experiment 2 replicated this finding with a different type of implicit goals. Experiment 3 found that primed implicit goals had no effect on choices where the options that served them undermined the explicit goal. Experiment 4 found that a primed implicit goal served by a multifinal option does not privilege it over a unifinal option if that goal had been already attained by a different means. Finally, Experiment 5, via 3 types of control groups, showed that choices were affected by both the explicit and implicit goals in isolation, and they shifted toward multifinality when these goals were conjointly present. The discussion considers the integrative potential of the multifinality framework and its implications for a variety of phenomena in the domain of motivated cognition. (PsycINFO Database Record (c) 2011 APA, all rights reserved)     

Obtaining depth map from segment-based stereo matching using graph cuts

In the paper, the algorithm of segment-based stereo matching using graph cuts is developed for extracting depth information from the stereo image pairs. The first step of the algorithm employs the mean-shift algorithm to segment the reference image, which ensures our method to correctly estimate in large untextured regions and precisely localize depth boundaries, followed by the use of Adaptive Support Weighted Self-Adaptation dissimilarity algorithm (ASW-SelfAd) for the estimation of initial disparity. This is followed by application of Singular Value Decomposition (SVD) in solving the robust disparity plane fitting. In order to ensure reliable pixel sets for the segment, we filter out outliers which contain occlusion region through three main rules, namely; cross-checking, judging reliable area and disparity distance measurement. Lastly, we apply improved clustering algorithm to merge the neighboring segments. The geometrical relationship of adjacent planes such as parallelism and intersection is employed for determination of whether two planes shall be merged. A new energy function is subsequently formulated with the use of graph cuts for the refinement of the disparity map. Finally, the depth information is extracted from the final disparity map. Experimental results on the Middlebury dataset demonstrate that our approach is effective in improving the state of the art.     

Analysis of PLR for Shared Switch Fabrics

A modular upgrade design for packet transport switch nodes is presented where packet loss is dramatically reduced by intra‐module and inter‐module buffer sharing. This modular design offers significant cost and power reduction in a high‐data‐rate system where buffers are highly costly and power‐greedy.     

A Composite Formation Route to Well‐Crystalline Manganese Oxide Nanocrystals: High Catalytic Activity of Manganate–Alumina Nanocomposites

Manganese oxide nanocrystals are combined with aluminum oxide nanocrystals to improve their crystallinity via calcination without a significant increase of crystal size. A nanocomposite, consisting of two metal oxides, can be synthesized by the reaction between permanganate anions and aluminum oxyhydroxide keggin cations. The as‐prepared manganese oxide–aluminum oxide nanocomposite is X‐ray amorphous whereas heat‐treatment gives rise to the crystallization of an α‐MnO₂ phase at 600 °C and Mn₃O₄/Mn₂O₃ and γ‐Al₂O₃ phases at 800 °C. Electron microscopy and N₂ adsorption‐desorption‐isotherm analysis clearly demonstrate that the as‐prepared nanocomposite is composed of a porous assembly of monodisperse primary particles with a size of ～20 nm and a surface area of >410 m² g^?1. Of particular interest is that the small particle size of the as‐prepared nanocomposite is well‐maintained up to 600 °C, a result of the prevention of the growth of manganate grains through nanoscale mixing with alumina grains. The calcined nanocomposite shows very‐high catalytic activity for the oxidation of cyclohexene with an extremely high conversion efficiency of >95% within 15 min. The present results show that the improvement of the crystallinity without significant crystal growth is very crucial for optimizing the catalytic activity of manganese oxide nanocrystals.     

Intact and impaired mechanisms of action understanding in autism.

Typically developing children understand and predict others' behavior by extracting and processing relevant information such as the logic of their actions within the situational constraints and the intentions conveyed by their gaze direction and emotional expressions. Children with autism have difficulties understanding and predicting others' actions. With the use of eye tracking and behavioral measures, we investigated action understanding mechanisms used by 18 children with autism and a well-matched group of 18 typically developing children. Results showed that children with autism (a) consider situational constraints in order to understand the logic of an agent's action and (b) show typical usage of the agent's emotional expressions to infer his or her intentions. We found (c) subtle atypicalities in the way children with autism respond to an agent's direct gaze and (d) marked impairments in their ability to attend to and interpret referential cues such as a head turn for understanding an agent's intentions. (PsycINFO Database Record (c) 2011 APA, all rights reserved)     

A study on the optimization of KCI-based index (Kor-Factor) in evaluating Korean journals

This study describes the development process of Kor-Factor, which is a novel composite evaluation index that was developed to promote Korean domestic academic journals. As more data accumulate, the Kor-Factor’s optimization process was modified in an attempt to address possible drawbacks of the original form; the result is presented in this study. This study compares Kor-Factor with the Impact Factor, which is the most well-known single element evaluation index. We found that Kor-Factor demonstrates a better power of differentiation and a greater capacity to reflect the reputability of key journals. The modified Kor-Factor, which has been developed through an optimization process, reveals a greater power of differentiation than the original Kor-Factor; however, the modified version has less capacity to reflect reputability. The evaluation elements of the modified Kor-Factor are better and are more evenly reflected on the index value than those of the original version. Finally, we propose the establishment of an appropriate data measurement period for the actual application of the index.