Acidogenic fermentation of blended food‐waste in combination with primary sludge for the production of volatile fatty acids

The performance of a laboratory‐scale anaerobic acidogenic fermenter fed with a mixture of blended kitchen food‐waste and primary sludge from a sewage treatment plant was investigated for the production of volatile fatty acids (VFA). The operating variables for acidogenic fermentation were kitchen food‐waste content (10 and 25 wt %), hydraulic retention time (HRT: 1, 3 and 5 days), temperature (ambient: 18 ± 2 °C, and mesophilic: 35 ± 2 °C) and pH (varied from 5.2 to 6.7). The experimental results indicated that effluent VFA concentrations and VFA production rates were higher at ambient temperature than at mesophilic conditions. The net amount of VFA with 10 wt % food‐waste increased up to 920 mg dm^?3 with an increase of HRT, but contrasting results (a decrease of 2610 mg dm^?3) were found due to the conversion of VFA into biogas in the case of 25 wt % food‐waste, which increased significantly at HRT of 3–5 days. In terms of biogas composition (CO₂ and CH₄), the organic matter was converted into CO₂ through the oxidative pathway by facultative species at low temperature while mesophilic temperature and optimum pH (6.3–7.8) played a pivotal role in increasing rate of conversion of VFA into biogas by methanogenesis. Rates of VFA production and their conversion are dependent on the food‐waste content in the mixture. Yet, the higher concentration of food‐waste (25% compared with 10%) did not produce VFA proportionally due to the increased rate of conversion of VFA into gaseous products. The maximum VFA production rate (0.318 g VFA_produced g^?1 VS_fed day^?1) was achieved in the 10 wt % food‐waste at ambient temperature and at a 5‐day HRT. Copyright © 2005 Society of Chemical Industry     

历史中心区复兴中的地域性问题与对策

本文以上海思南路47～48街坊改造为例,探讨城市形态更新与居民外迁问题,并期待相关地域性社会对策的出现。     

企业施工定额的编制以及施工成本分析平台的应用

本文阐述了施工企业内部编制定额的必要性和成本分析平台的实用性,并根据多年的工作经验就建筑施工企业对施工成本的控制谈谈一自己的认识和看法.     

锂离子电池正极材料锂锰氧化物的固相合成研究进展

阐述了固相合成反应的原理，综述了锂锰氧化物的几种固相合成方法，并着重介绍了熔融渍法，多步加热法，机械化学法和微波化学法等在锂锰氧化物合成中的研究进展。     

液态混合有机标准物质研究

本研究采用重量法配制有机液态混合标样 ,并对配制方法、混合标样的均匀性、稳定性及影响不确定度的因素进行了研究 ,并用气相色谱法进行了比对分析。经稳定性监测 ,稳定度大于等于一年 ,不确定度小于± 2 %。     

Formation of C4 species in the deactivation of a Pd/SiO2 catalyst during the selective hydrogenation of acetylene

The deactivation characteristics of Pd/SiO₂ in the selective hydrogenation of acetylene were correlated with changes in the amount of the C4 species produced. The amounts of butenes produced changed in parallel with the catalyst activity, indicating that the rate limiting step for butene production was the same as that for acetylene hydrogenation. On the other hand, the amount of 1,3-butadiene produced changed, showing a maximum with catalyst deactivation because 1,3-butadiene is an intermediate in the sequential reaction process which involves both the production and consumption of 1,3-butadiene. This was verified by a simultaneous TG/reaction experiment showing that 1,3-butadiene was a precursor of green oil. The catalyst showed a self-regenerative behavior in its activity and the amounts of C4 species produced during the early stage of deactivation because two opposite factors, which contributed to either the lowering or the promotion of activity, were involved in the process. A specific type of polymer species, produced during the initial period of deactivation, is proposed to be responsible for the promotion of catalyst activity.     

铝电解槽磁流体稳定性有限元分析

本文采用有限元法求解分层磁流体小扰动方程系统特征值，研究铝电解槽稳定性。研究结果表明，在没有电磁力时，铝液表面波动（内波）是稳定的。存在电磁力时，它会激发铝液表面波动的某些低频长波分量不稳定性，高频短波不受影响。被激发的不稳定波动频率和扰动增长率与电流密度，磁感应强度垂直分量，铝电解槽长宽比，电解质和铝液的密度差，厚度等因素密切相关。减少电流密度，磁感应强度，增加电极距离和铝液厚度可以提高铝电解槽的稳定性。这对铝电解槽优化设计和在线控制有重要意义。     

伪波阻抗反演在准噶尔盆地永进油田储层描述中的应用

永进油田目的层产状平缓,断层不发育,储层厚度小、埋深大、描述困难。运用伪波阻抗技术对该区的储层进行了研究,取得了较好的效果。