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81.
Synthesis of mesoporous materials SBA-15 and CMK-3 from fly ash and their application for CO2 adsorption 总被引:1,自引:0,他引:1
A supernatant solution of silicate species extracted from coal fly ash in a power plant by alkali fusion was used in acidic
condition to prepare a mesoporous silica SBA-15. The SBA-15 was used as a template for the synthesis of a mesoporous carbon
CMK-3 using sucrose as a carbon source. Characterization of the produced mesoporous materials by XRD, N2 adsorption-desorption, SEM, and TEM confirmed the formation of well-ordered hexagonal mesostructures. Textural properties
were found close to those prepared by pure chemicals. SBA-15 after polyethyleneimine impregnation and CMK-3 were tested for
carbon dioxide adsorption, successfully demonstrating the possibility of recycling the industrial waste product in a power
plant into a useful adsorbent. 相似文献
82.
Hong Rok Kim Jayeeta Chattopadhyay Jae Ik Son Daewon Pak 《Korean Journal of Chemical Engineering》2008,25(4):775-779
Pure TiO2 hollow spheres were prepared by using poly(styrene-methacrylic acid) latex particles as template; thereafter, titania hollow
spheres were coated by platinum with an appropriate amount of choloroplatinic acid solution to obtain Pt/TiO2 catalysts. The morphology and structure of nonstructural Pt/TiO2 hollow spheres were characterized by BET, XRD, TGA, SEM and TEM analysis. In the samples, a remarkably uniform layer of Pt
consisting of particles from 5 to 70 nm in size was formed over TiO2 hollow spheres. We found the electrocatalytic nature of the samples by cyclic voltammetric experiment in acidic solution.
The anodic peak current density of 20 wt% Pt-loaded TiO2 hollow particles was observed 2.5 times higher than that of 5 wt% Pt/TiO2 in the same experimental condition. Also, the anodic current density of 20 wt% Pt/TiO2 hollow spheres calcined at various temperatures followed the order: 400 °C≈500 °C>600 °C. The electrocatalytic activity of
the Pt-loaded TiO2 hollow spheres depends on the amount of atomic platinum present in the sample; a higher concentration of platinum results
in a larger current density value in anodic sweep, resulting in more oxygen production during electrolysis. Pt/TiO2 hollow sphere catalysts have also shown long term electrocatalytic stability in acidic media. 相似文献
83.
Effects of substituents of imidazolium cations on the performance of dye-sensitized TiO2 solar cells
Kyung Mo Son Man Gu Kang R. Vittal Jiwon Lee Kang-Jin Kim 《Journal of Applied Electrochemistry》2008,38(12):1647-1652
Imidazolium iodides (Im+I−s) were synthesized with different substituents of the cation and used as electrolytes in dye-sensitized solar cells (DSSCs),
and the effects of such substituents were investigated in terms of the photovoltaic performance of the cells. Synthesized
iodides were verified by 1H-NMR. Among the iodides, 1,3-diethylimidazolium iodide enabled a solar energy conversion efficiency of 4.8% for its DSSC,
while 1-(4-acetophenyl)-3-ethylimidazolium iodide rendered an efficiency of 3.1% for its cell. In all cases the short-circuit
photocurrent (J
sc) was found to increase with decrease in size of the substituent, which was also verified to be valid in the case of a quasi-solid
state DSSC. Results are explained by the electrostatic interactions between solvated Im+ and negatively charged species based on the correlation between diffusion coefficients of I− and I3− and J
sc values. These explanations are supported by steady-state voltammetry and electrochemical impedance spectroscopy (EIS). 相似文献
84.
Hyun-Wook Park Jae-Won Jang Young-Jin Lee Jin-Ho Kim Dae-Woo Jeon Jong-Heun Lee Hae-jin Hwang Mi-Jai Lee 《Metals and Materials International》2017,23(6):1227-1233
This study aims to develop an anode catalyst for a solid oxide fuel cell (SOFC) using electroless nickel plating. We have proposed a new method for electroless plating of Ni metal on yttria-stabilized zirconia (YSZ) particles. We examine the uniformity of the Ni layer on the plated core-shell powder, in addition to the content of Ni and the reproducibility of the plating. We have also evaluated the carbon deposition rate and characteristics of the SOFC anode catalyst. To synthesize Ni-plated YSZ particles, the plated powder is heat-treated at 1200 °C. The resultant particles, which have an average size of 50 μm, were subsequently used in the experiment. The size of the Ni particles and the Ni content both increase with increasing plating temperature and plating time. The X-ray diffraction pattern reveals the growth of Ni particles. After heat-treatment, Ni is oxidized to NiO, leading to the co-existence of Ni and NiO; Ni3P is also observed due to the presence of phosphorous in the plating solution. Following heat treatment for 1 h at 1200 °C, Ni is mostly oxidized to NiO. The carbon deposition rate of the reference YSZ powder is ~135%, while that of the Ni-plated YSZ is 1%-6%. 相似文献
85.
Published literature from the past 30 years concerning the removal of dyes from textile effluent has been reviewed. The relationship between the bioelimination by activated sewage sludge and the molecular structure of anionic, water-soluble dyes has been examined. Bioelimination of many commercially available dyes as a mechanism for decolorising textile waste waters has been shown to be an inefficient process. However, the information collated will be used as the basis for development of novel reactive dyes for potential commercial application. 相似文献
86.
Myeong-Jin Lee Young-Ju Jeon Ga-Eun Son Sihwa Sung Ju-Young Kim Heung Nam Han Soo Gyeong Cho Sang-Hyun Jung Sukbin Lee 《Metals and Materials International》2018,24(4):845-859
We present a new comprehensive scheme for generating grain boundary conformed, volumetric mesh elements from a three-dimensional voxellated polycrystalline microstructure. From the voxellated image of a polycrystalline microstructure obtained from the Monte Carlo Potts model in the context of isotropic normal grain growth simulation, its grain boundary network is approximated as a curvature-maintained conformal triangular surface mesh using a set of in-house codes. In order to improve the surface mesh quality and to adjust mesh resolution, various re-meshing techniques in a commercial software are applied to the approximated grain boundary mesh. It is found that the aspect ratio, the minimum angle and the Jacobian value of the re-meshed surface triangular mesh are successfully improved. Using such an enhanced surface mesh, conformal volumetric tetrahedral elements of the polycrystalline microstructure are created using a commercial software, again. The resultant mesh seamlessly retains the short- and long-range curvature of grain boundaries and junctions as well as the realistic morphology of the grains inside the polycrystal. It is noted that the proposed scheme is the first to successfully generate three-dimensional mesh elements for polycrystals with high enough quality to be used for the microstructure-based finite element analysis, while the realistic characteristics of grain boundaries and grains are maintained from the corresponding voxellated microstructure image. 相似文献
87.
Byung-Kook Hwang Hyuk-Soo Son Jae-Hyuk Kim Chang Hoon Ahn Chung-Hak Lee Jae-Yoon Song Young-Hyun Ra 《Journal of Industrial and Engineering Chemistry》2010,16(4):602-608
We have investigated the decomposition of excess sludge generated in a membrane bioreactor using a turbulent jet flow ozone contactor (TJC), which induced both hydrodynamic cavitation and ozonation reactions. We monitored the effects of various TJC operating parameters on the properties of the sludge, including the particle sizes, the particle size distribution, and the levels of soluble COD, total COD, and mixed liquor suspended solids. The TJC enhanced the degree of sludge reduction while consuming less energy, relative to conventional ozonation treatment systems, because of the synergic effects of hydrodynamic cavitation and ozonation. The hydrodynamic cavitation generated in the TJC increased the ozone mass transfer efficiency, which in turn promoted the rate of disintegration and solubilization of the sludge particles. 相似文献
88.
Ik Sang Shin Sung Mo Son Dae Ho Lim Yong Kang Heon Jung Ho Tae Lee 《Korean Journal of Chemical Engineering》2010,27(3):1015-1020
Characteristics of heat transfer were investigated in pressurized slurry bubble column reactors whose diameter was either
0.051, 0.076, 0.102 or 0.152 m (ID) and 1.5 m in height, respectively. Effects of gas velocity (U
G
), solid contents (S
C
), pressure (P), liquid viscosity (μ
L
) and column diameter (D) on the heat transfer coefficient (h) between the immersed vertical heater and the column were determined.
Multiple effects such as UG and D, P and D, μ
L
and D, and S
C
and D on the value of heat transfer coefficient were discussed. Temperature fluctuations were also measured and analyzed
by adapting chaos theory, which was used to explain the effects of operating variables on the heat transfer in the column.
The heat transfer coefficient increased with increasing gas velocity, pressure or solid content in the slurry phase, but decreased
with increasing liquid viscosity or column diameter. The decrease trend of h with increasing column diameter was somewhat
sensitive when the gas velocity was relatively high (U
G
⩾12 cm/s). The effects of column diameter on the h value became almost linear when the operating pressure (P=4−10 kg
f
/cm2), liquid viscosity (μ
L
=20−38 mPa·s) or solid content in the slurry phase (S
C
=10−20 wt%) was relatively high and gas velocity was relatively low, within these experimental conditions. The heat transfer
coefficient was well correlated in terms of dimensionless groups as well as operating variables. 相似文献
89.
Christiana Rissing Marcelo Rains David Y. Son 《Journal of Inorganic and Organometallic Polymers and Materials》2010,20(4):616-621
Oligomers consisting of alternating phenylethynyl and monosilyl or disilanyl moieties were synthesized in 15–64% precipitated yields by the reactions of dilithiated ethynylbenzene with dichlorodimethylsilane, dichlorodiphenylsilane, and 1,2-dichloro-1,1,2,2-tetramethyldisilane. Degrees of polymerization were fairly low due to chain termination reactions involving the deprotonation of ethynyl groups by aryllithium species. The presence of butyl chain ends was confirmed by 1H and 29Si NMR spectroscopy. 29Si NMR spectroscopy was utilized to illustrate the random pattern of connectivity along the oligomer backbones. The oligomers exhibit fluorescent behavior in solution. 相似文献
90.
Myeongjoo Son Seyeon Oh Junwon Choi Ji Tae Jang Kuk Hui Son Kyunghee Byun 《International journal of molecular sciences》2021,22(8)
Hypertension induces renal fibrosis or tubular interstitial fibrosis, which eventually results in end-stage renal disease. Epithelial-to-mesenchymal transition (EMT) is one of the underlying mechanisms of renal fibrosis. Though previous studies showed that Ecklonia cava extracts (ECE) and dieckol (DK) had inhibitory action on angiotensin (Ang) I-converting enzyme, which converts Ang I to Ang II. It is known that Ang II is involved in renal fibrosis; however, it was not evaluated whether ECE or DK attenuated hypertensive nephropathy by decreasing EMT. In this study, the effect of ECE and DK on decreasing Ang II and its down signal pathway of angiotensin type 1 receptor (AT1R)/TGFβ/SMAD, which is related with the EMT and restoring renal function in spontaneously hypertensive rats (SHRs), was investigated. Either ECE or DK significantly decreased the serum level of Ang II in the SHRs. Moreover, the renal expression of AT1R/TGFβ/SMAD was decreased by the administration of either ECE or DK. The mesenchymal cell markers in the kidney of SHRs was significantly decreased by ECE or DK. The fibrotic tissue of the kidney of SHRs was also significantly decreased by ECE or DK. The ratio of urine albumin/creatinine of SHRs was significantly decreased by ECE or DK. Overall, the results of this study indicate that ECE and DK decreased the serum levels of Ang II and expression of AT1R/TGFβ/SMAD, and then decreased the EMT and renal fibrosis in SHRs. Furthermore, the decrease in EMT and renal fibrosis could lead to the restoration of renal function. It seems that ECE or DK could be beneficial for decreasing hypertensive nephropathy by decreasing EMT and renal fibrosis. 相似文献